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Title: Electrodes for solid state gas sensor

Patent ·
OSTI ID:1007475

A mixed potential electrochemical sensor for the detection of gases has a ceria-based electrolyte with a surface for exposing to the gases to be detected, and with a reference wire electrode and a sensing wire electrode extending through the surface and fixed within the electrolyte as the electrolyte is compressed and sintered. The electrochemical sensor is formed by placing a wire reference electrode and a wire sensing electrode in a die, where each electrode has a first compressed planar section and a second section depending from the first section with the second section of each electrode extending axially within the die. The die is filled with an oxide-electrolyte powder and the powder is pressed within the die with the wire electrodes. The wire-electrodes and the pressed oxide-electrolyte powder are sintered to form a ceramic electrolyte base with a reference wire electrode and a sensing wire electrode depending therefrom.

Research Organization:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
W-7405-ENG-36
Assignee:
The Regents of the University of California (Los Alamos, NM)
Patent Number(s):
6,605,202
Application Number:
10/175,252
OSTI ID:
1007475
Country of Publication:
United States
Language:
English

References (6)

High-Temperature Hydrocarbon Sensors Based on a Stabilized Zirconia Electrolyte and Metal Oxide Electrodes journal January 1999
Highly selective CO sensor using stabilized zirconia and a couple of oxide electrodes journal April 1998
Mixed Potential Type NO[sub x] Sensor Based on Stabilized Zirconia and Oxide Electrode journal January 1996
Mixed-potential-type propylene sensor based on stabilized zirconia and oxide electrode journal February 2000
High-Temperature Carbon Monoxide Potentiometric Sensor journal January 1993
Ceria-Electrolyte-Based Mixed Potential Sensors for the Detection of Hydrocarbons and Carbon Monoxide journal January 1999

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