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  1. Tracing the plasma interactions for pulsed reactive crossed-beam laser ablation

    Pulsed reactive crossed-beam laser ablation is an effective technique to govern the chemical activity of plasma species and background molecules during pulsed laser deposition. Instead of using a constant background pressure, a gas pulse with a reactive gas, synchronized with the laser beam, is injected into vacuum or a low background pressure near the ablated area of the target. It intercepts the initially generated plasma plume, thereby enhancing the physicochemical interactions between the gaseous environment and the plasma species. For this study, kinetic energy resolved mass-spectrometry and time-resolved plasma imaging were used to study the physicochemical processes occurring during themore » reactive crossed beam laser ablation of a partially {sup 18}O substituted La{sub 0.6}Sr{sub 0.4}MnO{sub 3} target using oxygen as gas pulse. The characteristics of the ablated plasma are compared with those observed during pulsed laser deposition in different oxygen background pressures.« less
  2. Plasma interactions determine the composition in pulsed laser deposited thin films

    Plasma chemistry and scattering strongly affect the congruent, elemental transfer during pulsed laser deposition of target metal species in an oxygen atmosphere. Studying the plasma properties of La{sub 0.6}Sr{sub 0.4}MnO{sub 3}, we demonstrate for as grown La{sub 0.6}Sr{sub 0.4}MnO{sub 3-δ} films that a congruent transfer of metallic species is achieved in two pressure windows: ∼10{sup −3} mbar and ∼2 × 10{sup −1} mbar. In the intermediate pressure range, La{sub 0.6}Sr{sub 0.4}MnO{sub 3-δ} becomes cation deficient and simultaneously almost fully stoichiometric in oxygen. Important for thin film growth is the presence of negative atomic oxygen and under which conditions positive metal-oxygenmore » ions are created in the plasma. This insight into the plasma chemistry shows why the pressure window to obtain films with a desired composition and crystalline structure is narrow and requires a careful adjustment of the process parameters.« less
  3. Langmuir probe measurements and mass spectrometry of plasma plumes generated by laser ablation of La{sub 0.4}Ca{sub 0.6}MnO{sub 3}

    The plasma formed in vacuum by UV nanosecond laser ablation of La{sub 0.4}Ca{sub 0.6}MnO{sub 3} in the fluence range of 0.8 to 1.9 J cm{sup −2} using both Langmuir probe analysis and energy-resolved mass spectrometry has been studied. Mass spectrometry shows that the main positive ion species are Ca{sup +}, Mn{sup +}, La{sup +}, and LaO{sup +}. The Ca{sup +} and Mn{sup +} energy distributions are quite broad and lie in the 0–100 eV region, with the average energies increasing with laser fluence. In contrast, the La{sup +} and LaO{sup +} distributions are strongly peaked around 10 eV. The net time-of-arrival signal derivedmore » from the measured positive ion energy distributions is broadly consistent with the positive ion signal measured by the Langmuir probe. We also detected a significant number of O{sup −} ions with energies in the range of 0 to 10 eV. The Langmuir probe was also used to measure the temporal variation of the electron density and temperature at 6 cm from the ablation target. In the period when O{sup −} ions are found at this position, the plasma conditions are consistent with those required for significant negative oxygen ion formation, as revealed by studies on radio frequency excited oxygen plasma.« less
  4. Catalytic combustor for integrated gasification combined cycle power plant

    A gasification power plant 10 includes a compressor 32 producing a compressed air flow 36, an air separation unit 22 producing a nitrogen flow 44, a gasifier 14 producing a primary fuel flow 28 and a secondary fuel source 60 providing a secondary fuel flow 62 The plant also includes a catalytic combustor 12 combining the nitrogen flow and a combustor portion 38 of the compressed air flow to form a diluted air flow 39 and combining at least one of the primary fuel flow and secondary fuel flow and a mixer portion 78 of the diluted air flow tomore » produce a combustible mixture 80. A catalytic element 64 of the combustor 12 separately receives the combustible mixture and a backside cooling portion 84 of the diluted air flow and allows the mixture and the heated flow to produce a hot combustion gas 46 provided to a turbine 48. When fueled with the secondary fuel flow, nitrogen is not combined with the combustor portion.« less
  5. Stopping power of a buffer gas for laser plasma debris mitigation

    The stopping power of a buffer gas against laser-plasma debris is quantitatively assessed by means of visualization techniques. For ablation of planar tin targets in an Ar ambient, an expanding wavefront was visualized, whose translation energy was rapidly reduced within a few millimeters above the target surface. The fastest debris component was along the normal to the target with an initial kinetic energy of 1.1 keV. The buffer gas efficiency changed in a line-of-sight-dependent way, thermalizing more efficiently the on-axis components. The maximum stopping power of the gas buffer was determined as high as 0.4 keV/mm. Due to the reductionmore » in stopping power, nonlinearly with the debris kinetic energy, a gas buffer thickness of 10 mm is required at the studied atmospheric pressure in order to mitigate high energy debris below a fiducial threshold of 0.1 keV.« less
  6. Damage Mechanisms In Polymers Upon NIR Femtosecond Pulse Laser Irradiation: Sub-Threshold Processes And Their Implications For Laser Safety Applications

