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Title: Metal-assisted chemical etch porous silicon formation method

Patent ·
OSTI ID:1175032

A thin discontinuous layer of metal such as Au, Pt, or Au/Pd is deposited on a silicon surface. The surface is then etched in a solution including HF and an oxidant for a brief period, as little as a couple seconds to one hour. A preferred oxidant is H.sub.2 O.sub.2. Morphology and light emitting properties of porous silicon can be selectively controlled as a function of the type of metal deposited, Si doping type, silicon doping level, and/or etch time. Electrical assistance is unnecessary during the chemical etching of the invention, which may be conducted in the presence or absence of illumination.

Research Organization:
Univ. of Illinois at Urbana-Champaign, IL (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG02-91-ER-45439
Assignee:
The Board of Trustees of the University of Illinois (Urbana, IL)
Patent Number(s):
6,790,785
Application Number:
09/662,682
OSTI ID:
1175032
Country of Publication:
United States
Language:
English

References (4)

Chemical etching of porous silicon in diluted hydrofluoric acid journal December 1998
A role of illumination during etching to porous silicon oxidation journal August 1999
Effects of Wet Etching on Photoluminescence of Porous Silicon journal January 2000
Preparation of thin porous silicon layers by stain etching journal April 1997

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