Rapid and enhanced activation of microporous coordination polymers by flowing supercritical CO.sub.2
Patent
·
OSTI ID:1264476
Flowing supercritical CO.sub.2 is used to activate metal organic framework materials (MOF). MOFs are activated directly from N,N-dimethylformamide (DMF) thus avoiding exchange with a volatile solvent. Most MCPs display increased surface areas directly after treatment although those with coordinatively unsaturated metal centers benefit from additional heating.
- Research Organization:
- Univ. of Michigan, Ann Arbor, MI (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- SC0004888
- Assignee:
- The Regents Of The University Of Michigan (Ann Arbor, MI)
- Patent Number(s):
- 9,393,548
- Application Number:
- 14/139,184
- OSTI ID:
- 1264476
- Resource Relation:
- Patent File Date: 2013 Dec 23
- Country of Publication:
- United States
- Language:
- English
Correlation and Prediction of the Solubility of CO2 in a Mixture of Organic Solution Solvents
|
journal | May 2005 |
Stepwise and hysteretic sorption of N 2 , O 2 , CO 2 , and H 2 gases in a porous metal–organic framework [Zn2(BPnDC)2(bpy)]
|
journal | January 2010 |
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