A review of iron and cobalt porphyrins, phthalocyanines, and related complexes for electrochemical and photochemical reduction of carbon dioxide

Manbeck, Gerald F.; Fujita, Etsuko

doi:10.1142/S1088424615300013

Title: A review of iron and cobalt porphyrins, phthalocyanines, and related complexes for electrochemical and photochemical reduction of carbon dioxide

Journal Article · Mon Mar 30 00:00:00 EDT 2015 · Journal of Porphyrins and Phthalocyanines

DOI:https://doi.org/10.1142/S1088424615300013· OSTI ID:1182538

Manbeck, Gerald F. ^[1]; Fujita, Etsuko ^[1]

Brookhaven National Lab. (BNL), Upton, NY (United States)

This review summarizes research on the electrochemical and photochemical reduction of CO₂ using a variety of iron and cobalt porphyrins, phthalocyanines, and related complexes. Metalloporphyrins and metallophthalocyanines are visible light absorbers with extremely large extinction coefficients. However, yields of photochemically-generated active catalysts for CO₂ reduction are typically low owing to the requirement of a second photoinduced electron. This requirement is not relevant to the case of electrochemical CO₂ reduction. Recent progress on efficient and stable electrochemical systems includes the use of FeTPP catalysts that have prepositioned phenyl OH groups in their second coordination spheres. This has led to remarkable progress in carrying out coupled proton-electron transfer reactions for CO₂ reduction. Such ground-breaking research has to be continued in order to produce renewable fuels in an economically feasible manner.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC00112704

OSTI ID:: 1182538

Report Number(s):: BNL-107639-2015-JA; R&D Project: CO026; KC0304030

Journal Information:: Journal of Porphyrins and Phthalocyanines, Vol. 19, Issue 01-03; ISSN 1088-4246

Publisher:: World ScientificCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 152 works

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References (83)

