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Title: Desulfurization apparatus and method

Patent ·
OSTI ID:1084197

A method and system for desulfurization comprising first and second metal oxides; a walled enclosure having an inlet and an exhaust for the passage of gas to be treated; the first and second metal oxide being combinable with hydrogen sulfide to produce a reaction comprising a sulfide and water; the first metal oxide forming a first layer and the second metal oxide forming a second layer within the walled surroundings; the first and second layers being positioned so the first layer removes the bulk amount of the hydrogen sulfide from the treated gas prior to passage through the second layer, and the second layer removes substantially all of the remaining hydrogen sulfide from the treated gas; the first metal oxide producing a stoichiometrical capacity in excess of 500 mg sulfur/gram; the second metal oxide reacts with the hydrogen sulfide more favorably but has a stoichometrical capacity which is less than the first reactant; whereby the optimal amount by weight of the first and second metal oxides is achieved by utilizing two to three units by weight of the first metal oxide for every unit of the second metal oxide.

Research Organization:
DOESC (USDOE Office of Science (SC) (United States))
Sponsoring Organization:
USDOE
Assignee:
The United States of America as represented by the Secretary of the Army (Washington, DC)
Patent Number(s):
8,465,712
Application Number:
12/617,197
OSTI ID:
1084197
Country of Publication:
United States
Language:
English

References (9)

High-capacity sulfur adsorbent bed and gas desulfurization method patent June 2006
Process for removing sulfur oxides from a gas patent September 1983
Catalytic removal of sulfur dioxide from flue gas patent December 1998
Catalyzed diesel particulate matter filter with improved thermal stability patent November 2006
Sulfide removal process patent August 1976
Desulfurization and novel compositions for same patent July 2005
Reduction of spalling in mixed metal oxide desulfurization sorbents by addition of a large promoter metal oxide patent December 1997
Electrochemical solid-state device comprising b-site rich lanthanum calcium manganite patent November 2004
Cerium oxide solutions for the desulfurization of gases patent July 1994