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  1. Biogeochemical and community ecology responses to the wetting of non-perennial streams

    Transitions between dry and wet hydrologic states are the defining characteristic of non-perennial rivers and streams, which constitute the majority of the global river network. Although past work has focused on stream drying characteristics, there has been less focus on how hydrology, ecology and biogeochemistry respond and interact during stream wetting. Wetting mechanisms are highly variable and can range from dramatic floods and debris flows to gradual saturation by upwelling groundwater. This variation in wetting affects ecological and biogeochemical functions, including nutrient processing, sediment transport and the assembly of biotic communities. Here, in this work, we synthesize evidence describing the hydrological mechanisms underpinning different types of wetting regimes, the associated biogeochemical and organismal responses, and the potential scientific and management implications for downstream ecosystems. This combined multidisciplinary understanding of wetting dynamics in non-perennial streams will be key to predicting and managing for the effects of climate change on non-perennial ecosystems.

  2. Higher-order internal modes of variability imprinted in year-to-year California streamflow changes

    Climate internal variability plays a crucial role in the hydroclimate system, and this study quantifies its predictability on streamflow in California using historical observations, climate simulations, and various machine learning (ML) models. Here we demonstrate that while 5% of the year-to-year variability in seasonal peak streamflow can be attributed to the well-known climate variability indices, the explained variance surpasses 30% when higher-order empirical orthogonal functions of these indices are retained in the analysis. Notably, the results highlight the significant influence of the 5th empirical mode of the Pacific North American pattern and of the Pacific Decadal Oscillation in shaping the streamflow variability, which is consistent across all the tested ML models. A deeper investigation reveals a clear and monotonic quasi-linear response of streamflow to these dominant patterns, emphasizing the substantial role played by higher-order internal modes of variability in shaping regional hydroclimate systems, which contributes to bridging the gap between the well-known variability domains and local climate systems.

  3. Environmental Performance Report 2023: Annual Site Environmental Report per the U.S. Department of Energy Order 231.1B Chg 1

    The National Renewable Energy Laboratory's (NREL's) Environmental Performance Report provides a description of the laboratory's environmental management activities in calendar year 2023, including information on environmental and sustainability performance, environmental compliance activities and status, and environmental protection programs, highlights, and successes. The purpose of this report is to ensure that the U.S. Department of Energy (DOE) and the public receive timely, accurate information about events that have positively affected or could adversely affect the health and safety of the public or workers, the environment, or the operations of DOE facilities. This report meets the DOE requirements of the Annual Site Environmental Report (ASER) and has been prepared in accordance with DOE Order 231.1B Chg 1, Environment, Safety and Health Reporting.

  4. Using stable isotopes to inform water resource management in forested and agricultural ecosystems

    Present and future climatic trends are expected to markedly alter water fluxes and stores in the hydrologic cycle. In addition, water demand continues to grow due to increased human use and a growing population. Sustainably managing water resources requires a thorough understanding of water storage and flow in natural, agricultural, and urban ecosystems. Measurements of stable isotopes of water (hydrogen and oxygen) in the water cycle (atmosphere, soils, plants, surface water, and groundwater) can provide information on the transport pathways, sourcing, dynamics, ages, and storage pools of water that is difficult to obtain with other techniques. However, the potential of these techniques for practical questions has not been fully exploited yet. Here, we outline the benefits and limitations of potential applications of stable isotope methods useful to water managers, farmers, and other stakeholders. We also describe several case studies demonstrating how stable isotopes of water can support water management decision-making. Finally, we propose a workflow that guides users through a sequence of decisions required to apply stable isotope methods to examples of water management issues. We call for ongoing dialogue and a stronger connection between water management stakeholders and water stable isotope practitioners to identify the most pressing issues and develop best-practice guidelines to apply these techniques.

  5. Climate change-resilient snowpack estimation in the Western United States

    In the 21st century, warmer temperatures and changing atmospheric circulation will likely produce unprecedented changes in Western United States snowfall, with impacts on the timing, amount, and spatial patterns of snowpack. The ~900 snow pillow stations are indispensable to water resource management by measuring snow-water equivalent (SWE) in strategic but fixed locations. However, this network may not be impacted by climate change in the same way as the surrounding area and thus fail to accurately represent unmeasured locations; climate change thereby threatens our ability to measure the effects of climate change on snow. In this work, we show that maintaining the current peak SWE estimation skill is nonetheless possible. We find that explicitly including spatial correlations—either from gridded observations or learned by the model—improves skill at predicting distributed snowpack from sparse observations by 184%. Existing artificial intelligence methods can be useful tools to harness the many available sources of snowpack information to estimate snowpack in a nonstationary climate.