Carbon Dioxide Capture: Prospects for New Materials D'Alessandro, Deanna M.; Smit, Berend; Long, Jeffrey R. Angewandte Chemie International Edition, Vol. 49, Issue 35, p. 6058-6082 https://doi.org/10.1002/anie.201000431	journal	July 2010
Reduction potentials of CO2- and the alcohol radicals Schwarz, H. A.; Dodson, R. W. The Journal of Physical Chemistry, Vol. 93, Issue 1 https://doi.org/10.1021/j100338a079	journal	January 1989
Electrocatalytic and homogeneous approaches to conversion of CO ₂ to liquid fuels Benson, Eric E.; Kubiak, Clifford P.; Sathrum, Aaron J. Chem. Soc. Rev., Vol. 38, Issue 1 https://doi.org/10.1039/B804323J	journal	January 2009
Molecular Approaches to the Photocatalytic Reduction of Carbon Dioxide for Solar Fuels Morris, Amanda J.; Meyer, Gerald J.; Fujita, Etsuko Accounts of Chemical Research, Vol. 42, Issue 12 https://doi.org/10.1021/ar9001679	journal	December 2009
Advances in molecular photocatalytic and electrocatalytic CO2 reduction Windle, Christopher D.; Perutz, Robin N. Coordination Chemistry Reviews, Vol. 256, Issue 21-22 https://doi.org/10.1016/j.ccr.2012.03.010	journal	November 2012
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels Qiao, Jinli; Liu, Yuyu; Hong, Feng Chem. Soc. Rev., Vol. 43, Issue 2 https://doi.org/10.1039/C3CS60323G	journal	January 2014
A review on the electrochemical reduction of CO2 in fuel cells, metal electrodes and molecular catalysts Lim, Rern Jern; Xie, Mingshi; Sk, Mahasin Alam Catalysis Today, Vol. 233 https://doi.org/10.1016/j.cattod.2013.11.037	journal	September 2014
Recent advances in the photocatalytic conversion of carbon dioxide to fuels with water and/or hydrogen using solar energy and beyond Izumi, Yasuo Coordination Chemistry Reviews, Vol. 257, Issue 1 https://doi.org/10.1016/j.ccr.2012.04.018	journal	January 2013
Catalysis of the electrochemical reduction of carbon dioxide Costentin, Cyrille; Robert, Marc; Savéant, Jean-Michel Chem. Soc. Rev., Vol. 42, Issue 6 https://doi.org/10.1039/C2CS35360A	journal	January 2013
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO ₂ Fixation Appel, Aaron M.; Bercaw, John E.; Bocarsly, Andrew B. Chemical Reviews, Vol. 113, Issue 8 https://doi.org/10.1021/cr300463y	journal	June 2013
Transformation of Carbon Dioxide Sakakura, Toshiyasu; Choi, Jun-Chul; Yasuda, Hiroyuki Chemical Reviews, Vol. 107, Issue 6 https://doi.org/10.1021/cr068357u	journal	June 2007
Utilisation of CO2 as a chemical feedstock: opportunities and challenges Aresta, Michele; Dibenedetto, Angela Dalton Transactions, Issue 28 https://doi.org/10.1039/b700658f	journal	January 2007
Electrochemistry of cobalt tetraphenylporphyrin in aprotic media Truxillo, L. A.; Davis, D. G. Analytical Chemistry, Vol. 47, Issue 13 https://doi.org/10.1021/ac60363a052	journal	November 1975
Electrochemistry, spectroscopy, and reactivity of (meso-tetrakis(1-methylpyridinium-4-yl)porphinato)cobalt(III,II,I) in nonaqueous media Araullo-McAdams, C.; Kadish, K. M. Inorganic Chemistry, Vol. 29, Issue 15 https://doi.org/10.1021/ic00340a009	journal	July 1990
Electrocatalysis by metal phthalocyanines in the reduction of carbon dioxide Meshitsuka, Shunsuke; Ichikawa, Masaru; Tamaru, Kenzi Journal of the Chemical Society, Chemical Communications, Issue 5 https://doi.org/10.1039/c39740000158	journal	January 1974
Carbon Dioxide Reduction at a Metal Phthalocyanine Catalyzed Carbon Electrode Kapusta, S. Journal of The Electrochemical Society, Vol. 131, Issue 7 https://doi.org/10.1149/1.2115882	journal	January 1984
Catalytic reduction of carbon dioxide at carbon electrodes modified with cobalt phthalocyanine Lieber, Charles M.; Lewis, Nathan S. Journal of the American Chemical Society, Vol. 106, Issue 17 https://doi.org/10.1021/ja00329a082	journal	August 1984
