Slurry phase Fischer-Tropsch synthesis: Cobalt plus a water-gas shift catalyst, January 1, 1990--March 30, 1990
Abstract
Experiments to study cobalt-catalyzed reactions of light 1-alkenes added to synthesis gas feed have been performed. Data have been collected at 220{degrees}C, 0.45 to 1.48 MPa and a synthesis gas flow rate between 0.015 and 0.030 Nl/(gcatmin) with H{sub 2}/CO of 1.45 to 2.25. C{sub 2}H{sub 4}, C{sub 3}H{sub 6}, and C{sub 4}H{sub 8} were added to the synthesis gas feed in concentrations ranging from 0.5 to 1.2 mole% of total feed. For each material balance in which 1-alkenes were added, a material balance was performed at similar process conditions without 1-alkenes added. This use of ``base case`` process conditions should make data analysis and interpretation easier. Material balances without 1-alkenes were also repeated to allow verification of catalyst selectivity stability. A total of 49 balances were performed during a single run which lasted over 2500 hours-on-stream. The hydrocarbon data have not yet been completed analyzed.
- Authors:
- Publication Date:
- Research Org.:
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
- Sponsoring Org.:
- USDOE, Washington, DC (United States)
- OSTI Identifier:
- 10107780
- Report Number(s):
- DOE/PC/79816-8
ON: DE92004500
- DOE Contract Number:
- AC22-87PC79816
- Resource Type:
- Technical Report
- Resource Relation:
- Other Information: PBD: [1990]
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 01 COAL, LIGNITE, AND PEAT; COBALT; CATALYTIC EFFECTS; PROGRESS REPORT; FISCHER-TROPSCH SYNTHESIS; FUEL SLURRIES; ALKENES; SYNTHESIS GAS; FLOW RATE; QUANTITY RATIO; HYDROCARBONS; PROPYLENE; ETHYLENE; BUTENES; 010408; C1 PROCESSES
Citation Formats
Yates, I C, and Satterfield, C N. Slurry phase Fischer-Tropsch synthesis: Cobalt plus a water-gas shift catalyst, January 1, 1990--March 30, 1990. United States: N. p., 1990.
Web. doi:10.2172/10107780.
Yates, I C, & Satterfield, C N. Slurry phase Fischer-Tropsch synthesis: Cobalt plus a water-gas shift catalyst, January 1, 1990--March 30, 1990. United States. https://doi.org/10.2172/10107780
Yates, I C, and Satterfield, C N. 1990.
"Slurry phase Fischer-Tropsch synthesis: Cobalt plus a water-gas shift catalyst, January 1, 1990--March 30, 1990". United States. https://doi.org/10.2172/10107780. https://www.osti.gov/servlets/purl/10107780.
@article{osti_10107780,
title = {Slurry phase Fischer-Tropsch synthesis: Cobalt plus a water-gas shift catalyst, January 1, 1990--March 30, 1990},
author = {Yates, I C and Satterfield, C N},
abstractNote = {Experiments to study cobalt-catalyzed reactions of light 1-alkenes added to synthesis gas feed have been performed. Data have been collected at 220{degrees}C, 0.45 to 1.48 MPa and a synthesis gas flow rate between 0.015 and 0.030 Nl/(gcatmin) with H{sub 2}/CO of 1.45 to 2.25. C{sub 2}H{sub 4}, C{sub 3}H{sub 6}, and C{sub 4}H{sub 8} were added to the synthesis gas feed in concentrations ranging from 0.5 to 1.2 mole% of total feed. For each material balance in which 1-alkenes were added, a material balance was performed at similar process conditions without 1-alkenes added. This use of ``base case`` process conditions should make data analysis and interpretation easier. Material balances without 1-alkenes were also repeated to allow verification of catalyst selectivity stability. A total of 49 balances were performed during a single run which lasted over 2500 hours-on-stream. The hydrocarbon data have not yet been completed analyzed.},
doi = {10.2172/10107780},
url = {https://www.osti.gov/biblio/10107780},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Mon Dec 31 00:00:00 EST 1990},
month = {Mon Dec 31 00:00:00 EST 1990}
}