Iron Corrosion Observations: Pu(VI)-Fe Reduction Studies
- Los Alamos National Laboratory
Iron and Pu Reduction: (1) Very different appearances in iron reaction products were noted depending on pH, brine and initial iron phase; (2) Plutonium was associated with the Fe phases; (3) Green rust was often noted at the higher pH; (4) XANES established the green rust to be an Fe2/3 phase with a bromide center; and (5) This green rust phase was linked to Pu as Pu(IV).
- Research Organization:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Organization:
- DOE/LANL
- DOE Contract Number:
- AC52-06NA25396
- OSTI ID:
- 1050515
- Report Number(s):
- LA-UR-12-24638; TRN: US1204710
- Country of Publication:
- United States
- Language:
- English
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