An in-situ ftir study of the electroreduction of Co2 by copc-coated edge graphite electrodes Christensen, P. A.; Hamnett, A.; Muir, A. V. G. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 241, Issue 1-2 https://doi.org/10.1016/0022-0728(88)85139-8	journal	February 1988
Electrocatalysis of metal phthalocyanine thin film prepared by the plasma-assisted deposition on a glassy carbon in the reduction of carbon dioxide Tanabe, Hiroyoshi; Ohno, Kazunori Electrochimica Acta, Vol. 32, Issue 7 https://doi.org/10.1016/0013-4686(87)90042-9	journal	July 1987
Electrocatalytic CO2 reduction by cobalt octabutoxyphthalocyanine coated on graphite electrode Abe, Toshiyuki; Taguchi, Fumio; Yoshida, Tsukasa Journal of Molecular Catalysis A: Chemical, Vol. 112, Issue 1 https://doi.org/10.1016/1381-1169(96)00242-7	journal	October 1996
Electrochemical CO ₂ Reduction Catalysed by Cobalt Octacyanophthalocyanine and its Mechanism Abe, Toshiyuki; Imaya, Hiroshi; Yoshida, Tsukasa Journal of Porphyrins and Phthalocyanines, Vol. 01, Issue 04 https://doi.org/10.1002/(SICI)1099-1409(199710)1:4<315::AID-JPP35>3.0.CO;2-V	journal	October 1997
Gas diffusion electrode of high performance Motoo, Satoshi; Watanabe, Masahiro; Furuya, Nagakazu Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 160, Issue 1-2 https://doi.org/10.1016/S0022-0728(84)80139-4	journal	January 1984
Use of gas-diffusion electrodes for high-rate electrochemical reduction of carbon dioxide. II. Reduction at metal phthalocyanine-impregnated electrodes Mahmood, M. N.; Masheder, D.; Harty, C. J. Journal of Applied Electrochemistry, Vol. 17, Issue 6 https://doi.org/10.1007/BF01023606	journal	November 1987
Electroreduction of carbon dioxide on gas-diffusion electrodes modified by metal phthalocyanines Furuya, Nagakazu; Matsui, Kuniyasu Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 271, Issue 1-2 https://doi.org/10.1016/0022-0728(89)80074-9	journal	January 1989
Electroreduction of carbon dioxide by metal phthalocyanines Furuya, Nagakazu; Koide, Shoichiro Electrochimica Acta, Vol. 36, Issue 8 https://doi.org/10.1016/0013-4686(91)80010-6	journal	January 1991
Electrochemical reduction of CO2 at metal-porphyrin supported gas diffusion electrodes under high pressure CO2 Sonoyama, Noriyuki; Kirii, Masakazu; Sakata, Tadayoshi Electrochemistry Communications, Vol. 1, Issue 6 https://doi.org/10.1016/S1388-2481(99)00041-7	journal	June 1999
Electrochemical Reduction of CO[sub 2] with Transition Metal Phthalocyanine and Porphyrin Complexes Supported on Activated Carbon Fibers Magdesieva, T. V.; Yamamoto, T.; Tryk, D. A. Journal of The Electrochemical Society, Vol. 149, Issue 6 https://doi.org/10.1149/1.1475690	journal	January 2002
Rotating ring-disk electrode analysis of CO2 reduction electrocatalyzed by a cobalt tetramethylpyridoporphyrazine on the disk and detected as CO on a platinum ring Zhang, Jiujun; Pietro, William J.; Lever, A. B. P. Journal of Electroanalytical Chemistry, Vol. 403, Issue 1-2 https://doi.org/10.1016/0022-0728(95)04270-9	journal	February 1996
Microbial Fuel Cells: Methodology and Technology Logan, Bruce E.; Hamelers, Bert; Rozendal, René Environmental Science & Technology, Vol. 40, Issue 17, p. 5181-5192 https://doi.org/10.1021/es0605016	journal	September 2006
Electrochemical Reduction of Carbon Dioxide in an MFC–MEC System with a Layer-by-Layer Self-Assembly Carbon Nanotube/Cobalt Phthalocyanine Modified Electrode Zhao, Huazhang; Zhang, Yan; Zhao, Bin Environmental Science & Technology, Vol. 46, Issue 9 https://doi.org/10.1021/es300186f	journal	April 2012
