Coordination Chemistry in magnesium battery electrolytes: how ligands affect their performance

Shao, Yuyan; Liu, Tianbiao L.; Li, Guosheng; Gu, Meng; Nie, Zimin; Engelhard, Mark H.; Xiao, Jie; Lu, Dongping; Wang, Chong M.; Zhang, Jiguang; Liu, Jun

doi:10.1038/srep03130

Title: Coordination Chemistry in magnesium battery electrolytes: how ligands affect their performance

Journal Article · Mon Nov 04 00:00:00 EST 2013 · Scientific Reports

DOI:https://doi.org/10.1038/srep03130· OSTI ID:1107486

Shao, Yuyan ^[1]; Liu, Tianbiao L. ^[1]; Li, Guosheng ^[1]; Gu, Meng ^[1]; Nie, Zimin ^[1]; Engelhard, Mark H. ^[1]; Xiao, Jie ^[1]; Lu, Dongping ^[1]; Wang, Chong M. ^[1]; Zhang, Jiguang ^[1]; Liu, Jun ^[1]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Magnesium battery is potentially a safe, cost-effective, and high energy density technology for large scale energy storage. However, the development of magnesium battery has been hindered by the limited performance and the lack of fundamental understandings of electrolytes. Here, we present a coordination chemistry study of Mg(BH₄)₂ in ethereal solvents. The O donor denticity, i.e. ligand strength of the ethereal solvents which act as ligands to form solvated Mg complexes, plays a significant role in enhancing coulombic efficiency of the corresponding solvated Mg complex electrolytes. A new and safer electrolyte is developed based on Mg(BH4)2, diglyme and optimized LiBH4 additive. The new electrolyte demonstrates 100% coulombic efficiency, no dendrite formation, and stable cycling performance with the cathode capacity retention of ~90% for 300 cycles in a prototype magnesium battery.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Environmental Molecular Sciences Laboratory (EMSL)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1107486

Report Number(s):: PNNL-SA-97112; 47476; KC0203020; KC0208010

Journal Information:: Scientific Reports, Vol. 3; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 144 works

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