[Laser flash photolysis, EPR and Raman studies of liquids at elevated pressures]
The proposed research will solve a number of analytical chemical problems in solutions with measurement techniques that benefit from the use of elevated hydrostatic pressures: stopped-flow spectrophotometry (Gd{sup 3+} + L(ligand), [RuL{sub 5}H{sub 2}O]{sup 2+}, laser flash photolysis of Mo(CO){sub 6} + L, flash photolysis of binuclear metalloproteins), EPR spectroscopy (Gd{sup 3+} ion-exchanged into ETS-10 and ETAS-10 molecular sieves), laser flash photolysis kinetic studies of Mo(CO){sub 6}-2,2`-bipyridine, and electrochemical studies of metalloporphyrins using resonance Raman spectroscopy.
- Research Organization:
- Utah Univ., Salt Lake City, UT (United States). Dept. of Chemistry
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- FG02-84ER13227
- OSTI ID:
- 10188453
- Report Number(s):
- DOE/ER/13227-T5; ON: DE93001788
- Resource Relation:
- Other Information: PBD: [1992]
- Country of Publication:
- United States
- Language:
- English
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[Laser flash photolysis, EPR and Raman studies of liquids at elevated pressures]
Laser flash photolysis, EPR and raman studies of liquids at elevated pressures. Progress report, April 1, 1993--November 19, 1993
Thermal ring closure in Mo(CO){sub 5}L (L = bpy, dmbpy, dpbpy) transients generated by pulsed laser flash photolysis. Mechanistic information from high-pressure effects
Technical Report
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Wed Jan 01 00:00:00 EST 1992
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OSTI ID:10188453
Laser flash photolysis, EPR and raman studies of liquids at elevated pressures. Progress report, April 1, 1993--November 19, 1993
Technical Report
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Fri Nov 19 00:00:00 EST 1993
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OSTI ID:10188453
Thermal ring closure in Mo(CO){sub 5}L (L = bpy, dmbpy, dpbpy) transients generated by pulsed laser flash photolysis. Mechanistic information from high-pressure effects
Journal Article
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Mon Jun 01 00:00:00 EDT 1992
· Organometallics
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OSTI ID:10188453