Pressure-induced polymerization of P(CN) 3

Gou, Huiyang; Yonke, Brendan L.; Epshteyn, Albert; Kim, Duck Young; Smith, Jesse S.; Strobel, Timothy A.

doi:10.1063/1.4919640

Title: Pressure-induced polymerization of P(CN) ₃

Journal Article · Thu May 21 00:00:00 EDT 2015 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/1.4919640· OSTI ID:1338321

^[1]; Yonke, Brendan L. ^[2]; Epshteyn, Albert ^[2]; Kim, Duck Young ^[1]; Smith, Jesse S. ^[1]; Strobel, Timothy A. ^[1]

Carnegie Inst. of Washington, Argonne, IL (United States). Geophysical Lab.
Naval Research Lab. (NRL), Washington, DC (United States)

Motivated to explore the formation of novel extended carbon-nitrogen solids via well-defined molecular precursor pathways, we studied the chemical reactivity of highly pure phosphorous tricyanide, P(CN)₃, under conditions of high pressure at room temperature. Raman and infrared (IR) spectroscopic measurements reveal a series of phase transformations below 10 GPa, and several low-frequency vibrational modes are reported for the first time. Synchrotron powder Xray diffraction (PXRD) measurements taken during compression show that molecular P(CN)₃ is highly compressible with a bulk modulus of 10.0±0.3 GPa and polymerizes into an amorphous solid above ~10.0 GPa. Raman and infrared (IR) spectra, together with first-principles molecular-dynamics simulations, show that the amorphization transition is associated with polymerization of the cyanide groups into CN bonds with predominantly sp² character, similar to known carbon nitrides, resulting in a novel PCN polymeric phase, which is recoverable to ambient pressure.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Carnegie Inst. of Science, Washington, DC (United States). Geophysical Lab.

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0002006; AC02-06CH11357; FG02-99ER45775; NA0001974

OSTI ID:: 1338321

Alternate ID(s):: OSTI ID: 1228173

Journal Information:: Journal of Chemical Physics, Vol. 142, Issue 19; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 14 works

Citation information provided by
Web of Science

References (79)

