Block coordination copolymers

Koh, Kyoung Moo; Wong-Foy, Antek G.; Matzger, Adam J.; Benin, Annabelle I.; Willis, Richard R.

Title: Block coordination copolymers

Patent · Tue Dec 04 00:00:00 EST 2012

OSTI ID:1082482

Koh, Kyoung Moo; Wong-Foy, Antek G.; Matzger, Adam J.; Benin, Annabelle I.; Willis, Richard R.

The present invention provides compositions of crystalline coordination copolymers wherein multiple organic molecules are assembled to produce porous framework materials with layered or core-shell structures. These materials are synthesized by sequential growth techniques such as the seed growth technique. In addition, the invention provides a simple procedure for controlling functionality.

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Research Organization:: National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: FC26-07NT42121

Assignee:: UOP LLC (Des Plaines, IL) ; The Regents of the University of Michigan (Ann Arbor, MI)

Patent Number(s):: 8,324,323

Application Number:: 12/478,018

OSTI ID:: 1082482

Country of Publication:: United States

Language:: English

References (13)

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Synthesis, X-ray Crystal Structures, and Gas Sorption Properties of Pillared Square Grid Nets Based on Paddle-Wheel Motifs: Implications for Hydrogen Storage in Porous Materials Chun, Hyungphil; Dybtsev, Danil N.; Kim, Hyunuk Chemistry - A European Journal, Vol. 11, Issue 12 https://doi.org/10.1002/chem.200401201	journal	June 2005
Functional Porous Coordination Polymers Kitagawa, Susumu; Kitaura, Ryo; Noro, Shin-ichiro Angewandte Chemie International Edition, Vol. 43, Issue 18, p. 2334-2375 https://doi.org/10.1002/anie.200300610	journal	April 2004
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A Crystalline Mesoporous Coordination Copolymer with High Microporosity Koh, Kyoungmoo; Wong-Foy, Antek G.; Matzger, Adam J. Angewandte Chemie International Edition, Vol. 47, Issue 4, p. 677-680 https://doi.org/10.1002/anie.200705020	journal	January 2008
Systematic Functionalization of a Metal−Organic Framework via a Postsynthetic Modification Approach Tanabe, Kristine K.; Wang, Zhenqiang; Cohen, Seth M. Journal of the American Chemical Society, Vol. 130, Issue 26, p. 8508-8517 https://doi.org/10.1021/ja801848j	journal	July 2008

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