Slurry phase Fischer-Tropsch synthesis: Cobalt plus a water-gas shift catalyst. [Quarterly] report, June 30, 1988--September 30, 1988
This report details experiments performed on three different copper-based catalysts: Cu/Cr{sub 2}O{sub 3}, Cu/MnO/Cr{sub 2}O{sub 3} and Cu/ZnO/Al{sub 2}O{sub 3}. Of these three catalysts, the Cu/ZnO/Al{sub 2}O{sub 3} exhibits the greatest stability when slurried in octacosane. More than 1000 hours-on-stream indicate that the catalyst activity is not detrimentally affected by high pressure, high H{sub 2}/CO ratio, or the presence of alkenes. All of these are necessary stability characteristics for the water-gas shift catalyst, if it is to be used in combination with a cobalt Fischer-Tropsch catalyst. A review of documented reduction procedures for cobalt-based Fischer-Tropsch catalysts is presented.
- Research Organization:
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- AC22-87PC79816
- OSTI ID:
- 10114923
- Report Number(s):
- DOE/PC/79816-2; ON: DE93006468
- Resource Relation:
- Other Information: PBD: [1988]
- Country of Publication:
- United States
- Language:
- English
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