Prediction of New Low Compressibility Solids Liu, A. Y.; Cohen, M. L. Science, Vol. 245, Issue 4920 https://doi.org/10.1126/science.245.4920.841	journal	August 1989
Low-Compressibility Carbon Nitrides Teter, D. M.; Hemley, R. J. Science, Vol. 271, Issue 5245 https://doi.org/10.1126/science.271.5245.53	journal	January 1996
Experimental Realization of the Covalent Solid Carbon Nitride Niu, C.; Lu, Y. Z.; Lieber, C. M. Science, Vol. 261, Issue 5119 https://doi.org/10.1126/science.261.5119.334	journal	July 1993
Observation of crystalline $C_{3}$ $N_{4}$ Yu, Kin Man; Cohen, Marvin L.; Haller, E. E. Physical Review B, Vol. 49, Issue 7 https://doi.org/10.1103/PhysRevB.49.5034	journal	February 1994
Plasma chemical vapor deposition and properties of hard C ₃ N ₄ thin films Vepr̆ek, S.; Weidmann, J.; Glatz, F. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 13, Issue 6 https://doi.org/10.1116/1.579613	journal	November 1995
Growth and composition of covalent carbon nitride solids Zhang, Z. John; Fan, Shoushan; Lieber, Charles M. Applied Physics Letters, Vol. 66, Issue 26 https://doi.org/10.1063/1.113794	journal	June 1995
Effect of ultraviolet light irradiation on amorphous carbon nitride films Zhang, Mei; Nakayama, Yoshikazu Journal of Applied Physics, Vol. 82, Issue 10 https://doi.org/10.1063/1.366356	journal	November 1997
Synthesis of carbon nitride films at low temperatures Hammer, P.; Baker, M. A.; Lenardi, C. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 15, Issue 1 https://doi.org/10.1116/1.580481	journal	January 1997
A graphitic carbon nitride Sekine, T.; Kanda, H.; Bando, Y. Journal of Materials Science Letters, Vol. 9, Issue 12 https://doi.org/10.1007/BF00721588	journal	December 1990
Triazine-based Carbon Nitrides for Visible-Light-Driven Hydrogen Evolution Schwinghammer, Katharina; Tuffy, Brian; Mesch, Maria B. Angewandte Chemie International Edition, Vol. 52, Issue 9 https://doi.org/10.1002/anie.201206817	journal	January 2013
Triazine-Based Graphitic Carbon Nitride: a Two-Dimensional Semiconductor Algara-Siller, Gerardo; Severin, Nikolai; Chong, Samantha Y. Angewandte Chemie International Edition, Vol. 53, Issue 29 https://doi.org/10.1002/anie.201402191	journal	May 2014
FORMATION OF C ₃ N ₄ CLUSTERS BY LASER ABLATION OF NITRIDED GRAPHITE Murray, P. T.; Chen, M. Y. Surface Review and Letters, Vol. 03, Issue 01 https://doi.org/10.1142/S0218625X96000395	journal	February 1996
Influence of RF plasma properties on the deposited PACVD CNx layers Grüger, H.; Selbmann, D.; Wolf, E. Surface and Coatings Technology, Vol. 97, Issue 1-3 https://doi.org/10.1016/s0257-8972(97)00411-8	journal	December 1997
Experimental study on the stability of graphitic C3N4 under high pressure and high temperature Fang, Leiming; Ohfuji, Hiroaki; Shinmei, Toru Diamond and Related Materials, Vol. 20, Issue 5-6 https://doi.org/10.1016/j.diamond.2011.03.034	journal	May 2011
High-Pressure Bulk Synthesis of Crystalline C ₆ N ₉ H ₃ ·HCl: A Novel C ₃ N ₄ Graphitic Derivative Zhang, Zhihong; Leinenweber, Kurt; Bauer, Matt Journal of the American Chemical Society, Vol. 123, Issue 32 https://doi.org/10.1021/ja0103849	journal	August 2001
Synthesis of a bulk crystalline phase of carbon nitride Dymont, V. P.; Nekrashevich, E. M.; Starchenko, I. M. Journal of Experimental and Theoretical Physics Letters, Vol. 68, Issue 6 https://doi.org/10.1134/1.567896	journal	September 1998
Synthesis of carbon nitride crystals at high pressures and temperatures He, D. W.; Zhang, F. X.; Zhang, X. Y. Journal of Materials Research, Vol. 13, Issue 12 https://doi.org/10.1557/JMR.1998.0471	journal	December 1998
Synthesis of nanocrystalline nitrogen-rich carbon nitride powders at high pressure Andreyev, Alexey; Akaishi, Minoru; Golberg, Dmitri Diamond and Related Materials, Vol. 11, Issue 12 https://doi.org/10.1016/S0925-9635(02)00211-X	journal	December 2002
High-pressure pyrolysis study of C ₃ N ₆ H ₆ : a route to preparing bulk C ₃ N ₄ Ma, H. A.; Jia, X. P.; Chen, L. X. Journal of Physics: Condensed Matter, Vol. 14, Issue 44 https://doi.org/10.1088/0953-8984/14/44/466	journal	October 2002
Structure and stability of carbon nitride under high pressure and high temperature up to 125GPa and 3000K Kojima, Yohei; Ohfuji, Hiroaki Diamond and Related Materials, Vol. 39 https://doi.org/10.1016/j.diamond.2013.07.006	journal	October 2013
