Photochemical dimerization of organic compounds

Crabtree, Robert H; Brown, Stephen H; Muedas, Cesar A; Ferguson, Richard R

Title: Photochemical dimerization of organic compounds

Patent · Wed Jan 01 00:00:00 EST 1992

OSTI ID:868239

Crabtree, Robert H ^[1]; Brown, Stephen H ^[2]; Muedas, Cesar A ^[3]; Ferguson, Richard R ^[4]

Bethany, CT
Princeton, NJ
New Haven, CT
Branford, CT

At least one of selectivity and reaction rate of photosensitized vapor phase dimerizations, including dehydrodimerizations, hydrodimerizations and cross-dimerizations of saturated and unsaturated organic compounds is improved by conducting the dimerization in the presence of hydrogen or nitrous oxide.

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Research Organization:: Yale Univ., New Haven, CT (United States)

DOE Contract Number:: FG02-84ER13297

Assignee:: Yale University (New Haven, CT)

Patent Number(s):: US 5104503

OSTI ID:: 868239

Country of Publication:: United States

Language:: English

References (14)

The Polymerization and Hydrogenation of Ethylene by Means of Excited Mercury Atoms Olson, A. R.; Meyers, C. H. Journal of the American Chemical Society, Vol. 48, Issue 2 https://doi.org/10.1021/ja01413a012	journal	February 1926
The Reaction of Hydrogen Atoms with the Paraffin Hydrocarbons Trost, W. R.; Steacie, E. W. R. The Journal of Chemical Physics, Vol. 16, Issue 4 https://doi.org/10.1063/1.1746889	journal	April 1948
The Reactions of h and d Atoms with Cyclic and Paraffin Hydrocarbons Schiff, H. I.; Steacie, E. W. R. Canadian Journal of Chemistry, Vol. 29, Issue 1 https://doi.org/10.1139/v51-001	journal	January 1951
The Hydrogen-Ethylene Reaction in the Presence of Excited Mercury Atoms Olson, A. R.; Meyers, Charles H. Journal of the American Chemical Society, Vol. 49, Issue 12 https://doi.org/10.1021/ja01411a023	journal	December 1927
Kinetics of the reactions of silicon compounds. Part VI. Photolytic addition of trimethylsilane to tetrafluoroethylene Haszeldine, R. N.; Lythgoe, S.; Robinson, P. J. Journal of the Chemical Society B: Physical Organic https://doi.org/10.1039/j29700001634	journal	January 1970
�ber Zerlegung von Wasserstoffmolek�len durch angeregte Quecksilberatome Cario, G.; Franck, J. Zeitschrift f�r Physik, Vol. 11, Issue 1 https://doi.org/10.1007/BF01328410	journal	December 1922
THE REACTIONS OF ETHYLENE, HYDROGEN AND THE SATURATED HYDROCARBONS UNDER THE INFLUENCE OF EXCITED MERCURY ¹ Taylor, Hugh S.; Hill, Douglas G. Journal of the American Chemical Society, Vol. 51, Issue 10 https://doi.org/10.1021/ja01385a008	journal	October 1929
The Reaction of Hydrogen Atoms with Propylene Rabinovitch, B. S.; Davis, S. G.; Winkler, C. A. Canadian Journal of Research, Vol. 21b, Issue 12 https://doi.org/10.1139/cjr43b-034	journal	December 1943
Reactions of Silane with Unsaturated Hydrocarbons White, David G.; Rochow, Eugene G. Journal of the American Chemical Society, Vol. 76, Issue 15 https://doi.org/10.1021/ja01644a008	journal	August 1954
Mechanism of energy transfer in the triplet mercury photosensitization of paraffins Gunning, H. E.; Campbell, J. M.; Saunhu, H. S. Journal of the American Chemical Society, Vol. 95, Issue 3 https://doi.org/10.1021/ja00784a017	journal	February 1973
375. Polyfluoroalkyl compounds of silicon. Part VI. Reaction of 3,3,3-trifluoropropene with silane, and the conversion of the products into silicones and polysiloxanes Haszeldine, R. N.; Newlands, M. J.; Plumb, J. B. Journal of the Chemical Society (Resumed) https://doi.org/10.1039/jr9650002101	journal	January 1965
Competitive Unimolecular Decomposition of Alkyl Radicals. Tertiary Butyl Rupture Larson, C. W.; Rabinovitch, B. S. The Journal of Chemical Physics, Vol. 52, Issue 10 https://doi.org/10.1063/1.1672757	journal	May 1970
The Kinetics of Elementary Reactions of the Simple Hydrocarbons. Steacie, E. W. R. Chemical Reviews, Vol. 22, Issue 2 https://doi.org/10.1021/cr60072a001	journal	April 1938
Unimolecular Decomposition and Intramolecular Energy Relaxation in the Suprahigh‐Pressure Region Oref, I.; Schuetzle, D.; Rabinovitch, B. S. The Journal of Chemical Physics, Vol. 54, Issue 2 https://doi.org/10.1063/1.1674880	journal	January 1971

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Related Subjects

photochemical
dimerization
organic
compounds
selectivity
reaction
rate
photosensitized
vapor
phase
dimerizations
including
dehydrodimerizations
hydrodimerizations
cross-dimerizations
saturated
unsaturated
improved
conducting
presence
hydrogen
nitrous
oxide
photochemical dimerization
reaction rate
organic compound
organic compounds
vapor phase
nitrous oxide
unsaturated organic
/204/

Title: Photochemical dimerization of organic compounds

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References (14)

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