  6. Harmonized Database of Western U.S. Water Rights (HarDWR) v.1

    In the arid and semi-arid Western U.S., access to water is regulated through a legal system of water rights. Individuals, companies, organizations, municipalities, and tribal entities have documents that declare their water rights. State water regulatory agencies collate and maintain these records, which can be used in legal disputes over access to water. While these records are publicly available data in all Western U.S. states, the data have not yet been readily available in digital form from all states. Furthermore, there are many differences in data format, terminology, and definitions between state water regulatory agencies. Here, we have collected water rights data from 11 Western U.S. state agencies, harmonized terminology and use definitions, formatted them for consistency, and tied them to a Western U.S.-wide shapefile of water administrative boundaries.

  7. River systems under peaked stress

    The change in the global energy production mix towards variable renewable energy sources requires efficient utilization of regulated rivers to optimise hydropower operations meet the needs of a changing energy market. However, the flexible operation of hydropower plants causes non-natural, sub-daily fluctuating flows in the receiving water bodies, often referred to as ‘hydropeaking’. Drastic changes in sub-daily flow regimes undermine attempts to improve river system health. Environmental decision makers, including permitting authorities and river basin managers facing the intense and increasing pressure on river environments, should consider ecosystem services and biodiversity issues more thoroughly. The need for research innovations in hydropeaking operation design to fulfil both the water and energy security responsibilities of hydropower is highlighted. Our paper outlines optimized hydropeaking design as a future research direction to help researchers, managers, and decision-makers prioritize actions that could enable better integration of river science and energy system planning. The goal of this is to find a balanced hydropower operation strategy.

  8. Manganese exposure from spring and well waters in the Shenandoah Valley: interplay of aquifer lithology, soil composition, and redox conditions

    Abstract Manganese (Mn) is of particular concern in groundwater, as low-level chronic exposure to aqueous Mn concentrations in drinking water can result in a variety of health and neurodevelopmental effects. Much of the global population relies on drinking water sourced from karst aquifers. Thus, we seek to assess the relative risk of Mn contamination in karst by investigating the Shenandoah Valley, VA region, as it is underlain by both karst and non-karst aquifers and much of the population relies on water wells and spring water. Water and soil samples were collected throughout the Shenandoah Valley, to supplement pre-existing well water and spring data from the National Water Information System and the Virginia Household Water Quality Program, totaling 1815 wells and 119 springs. Soils were analyzed using X-ray fluorescence and Mn K-Edge X-ray absorption near-edge structure spectroscopy. Factors such as soil type, soil geochemistry, and aquifer lithology were linked with each location to determine if correlations exist with aqueous Mn concentrations. Analyzing the distribution of Mn in drinking water sources suggests that water wells and springs within karst aquifers are preferable with respect to chronic Mn exposure, with < 4.9% of wells and springs in dolostone and limestone aquifers exceeding 100 ppb Mn, while sandstone and shale aquifers have a heightened risk, with > 20% of wells exceeding 100 ppb Mn. The geochemistry of associated soils and spatial relationships to various hydrologic and geologic features indicates that water interactions with aquifer lithology and soils contribute to aqueous Mn concentrations. Relationships between aqueous Mn in spring waters and Mn in soils indicate that increasing aqueous Mn is correlated with decreasing soil Mn(IV). These results point to redox conditions exerting a dominant control on Mn in this region.

  9. Global peak water limit of future groundwater withdrawals

    Over the past 50 years, humans have extracted the Earth’s groundwater stocks at a steep rate, largely to fuel the irrigated green revolution of global agro-economic development. Given society’s growing reliance on groundwater, we explore ‘peak water limits’ to investigate whether, when, and where humanity might reach peak groundwater extraction. Using an integrated global model of the coupled human-Earth system, we simulate groundwater withdrawals across 235 water basins under 900 future scenarios covering a wide range of human and Earth system dimensions of global change over the 21st century. We find that global nonrenewable groundwater extraction exhibits a distinct peak-and-decline signature, characteristic of most depletable natural resources including oil, gold, copper, etc., in nearly all (98%) of the scenarios, peaking on average at 625 km3yr-1 around mid-century, followed by a consistent decline through 2100. Peak-and-decline occurs in about one-third (82) of basins across all scenarios, with 21 basins that might have already peaked, exposing about half (44%) of the global population to groundwater stress. Most of these basins are in countries with the highest current extraction rates, including the U.S., Mexico, Pakistan, India, China, Saudi Arabia, and Iran. Water basins that are now heavily dependent on groundwater resources for meeting their demands will likely face increasing costs of groundwater and food production, with important implications for global agricultural trade. Groundwater’s role in meeting global water demands will likely diminish toward the end of the century.

  10. Increasing resilience with wastewater reuse

    Drinking water infrastructure in urban settings is increasingly affected by population growth and disruptions like extreme weather events. This study explores how the integration of direct wastewater reuse can help to maintain drinking water service when the system is compromised.


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