Electrodes modified with iron porphyrin and carbon nanotubes: application to CO2 reduction and mechanism of synergistic electrocatalysis Zhao, Hua-Zhang; Chang, Ying-Yue; Liu, Chuan Journal of Solid State Electrochemistry, Vol. 17, Issue 6 https://doi.org/10.1007/s10008-013-2027-1	journal	February 2013
Reversible interconversion of carbon dioxide and formate by an electroactive enzyme Reda, T.; Plugge, C. M.; Abram, N. J. Proceedings of the National Academy of Sciences, Vol. 105, Issue 31, p. 10654-10658 https://doi.org/10.1073/pnas.0801290105	journal	July 2008
The Surface Trans Effect: Influence of Axial Ligands on the Surface Chemical Bonds of Adsorbed Metalloporphyrins Hieringer, Wolfgang; Flechtner, Ken; Kretschmann, Andreas Journal of the American Chemical Society, Vol. 133, Issue 16 https://doi.org/10.1021/ja1093502	journal	April 2011
Discriminative Response of Surface-Confined Metalloporphyrin Molecules to Carbon and Nitrogen Monoxide Seufert, Knud; Auwärter, Willi; Barth, Johannes V. Journal of the American Chemical Society, Vol. 132, Issue 51 https://doi.org/10.1021/ja1054884	journal	December 2010
Site-specific electronic and geometric interface structure of Co-tetraphenyl-porphyrin layers on Ag(111) Auwärter, Willi; Seufert, Knud; Klappenberger, Florian Physical Review B, Vol. 81, Issue 24 https://doi.org/10.1103/PhysRevB.81.245403	journal	June 2010
Chemical Fingerprints of Large Organic Molecules in Scanning Tunneling Microscopy: Imaging Adsorbate−Substrate Coupling of Metalloporphyrins Buchner, Florian; Warnick, Karl-Georg; Wölfle, Thorsten The Journal of Physical Chemistry C, Vol. 113, Issue 37 https://doi.org/10.1021/jp904680c	journal	August 2009
Adsorption of cobalt (II) octaethylporphyrin and 2H-octaethylporphyrin on Ag(111): new insight into the surface coordinative bond Bai, Yun; Buchner, Florian; Kellner, Ina New Journal of Physics, Vol. 11, Issue 12 https://doi.org/10.1088/1367-2630/11/12/125004	journal	December 2009
Interaction of Cobalt(II) Tetraarylporphyrins with a Ag(111) Surface Studied with Photoelectron Spectroscopy Lukasczyk, Thomas; Flechtner, Ken; Merte, Lindsay R. The Journal of Physical Chemistry C, Vol. 111, Issue 7 https://doi.org/10.1021/jp0652345	journal	January 2007
NO-Induced Reversible Switching of the Electronic Interaction between a Porphyrin-Coordinated Cobalt Ion and a Silver Surface Flechtner, Ken; Kretschmann, Andreas; Steinrück, Hans-Peter Journal of the American Chemical Society, Vol. 129, Issue 40 https://doi.org/10.1021/ja0756725	journal	October 2007
Electrocatalytic activity of CoII TPP-pyridine complex modified carbon electrode for CO2 reduction Atoguchi, Takashi; Aramata, Akiko; Kazusaka, Akio Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 318, Issue 1-2 https://doi.org/10.1016/0022-0728(91)85312-D	journal	November 1991
The electroreduction of carbon dioxide by macrocyclic cobalt complexes chemically modified on a glassy carbon electrode Aga, Hirohide; Aramata, Akiko; Hisaeda, Yoshio Journal of Electroanalytical Chemistry, Vol. 437, Issue 1-2 https://doi.org/10.1016/S0022-0728(97)00386-0	journal	November 1997
Aminopyridyl cation radical method for bridging between metal complex and glassy carbon: cobalt(II) tetraphenylporphyrin bonded on glassy carbon for enhancement of CO2 electroreduction Tanaka, Hideaki; Aramata, Akiko Journal of Electroanalytical Chemistry, Vol. 437, Issue 1-2 https://doi.org/10.1016/S0022-0728(97)00080-6	journal	November 1997
A Supramolecular Cobalt–Porphyrin-modified Electrode, toward the Electroreduction of Co₂ RamÍRez, Galo; Lucero, Mauricio; Riquelme, Andrea Journal of Coordination Chemistry, Vol. 57, Issue 3, p. 249-255 https://doi.org/10.1080/00958970410001677051	journal	February 2004
