Thermal evolution of the metastable r8 and bc8 polymorphs of silicon

Haberl, Bianca; Guthrie, Malcolm; Sinogeikin, Stanislav V.; Shen, Guoyin; Williams, James S.; Bradby, Jodie E.

doi:10.1080/08957959.2014.1003555

Title: Thermal evolution of the metastable r8 and bc8 polymorphs of silicon

Journal Article · Wed Jan 28 00:00:00 EST 2015 · High Pressure Research

DOI:https://doi.org/10.1080/08957959.2014.1003555· OSTI ID:1286830

Haberl, Bianca ^[1]; Guthrie, Malcolm ^[2]; Sinogeikin, Stanislav V. ^[3]; Shen, Guoyin ^[3]; Williams, James S. ^[1]; Bradby, Jodie E. ^[1]

Australian National Univ., Canberra, ACT (Australia)
Carnegie Inst. of Science, Washington, DC (United States)
Carnegie Inst. of Washington, Argonne, IL (United States). Geophysical Lab.

The kinetics of two metastable polymorphs of silicon under thermal annealing was investigated. These phases with body-centered cubic bc8 and rhombohedral r8 structures can be formed upon pressure release from metallic silicon.We study these metastable polymorphs were formed by two different methods, via point loading and in a diamond anvil cell (DAC). Upon thermal annealing different transition pathways were detected. In the point loading case, the previously reported Si-XIII formed and was confirmed as a new phase with an as-yet-unidentified structure. In the DAC case, bc8-Si transformed to the hexagonal-diamond structure at elevated pressure, consistent with previous studies at ambient pressure. In contrast, r8-Si transformed directly to diamond-cubic Si at a temperature of 255⁰C. In conclusion, these data were used to construct diagrams of the metastability regimes of the polymorphs formed in a DAC and may prove useful for potential technological applications of these metastable polymorphs.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS); Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research in Extreme Environments (EFree)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725; SC0001057

OSTI ID:: 1286830

Journal Information:: High Pressure Research, Vol. 35, Issue 2; ISSN 0895-7959

Publisher:: Taylor & FrancisCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 26 works

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Thermal evolution of the indentation-induced phases of silicon Wong, S.; Johnson, B. C.; Haberl, B. Journal of Applied Physics, Vol. 126, Issue 10 https://doi.org/10.1063/1.5108751	journal	September 2019
Shear-driven phase transformation in silicon nanowires Vincent, L.; Djomani, D.; Fakfakh, M. Nanotechnology, Vol. 29, Issue 12 https://doi.org/10.1088/1361-6528/aaa738	journal	February 2018
High-pressure studies with x-rays using diamond anvil cells Shen, Guoyin; Mao, Ho Kwang Reports on Progress in Physics, Vol. 80, Issue 1 https://doi.org/10.1088/1361-6633/80/1/016101	journal	November 2016

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36 MATERIALS SCIENCE
pressure-induced transitions
metastable polymorphs
silicon
in situ annealing

Title: Thermal evolution of the metastable r8 and bc8 polymorphs of silicon

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