Advanced direct liquefaction concepts for PETC generic units. Quarterly technical progress report, October 1992--December 1992
The reactivity of the THF insoluble fraction of the ashy resid component of Wilsonville recycle oil (WRO) during liquefaction of Black Thunder coal in tetralin was determined at 415{degrees}C and 60 minutes. The liquefaction runs were made by combining this material with Black Thunder coal at the same ratio used in the WRO coal runs. THF conversion and product distribution from liquefaction in tetralin in the presence of the THF insoluble fraction of the ashy resid were similar to results from liquefaction in WRO. THF conversion was greater than loot with an oil yield that was somewhat higher than in WRO. Differences in HC gas yield and H{sub 2} consumption were slight, while conversion and product distribution from liquefaction of Black Thunder coal in tetralin or in the WRO distillate were quite different. In both these solvents the 85--86% THF conversions were less than for runs in which the THF insoluble fraction of the ashy resid was present. This establishes that the THF insoluble fraction of the ashy resid is the reactive fraction of the WRO.
- Research Organization:
- Kentucky Univ., Lexington, KY (United States). Center for Applied Energy Research; Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); CONSOL, Inc., Pittsburgh, PA (United States); LDP Associates, Hamilton Square, NJ (United States)
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- AC22-91PC91040
- OSTI ID:
- 10175986
- Report Number(s):
- DOE/PC/91040-21; ON: DE93018921
- Resource Relation:
- Other Information: PBD: Feb 1993
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
COAL LIQUEFACTION
COMPARATIVE EVALUATIONS
CHEMICAL REACTION KINETICS
PROGRESS REPORT
RESIDUES
ORGANIC SOLVENTS
RECYCLING
HYDROGEN
CONSUMPTION RATES
TETRALIN
YIELDS
MOLYBDENUM
CATALYTIC EFFECTS
DEWAXING
HYDROGENATION
CARBON MONOXIDE
AGGLOMERATION
IRON
IMPREGNATION
010405
HYDROGENATION AND LIQUEFACTION