Enhanced photoelectrochemical catalysis of CO2 reduction mediated by a supramolecular electrode of packed CoII(tetrabenzoporphyrin) Ramírez, G.; Ferraudi, G.; Chen, Y. -Y. Inorganica Chimica Acta, Vol. 362, Issue 1 https://doi.org/10.1016/j.ica.2007.08.024	journal	January 2009
Selective electroacatalysis for CO2 reduction in the aqueous phase using cobalt phthalocyanine/poly-4-vinylpyridine modified electrodes Yoshida, Tsukasa; Kamato, Kazuhiro; Tsukamoto, Masaaki Journal of Electroanalytical Chemistry, Vol. 385, Issue 2 https://doi.org/10.1016/0022-0728(94)03762-R	journal	April 1995
Factors affecting selective electrocatalytic co2 reduction with cobalt phthalocyanine incorporated in a polyvinylpyridine membrane coated on a graphite electrode Abe, Toshiyuki; Yoshida, Tsukasa; Tokita, Sumio Journal of Electroanalytical Chemistry, Vol. 412, Issue 1-2 https://doi.org/10.1016/0022-0728(96)04631-1	journal	August 1996
Electrocatalytic Reduction of Carbon Dioxide by Cobalt-Phthalocyanine-Incorporated Polypyrrole Zhang, Aijian; Zhang, Weimin; Lu, Jiaxing Electrochemical and Solid-State Letters, Vol. 12, Issue 8 https://doi.org/10.1149/1.3139529	journal	January 2009
Electrochemical reduction of CO2 mediated by poly-M-aminophthalocyanines (M=Co, Ni, Fe): poly-Co-tetraaminophthalocyanine, a selective catalyst Isaacs, M.; Armijo, F.; Ramírez, G. Journal of Molecular Catalysis A: Chemical, Vol. 229, Issue 1-2 https://doi.org/10.1016/j.molcata.2004.11.026	journal	March 2005
Electrocatalytic reduction of carbon dioxide on a cobalt tetrakis(4-aminophenyl)porphyrin modified electrode in BMImBF ₄ Quezada, Diego; Honores, Jessica; García, Macarena New J. Chem., Vol. 38, Issue 8 https://doi.org/10.1039/C4NJ00519H	journal	January 2014
Covalent Attachment of Catalyst Molecules to Conductive Diamond: CO ₂ Reduction Using “Smart” Electrodes Yao, Shu A.; Ruther, Rose E.; Zhang, Linghong Journal of the American Chemical Society, Vol. 134, Issue 38 https://doi.org/10.1021/ja304783j	journal	September 2012
Electrocatalytic Behavior of Tetrasulfonated Metal Phthalocyanines in the Reduction of Carbon Dioxide Hiratsuka, Kazuya; Takahashi, Katsuhiro; Sasaki, Hideo Chemistry Letters, Vol. 6, Issue 10 https://doi.org/10.1246/cl.1977.1137	journal	October 1977
Electrocatalytic Behavior of Metal Porphyrins in the Reduction of Carbon Dioxide Takahashi, Katsuhiro; Hiratsuka, Kazuya; Sasaki, Hideo Chemistry Letters, Vol. 8, Issue 4 https://doi.org/10.1246/cl.1979.305	journal	April 1979
Electroreduction of Dioxygen Using Co–Ru Dinuclear Porphyrin Catalyst in Nafion Film Imaoka, Takane; Nakazawa, Shinsuke; Yamamoto, Kimihisa Chemistry Letters, Vol. 30, Issue 5 https://doi.org/10.1246/cl.2001.412	journal	May 2001
Synergetic activation of carbon dioxide molecule using phenylazomethine dendrimers as a catalyst Imaoka, Takane; Tanaka, Reiko; Yamamoto, Kimihisa Journal of Polymer Science Part A: Polymer Chemistry, Vol. 44, Issue 17 https://doi.org/10.1002/pola.21611	journal	January 2006
Catalysis of the electrochemical reduction of carbon dioxide by iron(“0”) porphyrins Hammouche, M.; Lexa, D.; Savéant, J. M. Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 249, Issue 1-2 https://doi.org/10.1016/0022-0728(88)80372-3	journal	July 1988
Pendant Acid–Base Groups in Molecular Catalysts: H-Bond Promoters or Proton Relays? Mechanisms of the Conversion of CO ₂ to CO by Electrogenerated Iron(0)Porphyrins Bearing Prepositioned Phenol Functionalities Costentin, Cyrille; Passard, Guillaume; Robert, Marc Journal of the American Chemical Society, Vol. 136, Issue 33 https://doi.org/10.1021/ja506193v	journal	August 2014
