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Title: Atomic line emission analyzer for hydrogen isotopes

Patent ·
OSTI ID:10146247

Apparatus for isotopic analysis of hydrogen comprises a low pressure chamber into which a sample of hydrogen is introduced and then exposed to an electrical discharge to excite the electrons of the hydrogen atoms to higher energy states and thereby cause the emission of light on the return to lower energy states, a Fresnel prism made at least in part of a material anomalously dispersive to the wavelengths of interest for dispersing the emitted light, and a photodiode array for receiving the dispersed light. The light emitted by the sample is filtered to pass only the desired wavelengths, such as one of the lines of the Balmer series for hydrogen, the wavelengths of which differ slightly from one isotope to another. The output of the photodiode array is processed to determine the relative amounts of each isotope present in the sample. Additionally, the sample itself may be recovered using, a metal hydride.

Research Organization:
Savannah River Site (SRS), Aiken, SC (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC09-89SR18035
Assignee:
Dept. of Energy
Patent Number(s):
PATENTS-US-A7697032
Application Number:
ON: DE93012007; PAN: 7-697,032
OSTI ID:
10146247
Resource Relation:
Other Information: PBD: 8 May 1991
Country of Publication:
United States
Language:
English