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Title: Method and apparatus for thermal swing adsorption and thermally-enhanced pressure swing adsorption

Patent ·
OSTI ID:1174885

The present invention provides compact adsorption systems that are capable of rapid temperature swings and rapid cycling. Novel methods of thermal swing adsorption and thermally-enhanced pressure swing adsorption are also described. In some aspects of the invention, a gas is passed through the adsorbent thus allowing heat exchangers to be very close to all portions of the adsorbent and utilize less space. In another aspect, the adsorption media is selectively heated, thus reducing energy costs. Methods and systems for gas adsorption/desorption having improved energy efficiency with capability of short cycle times are also described. In another aspect, the apparatus or methods utilize heat exchange channels of varying lengths that have volumes controlled to provide equal heat fluxes. Methods of fuel cell startup are also described. Advantages of the invention include the ability to use (typically) 30-100 times less adsorbent compared to conventional systems.

Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC06-76RL01830
Assignee:
Battelle Memorial Institute (Richland, WA)
Patent Number(s):
6,746,515
Application Number:
10/135,891
OSTI ID:
1174885
Country of Publication:
United States
Language:
English

References (5)

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Design, life testing, and future designs of cryogenic hydride refrigeration systems journal April 1985
Phoebus-J�lich: An autonomous energy supply system comprising photovoltaics, electrolytic hydrogen, fuel cell journal April 1998
Development of a metal hydride compressor journal February 1983