Single electron transfer and nucleophilic substitution. Reaction of alkyl bromides with aromatic anion radicals and low-oxidation-state iron porphyrins Lexa, Doris.; Saveant, Jean Michel.; Su Khac Binh, . Journal of the American Chemical Society, Vol. 110, Issue 23 https://doi.org/10.1021/ja00231a006	journal	November 1988
Outer-sphere and inner-sphere processes in reductive elimination. Direct and indirect electrochemical reduction of vicinal dibromoalkanes Lexa, Doris; Saveant, Jean Michel; Schaefer, Hans J. Journal of the American Chemical Society, Vol. 112, Issue 17 https://doi.org/10.1021/ja00173a002	journal	August 1990
Chemical catalysis of electrochemical reactions. Homogeneous catalysis of the electrochemical reduction of carbon dioxide by iron("0") porphyrins. Role of the addition of magnesium cations Hammouche, Mohamed; Lexa, Doris; Momenteau, Michel Journal of the American Chemical Society, Vol. 113, Issue 22 https://doi.org/10.1021/ja00022a038	journal	October 1991
Catalysis of the Electrochemical Reduction of Carbon Dioxide by Iron(0) Porphyrins. Synergistic Effect of Lewis Acid Cations Bhugun, Iqbal; Lexa, Doris; Savéant, Jean-Michel The Journal of Physical Chemistry, Vol. 100, Issue 51 https://doi.org/10.1021/jp9618486	journal	January 1996
Ultraefficient selective homogeneous catalysis of the electrochemical reduction of carbon dioxide by an iron(0) porphyrin associated with a weak Broensted acid cocatalyst Bhugun, Iqbal; Lexa, Doris; Saveant, Jean-Michel Journal of the American Chemical Society, Vol. 116, Issue 11 https://doi.org/10.1021/ja00090a068	journal	June 1994
Catalysis of the Electrochemical Reduction of Carbon Dioxide by Iron(0) Porphyrins: Synergystic Effect of Weak Brönsted Acids Bhugun, Iqbal; Lexa, Doris; Savéant, Jean-Michel Journal of the American Chemical Society, Vol. 118, Issue 7 https://doi.org/10.1021/ja9534462	journal	January 1996
Proton-Coupled Electron Transfer Cleavage of Heavy-Atom Bonds in Electrocatalytic Processes. Cleavage of a C–O Bond in the Catalyzed Electrochemical Reduction of CO ₂ Costentin, Cyrille; Drouet, Samuel; Passard, Guillaume Journal of the American Chemical Society, Vol. 135, Issue 24 https://doi.org/10.1021/ja4030148	journal	June 2013
A Local Proton Source Enhances CO ₂ Electroreduction to CO by a Molecular Fe Catalyst Costentin, Cyrille; Drouet, Samuel; Robert, Marc Science, Vol. 338, Issue 6103 https://doi.org/10.1126/science.1224581	journal	October 2012
The roles of the first and second coordination spheres in the design of molecular catalysts for H ₂ production and oxidation Rakowski DuBois, M.; DuBois, Daniel L. Chem. Soc. Rev., Vol. 38, Issue 1 https://doi.org/10.1039/B801197B	journal	January 2009
Reversible hydrogen storage using CO₂ and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures Hull, Jonathan F.; Himeda, Yuichiro; Wang, Wan-Hui Nature Chemistry, Vol. 4, Issue 5, p. 383-388 https://doi.org/10.1038/nchem.1295	journal	March 2012
Interconversion of CO2 and formic acid by bio-inspired Ir complexes with pendent bases Fujita, Etsuko; Muckerman, James T.; Himeda, Yuichiro Biochimica et Biophysica Acta (BBA) - Bioenergetics, Vol. 1827, Issue 8-9 https://doi.org/10.1016/j.bbabio.2012.11.004	journal	August 2013
Iron Porphyrin-Catalyzed Reduction of CO ₂ . Photochemical and Radiation Chemical Studies Grodkowski, J.; Behar, D.; Neta, P. The Journal of Physical Chemistry A, Vol. 101, Issue 3 https://doi.org/10.1021/jp9628139	journal	January 1997
Photoinduced decarbonylation from carbonyliron tetraphenylporphyrin in ethanol: effects of axial imidazole studied by laser flash photolysis Hoshino, Mikio; Ueda, Koichi; Takahashi, Makoto The Journal of Physical Chemistry, Vol. 96, Issue 22 https://doi.org/10.1021/j100201a034	journal	October 1992