High-Pressure Synthesis of Crystalline Carbon Nitride Imide, C2N2(NH) Horvath-Bordon, Elisabeta; Riedel, Ralf; McMillan, Paul F. Angewandte Chemie International Edition, Vol. 46, Issue 9 https://doi.org/10.1002/anie.200603851	journal	February 2007
Novel Synthetic Routes to Carbon Nitride Todd, M.; Kouvetakis, J.; Groy, T. L. Chemistry of Materials, Vol. 7, Issue 7 https://doi.org/10.1021/cm00055a023	journal	July 1995
Theoretical Tracing of a Novel Route from Molecular Precursors through Polymers to Dense, Hard C ₃ N ₄ Solids Kroll, Peter; Hoffmann, Roald Journal of the American Chemical Society, Vol. 121, Issue 19 https://doi.org/10.1021/ja984406b	journal	May 1999
Identification of new pillared-layered carbon nitride materials at high pressure Salamat, Ashkan; Deifallah, Malek; Cabrera, Raul Quesada Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep02122	journal	July 2013
Phosphorus-Doped Carbon Nitride Solid: Enhanced Electrical Conductivity and Photocurrent Generation Zhang, Yuanjian; Mori, Toshiyuki; Ye, Jinhua Journal of the American Chemical Society, Vol. 132, Issue 18 https://doi.org/10.1021/ja101749y	journal	May 2010
Unique Electronic Structure Induced High Photoreactivity of Sulfur-Doped Graphitic C ₃ N ₄ Liu, Gang; Niu, Ping; Sun, Chenghua Journal of the American Chemical Society, Vol. 132, Issue 33 https://doi.org/10.1021/ja103798k	journal	August 2010
Synthesis of Molecular Precursors to Carbon−Nitrogen−Phosphorus Polymeric Systems McMurran, Jeff; Kouvetakis, J.; Nesting, David C. Chemistry of Materials, Vol. 10, Issue 2 https://doi.org/10.1021/cm9705799	journal	February 1998
Synthesis of LiBC ₄ N ₄ , BC ₃ N ₃ , and Related C−N Compounds of Boron: New Precursors to Light Element Ceramics Williams, Darrick; Pleune, Brett; Kouvetakis, J. Journal of the American Chemical Society, Vol. 122, Issue 32 https://doi.org/10.1021/ja0006752	journal	August 2000
Structural and electronic properties of C3N4−nPn (n=0,1,2,3,4) Ding, F.; Feng, Y. P. Computational Materials Science, Vol. 30, Issue 3-4 https://doi.org/10.1016/j.commatsci.2004.02.032	journal	August 2004
Graphitic carbon nitride materials: variation of structure and morphology and their use as metal-free catalysts Thomas, Arne; Fischer, Anna; Goettmann, Frederic Journal of Materials Chemistry, Vol. 18, Issue 41 https://doi.org/10.1039/b800274f	journal	January 2008
A metal-free polymeric photocatalyst for hydrogen production from water under visible light Wang, Xinchen; Maeda, Kazuhiko; Thomas, Arne Nature Materials, Vol. 8, Issue 1 https://doi.org/10.1038/nmat2317	journal	November 2008
Graphitic carbon nitride materials: controllable synthesis and applications in fuel cells and photocatalysis Zheng, Yao; Liu, Jian; Liang, Ji Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee03479d	journal	January 2012
Ueber eine Verbindung des Cyans mit Phosphor Hübner, H.; Wehrhane, G. Annalen der Chemie und Pharmacie, Vol. 128, Issue 2 https://doi.org/10.1002/jlac.18631280218	journal	January 1863
Ueber den Cyanphosphor Wehrhane, G.; Hübner, H. Annalen der Chemie und Pharmacie, Vol. 132, Issue 3 https://doi.org/10.1002/jlac.18641320305	journal	January 1864
The crystal and molecular structure of phosphorus tricyanide Emerson, K.; Britton, D. Acta Crystallographica, Vol. 17, Issue 9 https://doi.org/10.1107/S0365110X64002948	journal	September 1964
Das Schwingungsspektrum des Phosphortricyanids Goubeau, J.; Haeberle, H.; Ulmer, H. Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 311, Issue 1-2 https://doi.org/10.1002/zaac.19613110115	journal	August 1961
Infrared and Raman spectra of P(CN)3 and As(CN)3 Miller, Foil A.; Frankiss, Stephen G.; Sala, Oswaldo Spectrochimica Acta, Vol. 21, Issue 4 https://doi.org/10.1016/0371-1951(65)80035-2	journal	April 1965
The Raman spectra of phosphorus and arsenic tricyanides, P(CN)3 and As(CN)3 Edwards, H. G. M.; Ingman, J. S.; Long, D. A. Spectrochimica Acta Part A: Molecular Spectroscopy, Vol. 32, Issue 4 https://doi.org/10.1016/0584-8539(76)80141-9	journal	January 1976
Vibrational frequencies and structural determination of phosphorous tricyanide Jensen, James O. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 60, Issue 11 https://doi.org/10.1016/j.saa.2003.12.032	journal	September 2004
