The solubilities of significant organic compounds in HLW tank supernate solutions
Large quantities of organic chemicals used in reprocessing spent nuclear-fuels at the Hanford Site have accumulated in underground high-level radioactive waste tanks. The organic content of these tanks must he known so that the potential for hazardous reactions between organic components and sodium nitrate/nitrite salts in the waste can he evaluated. The solubilities of organic compounds described in this report will help determine if they are present in the solid phases (salt cake and sludges) as well as the liquid phase (interstitial liquor/supernate) in the tanks. The solubilities of five significant sodium salts of carboxylic acids and aminocarboxylic acids [sodium oxalate, formate, citrate, nitrilotriacetate (NTA) and ethylendiaminetetraacetate (EDTA)] were measured in a simulated supernate solution at 25{degrees}C, 30{degrees}C, 40{degrees}C, and 50{degrees}C.
- Research Organization:
- Westinghouse Hanford Co., Richland, WA (United States)
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- AC06-87RL10930
- OSTI ID:
- 10105907
- Report Number(s):
- WHC-SA-2565; CONF-940813-32; ON: DE95004163; BR: 35AF11201/35AF11202
- Resource Relation:
- Conference: 208. American Chemical Society (ACS) national meeting,Washington, DC (United States),21-26 Aug 1994; Other Information: PBD: Aug 1994
- Country of Publication:
- United States
- Language:
- English
Similar Records
Solubilities of significant compounds in HLW tank supernate solutions - FY 1996 progress report
The solubilities of significant organic compounds in HLW tank supernate solutions -- FY 1995 progress report
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
HIGH-LEVEL RADIOACTIVE WASTES
CHEMICAL ANALYSIS
HANFORD RESERVATION
RADIOACTIVE WASTE STORAGE
TANKS
CARBOXYLIC ACIDS
STATISTICAL DATA
SOLUBILITY
ORGANIC COMPOUNDS
BENCH-SCALE EXPERIMENTS
052002
400105
WASTE DISPOSAL AND STORAGE
SEPARATION PROCEDURES