Convergent synthesis of multiporphyrin light-harvesting rods
Patent
·
OSTI ID:1174435
The present invention provides a convergent method for the synthesis of light harvesting rods. The rods are oligomers of the formula A.sup.1 (A.sup.b+1).sub.b, wherein b is at least 1, A.sup.1 through A.sup.b+1 are covalently coupled rod segments, and each rod segment A.sup.1 through A.sup.1+b comprises a compound of the formula X.sup.1 (X.sup.m+1).sub.m wherein m is at least 1 and X.sup.1 through X.sup.m+1 are covalently coupled porphyrinic macrocycles. Light harvesting arrays and solar cells containing such light harvesting rods are also described, along with intermediates useful in such methods and rods produced by such methods.
- Research Organization:
- North Carolina State University, Raleigh, NC (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- FG02-96ER14632
- Assignee:
- North Carolina State University (Raleigh, NC)
- Patent Number(s):
- 6,603,070
- Application Number:
- 09/939,010
- OSTI ID:
- 1174435
- Country of Publication:
- United States
- Language:
- English
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