Vibrational spectra, force constants and conformations of molecules of trivalent tricoordinate phosphorus compounds Katsyuba, Sergei A. Russian Chemical Reviews, Vol. 69, Issue 9 https://doi.org/10.1070/RC2000v069n09ABEH000551	journal	September 2000
The infrared and Raman spectra of ClC(CN)3 and the [C(CN)3]− ion Miller, Foil A.; Baer, William K. Spectrochimica Acta, Vol. 19, Issue 1 https://doi.org/10.1016/0371-1951(63)80094-6	journal	January 1963
The Raman and i.r. spectra of methyl phosphorus dicyanide and methyl arsenic dicyanide Edwards, H. G. M.; Ingman, J. S.; Long, D. A. Spectrochimica Acta Part A: Molecular Spectroscopy, Vol. 32, Issue 4 https://doi.org/10.1016/0584-8539(76)80142-0	journal	January 1976
Phase Transitions and Thermodynamic Properties of Rubidium and Cesium Cyanides Sugisaki, Masayasu; Matsuo, Takasuke; Suga, Hiroshi Bulletin of the Chemical Society of Japan, Vol. 41, Issue 8 https://doi.org/10.1246/bcsj.41.1747	journal	August 1968
Neutron diffraction study of KCN III and KCN IV at high pressure Decker, D. L.; Beyerlein, R. A.; Roult, G. Physical Review B, Vol. 10, Issue 8 https://doi.org/10.1103/PhysRevB.10.3584	journal	October 1974
Crystal structure of rubidium cyanide at 4 K determined by neutron powder diffraction Rowe, J. M.; Rush, J. J.; Lüty, F. Physical Review B, Vol. 29, Issue 4 https://doi.org/10.1103/PhysRevB.29.2168	journal	February 1984
High-pressure behavior of the alkali cyanides KCN and NaCN Heckathorn, J. W.; Kruger, M. B.; Gerlich, D. Physical Review B, Vol. 60, Issue 2 https://doi.org/10.1103/PhysRevB.60.979	journal	July 1999
High‐pressure Raman and x‐ray studies of the alkali cyanides up to 27 GPa Strössner, K.; Hochheimer, H. D.; Hönle, W. The Journal of Chemical Physics, Vol. 83, Issue 5 https://doi.org/10.1063/1.449289	journal	September 1985
Physical and chemical transformations of sodium cyanide at high pressures Chen, Jing-Yin; Yoo, Choong-Shik The Journal of Chemical Physics, Vol. 131, Issue 14 https://doi.org/10.1063/1.3245861	journal	October 2009
Phosphorus-carbon nuclear magnetic coupling constants in phosphorus(III) cyanides Tattershall, Bruce W. Polyhedron, Vol. 9, Issue 4 https://doi.org/10.1016/S0277-5387(00)86233-6	journal	January 1990
Calibration of the ruby pressure gauge to 800 kbar under quasi-hydrostatic conditions Mao, H. K.; Xu, J.; Bell, P. M. Journal of Geophysical Research, Vol. 91, Issue B5, p. 4673-4676 https://doi.org/10.1029/JB091iB05p04673	journal	January 1986
Two-dimensional detector software: From real detector to idealised image or two-theta scan Hammersley, A. P.; Svensson, S. O.; Hanfland, M. High Pressure Research, Vol. 14, Issue 4-6, p. 235-248 https://doi.org/10.1080/08957959608201408	journal	January 1996
ESPOIR: A Program for Solving Structures by Monte Carlo Analysis of Powder Diffraction Data Le Bail, Armel Materials Science Forum, Vol. 378-381 https://doi.org/10.4028/www.scientific.net/MSF.378-381.65	journal	October 2001
XRDA 3.1 - a program for X-ray diffraction analysis on a PC Desgreniers, S.; Lagarec, K. Journal of Applied Crystallography, Vol. 31, Issue 1 https://doi.org/10.1107/S0021889897007322	journal	February 1998
Phonons and related crystal properties from density-functional perturbation theory Baroni, Stefano; de Gironcoli, Stefano; Dal Corso, Andrea Reviews of Modern Physics, Vol. 73, Issue 2 https://doi.org/10.1103/RevModPhys.73.515	journal	July 2001
QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials Giannozzi, Paolo; Baroni, Stefano; Bonini, Nicola Journal of Physics: Condensed Matter, Vol. 21, Issue 39, Article No. 395502 https://doi.org/10.1088/0953-8984/21/39/395502	journal	September 2009
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Soft self-consistent pseudopotentials in a generalized eigenvalue formalism Vanderbilt, David Physical Review B, Vol. 41, Issue 11, p. 7892-7895 https://doi.org/10.1103/PhysRevB.41.7892	journal	April 1990
Chemical and phase transformations of cyanogen at high pressures Yoo, Choong Shik; Nicol, Malcolm The Journal of Physical Chemistry, Vol. 90, Issue 25 https://doi.org/10.1021/j100283a028	journal	December 1986
Pressure-induced phase transition and polymerization of tetracyanoethylene (TCNE) Tomasino, Dane; Chen, Jing-Yin; Kim, Minesob The Journal of Chemical Physics, Vol. 138, Issue 9 https://doi.org/10.1063/1.4793710	journal	March 2013
