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Title: Novel cross-linked polystyrenes with large space network as tailor-made catalyst supports for sustainable media

Journal Article · · European Polymer Journal
 [1];  [2];  [1];  [3];  [2];  [3];  [3];  [1];  [2];  [1]
  1. Univ. of Perugia (Italy)
  2. Hasselt Univ., Diepenbeek (Belgium)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
+ Show Author Affiliations

For a novel class of polystyrene-based gel-type resins (SPACeR, SP), containing the large 1,4-bis (4-vinylphenoxy)benzene cross-linker, is introduced; SP-immobilized 1,5,7-triazabicyclo [4.4.0]dec-5-ene (TBD) and triethylamine (TEA) bases are synthesized and characterized in terms of their structural, thermal and morphological features, and their catalytic efficiency in a series of fundamental chemical transformations under solvent-free conditions is investigated.

Research Organization:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Sponsoring Organization:
USDOE Office of Science (SC)
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1265889
Journal Information:
European Polymer Journal, Vol. 73, Issue C; ISSN 0014-3057
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 26 works
Citation information provided by
Web of Science

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Cited By (7)

Chiral catalysts immobilized on achiral polymers: effect of the polymer support on the performance of the catalyst journal January 2018
A tailored polymeric cationic tag–anionic Pd( ii ) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL journal January 2019
A continuous flow approach for the C–H functionalization of 1,2,3-triazoles in γ-valerolactone as a biomass-derived medium journal January 2018
Boosting biomass valorisation. Synergistic design of continuous flow reactors and water-tolerant polystyrene acid catalysts for a non-stop production of esters journal January 2018
Synthesis of β-Cyano Ketones Promoted by a Heterogeneous Fluoride Catalyst journal June 2016
Synthesis, characterization and catalytic activity of novel large network polystyrene-immobilized organic bases journal January 2015
Poly(vinylbenzyl chloride- co -divinyl benzene) polyHIPE monolith-supported o -hydroxynaphthaldehyde propylenediamine Schiff base ligand complex of copper( ii ) ions as a catalyst for the epoxidation of cyclohexene journal January 2019

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