Cobalt Porphyrin Catalyzed Reduction of CO ₂ . Radiation Chemical, Photochemical, and Electrochemical Studies Behar, D.; Dhanasekaran, T.; Neta, P. The Journal of Physical Chemistry A, Vol. 102, Issue 17 https://doi.org/10.1021/jp9807017	journal	April 1998
One-electron transfer reactions involving zinc and cobalt porphyrins in aqueous solutions Neta, P. The Journal of Physical Chemistry, Vol. 85, Issue 24 https://doi.org/10.1021/j150624a030	journal	November 1981
Spectrophotometric and kinetic studies of the radiolytic reduction of several pyridylporphyrins and their metal complexes Baral, S.; Neta, P.; Hambright, P. Radiation Physics and Chemistry (1977), Vol. 24, Issue 2 https://doi.org/10.1016/0146-5724(84)90059-1	journal	January 1984
One- and two-electron reduction of aluminum and tin pyridylporphyrins. A kinetic spectrophotometric study Baral, S.; Hambright, P.; Neta, P. The Journal of Physical Chemistry, Vol. 88, Issue 8 https://doi.org/10.1021/j150652a031	journal	April 1984
The Electrochemical Evaluation of the Metal-Carbon Bond Energies (−Δ G _BF ) of Alkylated Iron and Cobalt Porphyrins [( por ) M - R ] Qiu, Aimin; Sawyer, Donald T. Journal of Porphyrins and Phthalocyanines, Vol. 01, Issue 02 https://doi.org/10.1002/(SICI)1099-1409(199704)1:2<125::AID-JPP15>3.0.CO;2-X	journal	April 1997
p -Terphenyl-Sensitized Photoreduction of CO ₂ with Cobalt and Iron Porphyrins. Interaction between CO and Reduced Metalloporphyrins Dhanasekaran, T.; Grodkowski, J.; Neta, P. The Journal of Physical Chemistry A, Vol. 103, Issue 38 https://doi.org/10.1021/jp991423u	journal	September 1999
Photocatalysis of oligo(p-phenylenes): photochemical reduction of carbon dioxide with triethylamine Matsuoka, Shinjiro; Kohzuki, Takao; Pac, Chyongjin The Journal of Physical Chemistry, Vol. 96, Issue 11 https://doi.org/10.1021/j100190a057	journal	May 1992
Cobalt Corrin Catalyzed Photoreduction of CO ₂ Grodkowski, J.; Neta, P. The Journal of Physical Chemistry A, Vol. 104, Issue 9 https://doi.org/10.1021/jp9939569	journal	March 2000
Reduction of Cobalt and Iron Phthalocyanines and the Role of the Reduced Species in Catalyzed Photoreduction of CO ₂ Grodkowski, J.; Dhanasekaran, T.; Neta, P. The Journal of Physical Chemistry A, Vol. 104, Issue 48 https://doi.org/10.1021/jp002709y	journal	December 2000
Reduction of Cobalt and Iron Corroles and Catalyzed Reduction of CO ₂ Grodkowski, Jan; Neta, Pedatsur; Fujita, Etsuko The Journal of Physical Chemistry A, Vol. 106, Issue 18 https://doi.org/10.1021/jp013668o	journal	May 2002
Carbon dioxide activation by cobalt(I) macrocycles: factors affecting carbon dioxide and carbon monoxide binding Fujita, Etsuko; Creutz, Carol; Sutin, Norman Journal of the American Chemical Society, Vol. 113, Issue 1 https://doi.org/10.1021/ja00001a048	journal	January 1991
Electrochemical CO2 reduction catalysed by cobalt octacyanophthalocyanine and its mechanism Abe, Toshiyuki; Imaya, Hiroshi; Yoshida, Tsukasa Journal of Porphyrins and Phthalocyanines, Vol. 1, Issue 4 https://doi.org/10.1002/(sici)1099-1409(199710)1:4<315::aid-jpp35>3.3.co;2-m	journal	October 1997
Site-specific electronic and geometric interface structure of Co-tetraphenyl-porphyrin layers on Ag(111) Auwärter, W.; Seufert, K.; Klappenberger, F. American Physical Society https://doi.org/10.5167/uzh-36018	text	January 2010
Transformation of Carbon Dioxide Sakakura, Toshiyasu; Choi, Jun-Chul; Yasuda, Hiroyuki ChemInform, Vol. 38, Issue 36 https://doi.org/10.1002/chin.200736261	journal	September 2007