K ₃ Fe(CN) ₆ : Pressure-Induced Polymerization and Enhanced Conductivity Li, Kuo; Zheng, Haiyan; Ivanov, Ilia N. The Journal of Physical Chemistry C, Vol. 117, Issue 46 https://doi.org/10.1021/jp407429z	journal	November 2013
Raman spectroscopic study of high-pressure behavior of ${Ag}_{3}$ [Co(CN) $_{6}$ ] Rao, Rekha; Achary, S. N.; Tyagi, A. K. Physical Review B, Vol. 84, Issue 5 https://doi.org/10.1103/PhysRevB.84.054107	journal	August 2011
Large negative linear compressibility of Ag3[Co(CN)6] Goodwin, A. L.; Keen, D. A.; Tucker, M. G. Proceedings of the National Academy of Sciences, Vol. 105, Issue 48 https://doi.org/10.1073/pnas.0804789105	journal	November 2008
Solid state polymerization of cyanoacetylene into conjugated linear chains under pressure Aoki, K.; Kakudate, Y.; Yoshida, M. The Journal of Chemical Physics, Vol. 91, Issue 2 https://doi.org/10.1063/1.457130	journal	July 1989
Optical modes of t r a n s ‐polyacetylene Schügerl, F. B.; Kuzmany, H. The Journal of Chemical Physics, Vol. 74, Issue 2 https://doi.org/10.1063/1.441151	journal	January 1981
Graphitic network models of ‘‘diamondlike’’ carbon Tamor, M. A.; Wu, C. H. Journal of Applied Physics, Vol. 67, Issue 2 https://doi.org/10.1063/1.345808	journal	January 1990
Resonant Raman spectroscopy of disordered, amorphous, and diamondlike carbon Ferrari, A. C.; Robertson, J. Physical Review B, Vol. 64, Issue 7 https://doi.org/10.1103/PhysRevB.64.075414	journal	July 2001
Modeling studies of amorphous carbon Beeman, D.; Silverman, J.; Lynds, R. Physical Review B, Vol. 30, Issue 2 https://doi.org/10.1103/PhysRevB.30.870	journal	July 1984
Symmetry breaking in nitrogen-doped amorphous carbon: Infrared observation of the Raman-active G and D bands Kaufman, J. H.; Metin, S.; Saperstein, D. D. Physical Review B, Vol. 39, Issue 18 https://doi.org/10.1103/PhysRevB.39.13053	journal	June 1989
Superhard and Elastic Carbon Nitride Thin Films Having Fullerenelike Microstructure Sjöström, H.; Stafström, S.; Boman, M. Physical Review Letters, Vol. 75, Issue 7 https://doi.org/10.1103/physrevlett.75.1336	journal	August 1995
Role of nitrogen in the formation of hard and elastic ${CN}_{x}$ thin films by reactive magnetron sputtering Hellgren, Niklas; Johansson, Mats P.; Broitman, Esteban Physical Review B, Vol. 59, Issue 7 https://doi.org/10.1103/PhysRevB.59.5162	journal	February 1999
Ultraviolet and visible Raman studies of nitrogenated tetrahedral amorphous carbon films Shi, J. R.; Shi, X.; Sun, Z. Thin Solid Films, Vol. 366, Issue 1-2 https://doi.org/10.1016/S0040-6090(00)00732-X	journal	May 2000
Triggering dynamics of the high-pressure benzene amorphization Ciabini, Lucia; Santoro, Mario; Gorelli, Federico A. Nature Materials, Vol. 6, Issue 1 https://doi.org/10.1038/nmat1803	journal	December 2006
High-pressure polymerization of phenylacetylene and of the benzene and acetylene moieties Santoro, Mario; Ciabini, Lucia; Bini, Roberto Journal of Raman Spectroscopy, Vol. 34, Issue 7-8 https://doi.org/10.1002/jrs.1024	journal	January 2003
Molecules under extreme conditions: Chemical reactions at high pressure Schettino, Vincenzo; Bini, Roberto Physical Chemistry Chemical Physics, Vol. 5, Issue 10 https://doi.org/10.1039/b301381b	journal	January 2003
Benzene bridges under pressure McMillan, Paul F. Nature Materials, Vol. 6, Issue 1 https://doi.org/10.1038/nmat1815	journal	January 2007
Calculated high‐pressure properties of solid acetylene and possible polymerization paths LeSar, R. The Journal of Chemical Physics, Vol. 86, Issue 3 https://doi.org/10.1063/1.452238	journal	February 1987
Revisiting the Electronic Structure of Phosphazenes Chaplin, Adrian B.; Harrison, John A.; Dyson, Paul J. Inorganic Chemistry, Vol. 44, Issue 23 https://doi.org/10.1021/ic0511266	journal	November 2005
Structure and Conformation of the Medium-Sized Chlorophosphazene Rings Bowers, David J.; Wright, Brian D.; Scionti, Vincenzo Inorganic Chemistry, Vol. 53, Issue 17 https://doi.org/10.1021/ic500272b	journal	August 2014
Synthesis of a New Class of Fused Cyclotetraphosphazene Ring Systems Beşli, Serap; Mutlu, Ceylan; İbişoğlu, Hanife Inorganic Chemistry, Vol. 54, Issue 1 https://doi.org/10.1021/ic5025235	journal	December 2014