    This contribution investigates laser-induced damage of thin film and bulk polymer samples, with the focus on physical processes occurring close to the damage threshold. In-situ real-time reflectivity (RTR) measurements with picosecond (ps) and nanosecond (ns) temporal resolution were performed on thin polymer films on a timescale up to a few microseconds ({mu}s). A model for polymer thin film damage is presented, indicating that irreversible chemical modification processes take place already below the fluence threshold for macroscopic damage. On dye-doped bulk polymer filters (as used for laser goggles), transmission studies using fs-and ps-laser pulses reveal the optical saturation behavior of themore » material and its relation to the threshold of permanent damage. Implications of the sub-threshold processes for laser safety applications will be discussed for thin film and bulk polymer damage.« less
  7. Laser-Induced Forward Transfer Using Triazene Polymer Dynamic Releaser Layer

    This article presents a short review of the use of triazene polymer as a dynamic release layer (DRL) for laser-induced forward transfer (LIFT), before looking at the latest research in more detail. The field of triazene polymer ablation only started around 20 years ago and has grown rapidly into a number of different application areas. Most promisingly, triazene ablation has been refined as a method for propulsion, bringing the benefits of LIFT to the deposition of sensitive transfer materials. The key to understanding LIFT with a triazene DRL is to understand the more fundamental nature of triazene polymer ablation inmore » both frontside and backside orientations. This article focuses on the most recent experimental results on LIFT with a triazene DRL: the effect of picosecond pulse lengths compared with nanosecond pulse lengths; the effect of reduced air pressure; and the improvements in transfer in terms of range of transfer materials, and transfer across a gap. The results all help improve fundamental understanding of triazene-based LIFT, and the transfer of functioning OLEDs demonstrates the capability of the technique.« less
  8. A Review of Laser Ablation Propulsion

    Laser Ablation Propulsion is a broad field with a wide range of applications. We review the 30-year history of laser ablation propulsion from the transition from earlier pure photon propulsion concepts of Oberth and Saenger through Kantrowitz's original laser ablation propulsion idea to the development of air-breathing 'Lightcraft' and advanced spacecraft propulsion engines. The polymers POM and GAP have played an important role in experiments and liquid ablation fuels show great promise. Some applications use a laser system which is distant from the propelled object, for example, on another spacecraft, the Earth or a planet. Others use a laser thatmore » is part of the spacecraft propulsion system on the spacecraft. Propulsion is produced when an intense laser beam strikes a condensed matter surface and produces a vapor or plasma jet. The advantages of this idea are that exhaust velocity of the propulsion engine covers a broader range than is available from chemistry, that it can be varied to meet the instantaneous demands of the particular mission, and that practical realizations give lower mass and greater simplicity for a payload delivery system. We review the underlying theory, buttressed by extensive experimental data. The primary problem in laser space propulsion theory has been the absence of a way to predict thrust and specific impulse over the transition from the vapor to the plasma regimes. We briefly discuss a method for combining two new vapor regime treatments with plasma regime theory, giving a smooth transition from one regime to the other. We conclude with a section on future directions.« less
  9. Fabrication of organic light-emitting diode pixels by laser-assisted forward transfer

    Fabrication of a polymer light-emitting device was achieved by a laser forward transfer technique using the decomposition of a thin triazene polymer film by a XeCl excimer laser. The dry deposition process allows transfer of a bilayer consisting of the electroluminescent polymer poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] covered with an aluminum electrode onto a receiver substrate. The soft transfer results in laterally well resolved pixels ({approx_equal}500 {mu}m), whose fluorescence as well as electroluminescence spectra remain unaltered. The rectifying and smooth current-voltage characteristics add to the merits of this laser-based transfer method that opens up the possibility of direct-writing heat- and UV-sensitive materials.
  10. Finite-size effects in lattice QCD with dynamical Wilson fermions

    As computing resources are limited, choosing the parameters for a full lattice QCD simulation always amounts to a compromise between the competing objectives of a lattice spacing as small, quarks as light, and a volume as large as possible. Aiming to push unquenched simulations with the Wilson action towards the computationally expensive regime of small quark masses we address the question whether one can possibly save computing time by extrapolating results from small lattices to the infinite volume, prior to the usual chiral and continuum extrapolations. In the present work the systematic volume dependence of simulated pion and nucleon massesmore » is investigated and compared with a long-standing analytic formula by Luescher and with results from chiral perturbation theory (ChPT). We analyze data from hybrid Monte Carlo simulations with the standard (unimproved) two-flavor Wilson action at two different lattice spacings of a{approx_equal}0.08 and 0.13 fm. The quark masses considered correspond to approximately 85% and 50% (at the smaller a) and 36% (at the larger a) of the strange quark mass. At each quark mass we study at least three different lattices with L/a=10 to 24 sites in the spatial directions (L=0.85-2.08 fm). We find that an exponential ansatz fits the volume dependence of the pion masses well, but with a coefficient about an order of magnitude larger than the theoretical leading-order prediction. In the case of the nucleon we observe a remarkably good agreement between our lattice data and a recent formula from relativistic baryon ChPT.« less

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