Magnetic structure and magnetocalorics of GdPO4

Palacios, E.; Rodriguez-Velamazsn, J. A.; Evangelisti, Marco; McIntyre, G. J.; Lorusso, G.; Visser, Dirk; de Jongh, L. Jos; Boatner, Lynn A.

doi:10.1103/PhysRevB.90.214423

Title: Magnetic structure and magnetocalorics of ${GdPO}_{4}$

Journal Article · Fri Dec 12 00:00:00 EST 2014 · Physical Review. B, Condensed Matter and Materials Physics

DOI:https://doi.org/10.1103/PhysRevB.90.214423· OSTI ID:1286793

Palacios, E. ^[1]; Rodriguez-Velamazsn, J. A. ^[2]; Evangelisti, Marco ^[1]; McIntyre, G. J. ^[3]; Lorusso, G. ^[1]; Visser, Dirk ^[4]; de Jongh, L. Jos ^[5]; Boatner, Lynn A. ^[6]

CSIC - Univ. of Zaragoza, Zaragoza (Spain)
CSIC - Univ. of Zaragoza, Zaragoza (Spain); Institut Laue-Langevin (ILL), Grenoble (France)
Institut Laue-Langevin (ILL), Grenoble (France); Australian Nuclear Science and Technology Organization, Lucas Heights, NSW (Australia)
Rutherford Appleton Lab., Didcot (United Kingdom); Delft Univ. of Technology, Delft (The Netherlands)
Leiden Univ., Leiden (The Netherlands)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

The magnetic ordering structure of GdPO₄ is determined at T = 60 mK by diffraction of hot neutrons with wavelength = 0.4696 Å. It corresponds to a non-collinear antiferromagnetic arrangement of the Gd moments with propagation vector k = (1/2, 0, 1/2). This arrangement is found to minimize the dipole-dipole interaction and the crystal field anisotropy energy, the magnetic superexchange being much smaller. The intensity of the magnetic reflections decreases with increasing temperature and vanishes at T ≈ 0.8 K, in agreement with the magnetic ordering temperature T_N = 0.77 K, as reported in previous works based on heat capacity and magnetic susceptibility measurements. The magnetocaloric parameters have been determined from heat capacity data at constant applied fields up to 7 T, as well as from isothermal magnetization data. Lastly, the magnetocaloric effect, for a field change ΔB = 0 – 7T, reaches –ΔS_T = 375.8mJ / cm³K^–1 at T = 2.1 K, largely exceeding the maximum values reported to date for Gd-based magnetic refrigerants.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1286793

Alternate ID(s):: OSTI ID: 1180469

Journal Information:: Physical Review. B, Condensed Matter and Materials Physics, Vol. 90, Issue 21; ISSN 1098-0121

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 87 works

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High-performance low-temperature magnetic refrigerants made of gadolinium-hydroxy-chloride Wang, Yanyan; Qin, Lei; Zhou, Guo-Jun Journal of Materials Chemistry C, Vol. 4, Issue 27 https://doi.org/10.1039/c6tc01291d	journal	January 2016
A novel alb metalloring organic framework with a {Ni ₁₂ Gd ₂₄ } cage exhibiting a significant magnetocaloric effect Feng, Ya-Nan; Tian, Chong-Bin; Du, Shao-Wu Dalton Transactions, Vol. 46, Issue 31 https://doi.org/10.1039/c7dt02358h	journal	January 2017
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Ferromagnetic Ising chains in frustrated LnODCO ₃ : the influence of magnetic structure in magnetocaloric frameworks Dixey, Richard J. C.; Stenning, Gavin B. G.; Manuel, Pascal Journal of Materials Chemistry C, Vol. 7, Issue 42 https://doi.org/10.1039/c9tc04980k	journal	January 2019
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Features of the Low-Temperature Heat Capacity of Er3 –xTmxAl5O12 Garnet Single Crystals Charnaya, E. V.; Shevchenko, E. V.; Khazanov, E. N. Journal of Communications Technology and Electronics, Vol. 64, Issue 8 https://doi.org/10.1134/s1064226919070064	journal	August 2019

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