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Electrochemical CO ₂ and Proton Reduction by a Co(dithiacyclam) Complex: Electrochemical CO ₂ and Proton Reduction by a Co(dithiacyclam) Complex Iffland, Linda; Siegmund, Daniel; Apfel, Ulf-Peter Zeitschrift für anorganische und allgemeine Chemie, Vol. 646, Issue 13 https://doi.org/10.1002/zaac.201900356	journal	February 2020
Conversion of Carbon Dioxide into Formic Acid Fegade, Umesh; Jethave, Ganesh Conversion of Carbon Dioxide into Hydrocarbons Vol. 2 Technology, p. 91-110 https://doi.org/10.1007/978-3-030-28638-5_4	book	November 2019
Heterogeneous molecular catalysts for electrocatalytic CO2 reduction Corbin, Nathan; Zeng, Joy; Williams, Kindle Nano Research, Vol. 12, Issue 9 https://doi.org/10.1007/s12274-019-2403-y	journal	May 2019
Highly selective and active CO2 reduction electrocatalysts based on cobalt phthalocyanine/carbon nanotube hybrid structures Zhang, Xing; Wu, Zishan; Zhang, Xiao Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14675	journal	March 2017
CO2 electrochemical catalytic reduction with a highly active cobalt phthalocyanine Wang, Min; Torbensen, Kristian; Salvatore, Danielle Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-11542-w	journal	August 2019
Role of 2 ^nd sphere H-bonding residues in tuning the kinetics of CO ₂ reduction to CO by iron porphyrin complexes Sen, Pritha; Mondal, Biswajit; Saha, Dibyajyoti Dalton Transactions, Vol. 48, Issue 18 https://doi.org/10.1039/c8dt03850c	journal	January 2019
Synthesis and investigation of tetraphenyltetrabenzoporphyrins for electrocatalytic reduction of carbon dioxide Apaydin, Dogukan H.; Portenkirchner, Engelbert; Jintanalert, Pichayada Sustainable Energy & Fuels, Vol. 2, Issue 12 https://doi.org/10.1039/c8se00422f	journal	January 2018
Mild pyrolysis of ionic self-assembled cobalt porphyrins on carbon toward efficient electrochemical conversion of CO ₂ to CO Zhang, Xue; Liu, Huiyuan; Qin, Jiaqi Chemical Communications, Vol. 55, Issue 39 https://doi.org/10.1039/c9cc02156f	journal	January 2019
Structural features of molecular electrocatalysts in multi-electron redox processes for renewable energy – recent advances Das, Biswanath; Thapper, Anders; Ott, Sascha Sustainable Energy & Fuels, Vol. 3, Issue 9 https://doi.org/10.1039/c9se00280d	journal	January 2019
Heterogenization of a macrocyclic cobalt complex for photocatalytic CO ₂ reduction Jin, Tong; Liu, Chao; Li, Gonghu Journal of Coordination Chemistry, Vol. 69, Issue 11-13 https://doi.org/10.1080/00958972.2016.1190452	journal	June 2016
Zn(II) porphyrin-based photocatalytic synthesis of Cu nanoparticles for electrochemical reduction of CO 2 Zhang, Siyu; Zhang, Xue; Liu, Huiyuan Journal of Porphyrins and Phthalocyanines, Vol. 22, Issue 05 https://doi.org/10.1142/s1088424618500293	journal	April 2018
Synthesis, electrochemical and spectroelectrochemical characterization of iron(III) tetraarylporphyrins containing four β,β′-butano and β,β′-benzo fused rings Xu, Weijie; Fang, Yuanyuan; Ou, Zhongping Journal of Porphyrins and Phthalocyanines, Vol. 22, Issue 06 https://doi.org/10.1142/s1088424618500517	journal	June 2018
Vibrational structure analysis of cobalt fluoro-porphyrin surface coatings on gallium phosphide Khusnutdinova, Diana; Beiler, Anna M.; Wadsworth, Brian L. Journal of Porphyrins and Phthalocyanines, Vol. 22, Issue 06 https://doi.org/10.1142/s1088424618500906	journal	June 2018
Two‐Dimensional Metal–Organic Framework Nanosheets with Cobalt‐Porphyrins for High‐Performance CO ₂ Electroreduction Zhang, Xiang‐Da; Hou, Shu‐Zhen; Wu, Jian‐Xiang Chemistry – A European Journal, Vol. 26, Issue 7 https://doi.org/10.1002/chem.201904072	journal	January 2020
Superstructured metallocorroles for electrochemical CO ₂ reduction Sinha, Woormileela; Mahammed, Atif; Fridman, Natalia Chemical Communications, Vol. 55, Issue 79 https://doi.org/10.1039/c9cc06645d	journal	January 2019

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