Hydrogen production using ammonia borane

Hamilton, Charles W; Baker, R. Thomas; Semelsberger, Troy A; Shrestha, Roshan P

Title: Hydrogen production using ammonia borane

Patent · Tue Dec 24 00:00:00 EST 2013

OSTI ID:1111472

Hamilton, Charles W; Baker, R. Thomas; Semelsberger, Troy A; Shrestha, Roshan P

Hydrogen ("H.sub.2") is produced when ammonia borane reacts with a catalyst complex of the formula L.sub.nM-X wherein M is a base metal such as iron, X is an anionic nitrogen- or phosphorus-based ligand or hydride, and L is a neutral ancillary ligand that is a neutral monodentate or polydentate ligand.

View Patent

Cite

Export

Save

Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC52-06NA25396

Assignee:: Los Alamos National Security, LLC (Los Alamos, NM)

Patent Number(s):: 8,613,902

Application Number:: 12/416,835

OSTI ID:: 1111472

Country of Publication:: United States

Language:: English

References (12)

Efficient Catalysis of Ammonia Borane Dehydrogenation Denney, Melanie C.; Pons, Vincent; Hebden, Travis J. Journal of the American Chemical Society, Vol. 128, Issue 37 https://doi.org/10.1021/ja062419g	journal	September 2006
Amineborane-Based Chemical Hydrogen Storage: Enhanced Ammonia Borane Dehydrogenation in Ionic Liquids Bluhm, Martin E.; Bradley, Mark G.; Butterick, Robert Journal of the American Chemical Society, Vol. 128, Issue 24 https://doi.org/10.1021/ja062085v	journal	June 2006
Process for preparing optically active cyclohexanol derivatives Murayama, Toshiyuki; Matsumoto, Takaji; Miura, Takashi https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5756863 US Patent Document 5,756,863	patent	May 1998
Acid Initiation of Ammonia–Borane Dehydrogenation for Hydrogen Storage Stephens, Frances H.; Baker, R. Tom; Matus, Myrna H. Angewandte Chemie International Edition, Vol. 46, Issue 5 https://doi.org/10.1002/anie.200603285	journal	January 2007
Thermal decomposition of B–N–H compounds investigated by using combined thermoanalytical methods Baitalow, F.; Baumann, J.; Wolf, G. Thermochimica Acta, Vol. 391, Issue 1-2 https://doi.org/10.1016/S0040-6031(02)00173-9	journal	August 2002
4-methoxybiphenyl hydrazone derivatives Park, Sheldon B.; Chee, Gaik-Lean; Dekeyser, Mark A. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6706895 US Patent Document 6,706,895	patent	March 2004
Base Metal Catalyzed Dehydrogenation of Ammonia−Borane for Chemical Hydrogen Storage Keaton, Richard J.; Blacquiere, Johanna M.; Baker, R. Tom Journal of the American Chemical Society, Vol. 129, Issue 7 https://doi.org/10.1021/ja066860i	journal	February 2007
Transition Metal-Catalyzed Formation of Boron−Nitrogen Bonds: Catalytic Dehydrocoupling of Amine-Borane Adducts to Form Aminoboranes and Borazines Jaska, Cory A.; Temple, Karen; Lough, Alan J. Journal of the American Chemical Society, Vol. 125, Issue 31 https://doi.org/10.1021/ja030160l	journal	August 2003
The Metal−Ligand Bifunctional Catalysis: A Theoretical Study on the Ruthenium(II)-Catalyzed Hydrogen Transfer between Alcohols and Carbonyl Compounds Yamakawa, Masashi; Ito, Hisashi; Noyori, Ryoji Journal of the American Chemical Society, Vol. 122, Issue 7 https://doi.org/10.1021/ja991638h	journal	February 2000
Hydrogen storage material and related processes Soloveichik, Grigorii Lev; Andrus, Matthew John https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7754641 US Patent Document 7,754,641	patent	July 2010
Ruthenium-Catalyzed Dehydrogenation of Ammonia Boranes Blaquiere, Nicole; Diallo-Garcia, Sarah; Gorelsky, Serge I. Journal of the American Chemical Society, Vol. 130, Issue 43 https://doi.org/10.1021/ja804235t	journal	October 2008
Ruthenium Complexes with Cooperative PNP Ligands: Bifunctional Catalysts for the Dehydrogenation of Ammonia-Borane Käß, Martina; Friedrich, Anja; Drees, Markus Angewandte Chemie International Edition, Vol. 48, Issue 5 https://doi.org/10.1002/anie.200805108	journal	January 2009

Similar Records

Organo-Lewis acids as cocatalysts in cationic metallocene polymerization catalysis. Unusual characteristics of sterically encumbered tris(perfluorobiphenyl)borane

Journal Article · Wed Dec 11 00:00:00 EST 1996 · Journal of the American Chemical Society · OSTI ID:1111472

Chen, Y X; Stern, C L; Yang, S; +1 more

Chemical Hydrogen Storage Using Polyhedral Borane Anions and Aluminum-Ammonia-Borane Complexes

Technical Report · Fri Oct 01 00:00:00 EDT 2010 · OSTI ID:1111472

Hawthorne, M Frederick; Jalisatgi, Satish S; Safronov, Alexander V; +2 more

Catalytic ionic hydrogenation of ketones using tungsten or molybdenum catalysts with increased lifetimes

Patent · Tue Sep 02 00:00:00 EDT 2003 · OSTI ID:1111472

Bullock, R. Morris; Kimmich, Barbara F. M.; Fagan, Paul J.; +1 more

Related Subjects

08 HYDROGEN

Title: Hydrogen production using ammonia borane

Citation Formats

References (12)

Similar Records

Related Subjects