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In this study, a cooled gas turbine (GT) analysis was conducted for varying levels of ammonia (NH₃) blends with methane. The ultimate goal is to have a gas turbine design that can be used for all the fuel blends (including 100% NH₃) without any changes to the system. The technological developments in the cooling system, gas turbine design, and materials that will be required for NH₃ combustion were identified and analyzed in this study to develop an advanced gas turbine design for NH₃ fuels. The study includes a combined cycle performance analysis with the NH₃ fuel blends using the advanced gas turbine design developed in this study. A techno-economic analysis was conducted for analyzing the impact of the NH₃ fuels on the levelized cost of electricity and cost sensitivities to fuel price and capacity factor.

The University of Kentucky (UKy) project titled “Ash Fouling Free Regenerative Air Preheater for Deep Cyclic Operation”, DE-FE0031757, was conducted from 8/15/2019 to 8/14/2024 in two Budget Periods. Other participants included PPL Corporation and Black Dragon Double Boiler. The overall goal was to investigate the proposed self-cleaning technology to achieve ash fouling free air preheater operation in a coal-fired power plant, especially during deep cycling. All project deliverables, milestones, and success criteria were met. UKy obtained the following scientific findings. • Temporary and periodic high temperature of heating elements (450 ~ 500 °F) can prevent ash accumulation and maintain air preheater free of clogging. • The ash samples analysis and unit operation provide solid evidence of ABS formed during low load with SCR ammonia slip being the major cause of ash accumulation, and air preheater clogging can be prevented by raising the heating element temperature up to 450 °F~ 500 °F at which ABS is decomposed. • In-situ self-cleaning can be controlled by monitoring temperature and/or presetting fixed number of cleanings per day. Both approaches in pilot testing show positive results for maintaining an ash free state for the air preheater. • Temperature criteria (cold end or gas outlet temperature) for entering self-cleaning service is critical to balance the number of cleaning cycles with maintaining the ash level. • Temperature criteria (cold end or gas outlet temperature) for exiting self-cleaning service is critical to balance the duration of the cleaning cycles with maintaining the ash level.

The overall goal of the project is completion of an initial design of a commercial-scale, Carbon Capture, Utilization, and Storage Direct Air Capture (CCUS-DAC) plant design at three different sites that captures a net of at least 100,000 tonnes per year (TPY) carbon dioxide (CO₂) from the atmosphere and considers compression and conditioning of the captured CO₂ for purpose of pipeline transportation to different geological formation sites for deep well injection and underground storage. In addition to the leading system consisting of a scaled-up Global Thermostat DAC unit, overall plant design includes a combined Heat and Power (CHP) unit integrated with a conventional liquid amine-based carbon capture system (90% capture) and compression facilities. These are considered balance of plant (BOP) systems and are required to provide low carbon-intensity steam and power to the DAC process. A second approach involving provision of DAC units modified to directly capture emissions from the CHP unit was initially assessed as an alternative and it was determined to be less mature than considered approach and not included in the scaled-up plant design efforts. Three geographically diverse continental United States locations were selected to better understand the effect of local/regional ambient conditions on scaled-up DAC system performance and project costs: Bucks, Alabama (hot wet climate), Odessa, Texas (dry hot climate), and Goose Creek, Illinois (mid continental climate). The team focused on initial engineering design activities, including the development of project design criteria, initiation of site-specific studies and investigations, completion of DAC system process and equipment design, and definition of balance of plant (BOP) engineering. The purpose of the activities were to develop Technoeconomic Analysis (TEA), Life-Cycle Analysis (LCA), and Environmental, Health, and Safety (EH&S) analysis, and Business Case Analysis (BCA) to validate that the project engineering and scale-up plans of the DAC systems, at each of the three distinct case studies considered, are technically, economically, and environmentally feasible for commercial-scale operation.

