Stabilization of polyaniline solutions
Conference
·
OSTI ID:10107030
Adding hindered amine light stabilizers (HALS) to N-methyl- pyrrolidinone (NMP) solutions of polyaniline delays gelation. It is hypothesized that HALS act in some manner other than as traditional antioxidants in preventing gelation; the secondary amine functional group appears to play a critical role, perhaps by disrupting the physical crystallization network that may contribute to gelation. Pyrrolidine, a secondary amine, or ammonia is an effective cosolvent with NMP in dissolving PAn-EB (emeraldine base). 6 refs, 4 figs.
- Research Organization:
- Los Alamos National Lab., NM (United States)
- Sponsoring Organization:
- USDOE, Washington, DC (United States); National Aeronautics and Space Administration, Washington, DC (United States)
- DOE Contract Number:
- W-7405-ENG-36
- OSTI ID:
- 10107030
- Report Number(s):
- LA-UR-93-3967; CONF-940301-2; ON: DE94003958
- Resource Relation:
- Conference: 207. spring national meeting of the American Chemical Society (ACS),San Diego, CA (United States),13-18 Mar 1994; Other Information: PBD: [1993]
- Country of Publication:
- United States
- Language:
- English
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