Magnetic and magnetocaloric properties of iron subs tituted holmium chromite and dysprosium chromite

Yin, Shiqi; Sharma, Vinit; McDannald, Austin; Reboredo, Fernando A.; Jain, Menka

doi:10.1039/C5RA24323H

Title: Magnetic and magnetocaloric properties of iron subs tituted holmium chromite and dysprosium chromite

Journal Article · Mon Jan 11 00:00:00 EST 2016 · RSC Advances

DOI:https://doi.org/10.1039/C5RA24323H· OSTI ID:1324067

Yin, Shiqi ^[1]; Sharma, Vinit ^[2]; McDannald, Austin ^[1]; Reboredo, Fernando A. ^[2]; Jain, Menka ^[1]

Univ. of Connecticut, Storrs, CT (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

In this work, structural, magnetic, and magnetocaloric properties of HoCrO₃ and Fe substituted HoCrO₃ and DyCrO₃ (i.e. HoCr_0.7Fe_0.3O₃ and DyCr_0.7Fe_0.3O₃) powder samples were synthesized via a solution route. The structural properties of the samples were examined by Raman spectroscopy and x-ray diffraction techniques, which were further confirmed using first-principle calculations. The dc magnetic measurements indicate that the Cr³⁺ ordering temperatures for the HoCrO₃, HoCr_0.7Fe_0.3O₃, and DyCr_0.7Fe_0.3O₃ samples are 140 K, 174 K, and 160 K, respectively. The ac magnetic measurements not only confirmed the Cr₃₊ ordering transitions in these samples (obtained using dc magnetic measurements), but also clearly showed the Ho³⁺ ordering at ~10 K in the present HoCrO₃ and HoCr_0.7Fe_0.3O₃ samples, which to our knowledge, is the first ac magnetic evidence of Ho³⁺ ordering in this system. The effective magnetic moments were determined to be 11.67μB, 11.30μB, and 11.27μB for the HoCrO₃, HoCr_0.7Fe_0.3O₃, and DyCr_0.7Fe_0.3O₃ samples, respectively. For the first time, the magnetocaloric properties of HoCrO₃ and HoCr_0.7Fe_0.3O₃ were studied here, showing their potential for applications in magnetic refrigeration. In an applied dc magnetic field of 7 T, the maximum magnetocaloric value were determined to be 7.2 (at 20 K), 6.83 (at 20 K), 13.08 J/kg K (at 5 K) and the relative cooling power were 408, 387, and 500 J/kg for the HoCrO₃, HoCr_0.7Fe_0.3O₃, and DyCr_0.7Fe_0.3O₃ samples, respectively.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Oak Ridge Leadership Computing Facility (OLCF)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1324067

Journal Information:: RSC Advances, Vol. 6, Issue 12; ISSN 2046-2069

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 38 works

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