Cited By (2)

Carbodiphosphorane mediated synthesis of a triflyloxyphosphonium dication and its reactivity towards nucleophiles Yogendra, S.; Hennersdorf, F.; Bauzá, A. Chemical Communications, Vol. 53, Issue 20 https://doi.org/10.1039/c7cc00982h	journal	January 2017
From Molecules to Carbon Materials—High Pressure Induced Polymerization and Bonding Mechanisms of Unsaturated Compounds Yang, Xin; Wang, Xuan; Wang, Yida Crystals, Vol. 9, Issue 10 https://doi.org/10.3390/cryst9100490	journal	September 2019

Similar Records

Pressure-induced polymerization of P(CN){sub 3}

Journal Article · Thu May 21 00:00:00 EDT 2015 · Journal of Chemical Physics · OSTI ID:1338321

Gou, Huiyang; Kim, Duck Young; Yonke, Brendan L.; +2 more

Pressure-Induced Polymerization of LiN(CN)₂

Journal Article · Fri Oct 28 00:00:00 EDT 2016 · Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory · OSTI ID:1338321

Keefer, Derek W.; Gou, Huiyang; Purdy, Andrew P.; +4 more

Tetracyanomethane under Pressure: Extended CN Polymers from Precursors with Built-in sp³ Centers

Journal Article · Mon Feb 12 00:00:00 EST 2018 · Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory · OSTI ID:1338321

Keefer, Derek W.; Gou, Huiyang; Wang, Qianqian; +6 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Pressure-induced polymerization of P(CN) 3

Citation Formats

References (79)

Cited By (2)

Similar Records

Related Subjects

Title: Pressure-induced polymerization of P(CN) ₃