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Title: Voltammetry Method Evaluation

Technical Report ·
DOI:https://doi.org/10.2172/1326966· OSTI ID:1326966
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  1. Argonne National Lab. (ANL), Argonne, IL (United States)

The purpose of the ANL MPACT Voltammetry project is to evaluate the suitability of previously developed cyclic voltammetry techniques to provide electroanalytical measurements of actinide concentrations in realistic used fuel processing scenarios. The molten salts in these scenarios are very challenging as they include high concentrations of multiple electrochemically active species, thereby creating a variety of complications. Some of the problems that arise therein include issues related to uncompensated resistance, cylindrical diffusion, and alloying of the electrodeposited metals. Improvements to the existing voltammetry technique to account for these issues have been implemented, resulting in good measurements of actinide concentrations across a wide range of adverse conditions.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE Office of Nuclear Energy (NE), Fuel Cycle Technologies (NE-5)
DOE Contract Number:
AC02-06CH11357
OSTI ID:
1326966
Report Number(s):
FCRD-MPACT-2016-000401; 129349; TRN: US1700301
Country of Publication:
United States
Language:
English