This paper presents the second part of a study in which the leading-edge and suction surface of a compressor blade was modified to delay onset of phase change for sCO₂ compressors operating near the critical point. Using a first-of-its-kind apparatus for the measurement of sCO₂ flow fields, Particle Image Velocimetry (PIV) is used for local flow field measurements of two compressor blade geometries: the modified “biased-wedge,” and a conventional constant thickness blade. Utilizing the developed hardware, the feasibility of a simple, laser-based diagnostic for qualitatively measuring liquid phase regions, is also presented. The design of the optical diagnostics rig, a discussion of numerous challenges, and necessary considerations involved in performing optical-based measurements like PIV, in sCO₂, are discussed. Velocity field measurements for the modified compressor profile show a much lower suction peak compared to a conventional blade. Furthermore, these results validate numerical results at the tested conditions, where the suction side profile of the biased wedge works to minimize the local pressure gradient.

To monitor the stability of various energy and manufacturing systems, sensors capable of operating at temperatures exceeding 1000 °C in diverse environments for extended durations are essential. However, under harsh conditions, degradation of sensing materials is a concern that can be controlled by embedding the sensors into refractory oxides. Doped-LaCrO3 based composites are excellent candidates for high-temperature sensing applications due to their good thermoelectrical properties. However, chemical reactivity between the conductive phase and the refractory oxides can decrease the performance of the sensors. In this work, it was devised gradient-type protective layers safeguarding conductive phases within embedded thermocouples, which were fabricated and characterized by X-Ray Diffraction for phase development analysis, Scanning Electron Microscopy and Energy-dispersive X-ray spectroscopy for microstructure and cationic interdiffusion kinetics, long-term thermoelectric testing was completed up to 1400 °C. The enhanced performance of these novel sensors addresses a critical limitation, rendering them viable for long-term high-temperature applications.

Increasingly, coal-fired power plants are required to balance power grids by compensating for the variable electricity supply from renewable energy sources. Fossil-fueled power plants, originally designed to be base loaded, will increasingly need to operate on a load following or cyclic basis. This demanding requirement for operational flexibility will need to be evaluated for resilience to frequent start-ups, meeting major and rapid load changes, and providing frequency control duties. Our research objective was to evaluate and improve flexibility of existing power plants by improving and redesigning components and defining new operational strategies, with acceptable impacts on component life, efficiency and emissions.

The overall motivation of this project was to demonstrate at laboratory, bench-scale, and full-scale demonstration levels that (a) coal ash surface impoundments can go through closure by removal as per USEPA and state regulations so that the material can be used as is (other than draining free water using CCRs piles) in high-volume beneficial applications, (b) FGD material from closed out FGD facilities can be excavated and recompacted for coal mine reclamation, and (c) harvested CCRs can be beneficially utilized (providing a net environmental gain) in large-volumes for reclamation at abandoned coal mine sites across the US, especially in the Eastern and Midwest coal mining regions. The objectives of this project were to: 1) promote the safe and cost-effective closure by removal of coal ash impoundments, 2) harvest landfilled FGD, and 3) promote the high-volume beneficial use of these harvested CCRs in the reclamation of abandoned surface coal mine sites across the eastern and midwestern coal mining regions of the United States. The major tasks carried out for this project are summarized below: 1) Conesville Full-Scale Demonstration Project: About 2 million tons of harvested CCR materials from the closure by removal of an inactive fly ash pond and an adjacent old FGD landfill were used for the full-scale demonstration project to fully reclaim a nearby partially completed abandoned surface coal mine. Site monitoring for the project duration was carried out and results are discussed. 2) Laboratory Testing: Geotechnical and environmental testing of harvested ponded fly ash and landfilled FGD material at the former Conesville power plant were carried out. Completing the laboratory testing allowed for QA/QC for the full-scale site construction and informed the formulation of the risk analysis. 3) Risk Analysis: We developed a reliable computational model for fate and transport. We used these models and the rich set of monitored data for the Conesville site to analyze risks to human health and ecological risks associated with high-volume surface mine reclamation using harvested CCRs. 4) GIS Siting Study: A Geographic Information System (GIS) study was carried out for three states in the Eastern coal mining region and two states in the Midwest coal region. This effort provided site specific GIS information for five states and allowed us to establish protocols that other states can follow in implementing their own state specific GIS study.

An important need for coal fired power plants is the ability to monitor multiple systems with ease and accuracy. Common implementations of these monitoring systems come with drawbacks due to the nature of coal fired power plants. Harsh environments, High Temperatures, and lots of RF (Radio Frequency) noise can create issues for accurately recording and transmitting data across wireless signals. In addition, as renewable energy sources come online, existing fossil fueled plants will need to operate more flexibly with their maintenance schedules outside of standard conditions. Therefore, additional sensing and control mechanisms need placed in existing plants to provide operators with more information such that maintenance decisions can be made well in advance of failures. A solution to this problem is the Next Generation of Smart Sensors, which leverages the power of 5G cellular signals and machine learning to overcome the myriad of problems with current implementations

The levelized cost of energy (LCOE) and other cost metrics used in energy planning do not account for out-of-market impacts of the technology choice. While a decision-maker at the utility or asset owner level may compare multiple forms of electricity generating technology using LCOE, a decision-maker over energy policy or community stakeholders may be interested in considering impacts beyond those that LCOE measures. This report quantifies economic impacts such as jobs and wage growth across electricity generation technologies then develops an approach to systematically compare socioeconomic metrics across technology choices. To address additional workforce related impacts, this report also compares the typical workforce education requirements and annual income levels for multiple types of electricity generating facilities. The grid scale electricity generating technologies analyzed in this report produce power using conventional hydroelectric dams, coal, natural gas, nuclear reactors, solar PV, land-based wind turbines, geothermal heat, and woody biomass combustion. Although it doesn’t generate electricity itself, the economic impacts associated with battery storage equipment manufacturing and installation were also analyzed.

In amine scrubbing carbon capture, concerns about amine solvent degradation include whether it can affect the ability of the solvent to capture CO₂. This study examines the interactions between the three most reported monoethanolamine (MEA) thermal degradation compounds namely, oxazolidine-2-one (OZD), N-(2-hydroxyethyl)-ethylenediamine (HEEDA), and N-(2- hydroxyethyl)-imidazoline-2-one (HEIA) with CO₂ in the presence and absence of MEA. We compared ¹H NMR, ¹³C NMR, and heteronuclear single-quantum coherence (HSQC) NMR for neat OZD, HEEDA, and HEIA samples with CO₂-loaded samples to observe changes in protonation and unique carbamate species formation. We found that OZD and HEIA did not directly react with CO₂ or undergo proton shifting based on our comparison of the neat OZD and HEIA samples with CO₂-loaded spectra. However, we observed that the OZD can protonate when sparged with CO₂ in the presence of MEA, which suggests that the OZD acts as an intermediate. The NMR spectra for HEEDA indicated that HEEDA directly reacts with CO₂ at both amino groups and can protonate. In the presence of MEA, HEEDA and MEA can act like a solvent blend, resulting in multiple carbamates forming within the solvent. The neat HEIA spectrum, compared with CO₂-loaded HEIA spectra, revealed similar results as OZD, where it does not react with CO₂ or protonate directly. However, HEIA does not protonate in the presence of MEA. These degradation compound reactions can increase the number of general equilibrium reactions during carbon capture and impact the model MEA solvent. This work helps provide a more complete picture of the reactions as the solvent degrades. Although this study examines CO₂ effects on thermal degradation products for MEA, other amines such as piperazine or 1- amino-3-propanol will degrade, and the degradation may speciate similarly with CO₂. Furthermore, this study can impact and improve process models by assessing the degradation compounds’ reactions with CO₂ and potentially incorporating them into the model based on a neat solvent.