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Title: One-dimensional cold cap model for melters with bubblers

Journal Article · · Journal of the American Ceramic Society
DOI:https://doi.org/10.1111/jace.13775· OSTI ID:1259504
 [1];  [2];  [2];  [2];  [3];  [4];  [2]
  1. Univ. of Chemistry and Technology Prague, Prague (Czech Republic)
  2. Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
  3. Idaho National Lab. (INL), Idaho Falls, ID (United States)
  4. U.S. Dept. of Energy, Richland, WA (United States)

The rate of glass production during vitrification in an all-electrical melter greatly impacts the cost and schedule of nuclear waste treatment and immobilization. The feed is charged to the melter on the top of the molten glass, where it forms a layer of reacting and melting material, called the cold cap. During the final stages of the batch-to-glass conversion process, gases evolved from reactions produce primary foam, the growth and collapse of which controls the glass production rate. The mathematical model of the cold cap was revised to include functional representation of primary foam behavior and to account for the dry cold cap surface. The melting rate is computed as a response to the dependence of the primary foam collapse temperature on the heating rate and melter operating conditions, including the effect of bubbling on the cold cap bottom and top surface temperatures. The simulation results are in good agreement with experimental data from laboratory-scale and pilot-scale melter studies. Lastly, the cold cap model will become part of the full three-dimensional mathematical model of the waste glass melter.

Research Organization:
Idaho National Laboratory (INL), Idaho Falls, ID (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
AC07-05ID14517
OSTI ID:
1259504
Alternate ID(s):
OSTI ID: 1401148
Report Number(s):
INL/JOU-15-34746
Journal Information:
Journal of the American Ceramic Society, Vol. 98, Issue 10; ISSN 0002-7820
Publisher:
American Ceramic SocietyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 36 works
Citation information provided by
Web of Science

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Cited By (8)

Foaming during nuclear waste melter feeds conversion to glass: Application of evolved gas analysis journal April 2018
Heat transfer from glass melt to cold cap: Effect of heating rate journal February 2019
Rheology of simulated radioactive waste slurry and cold cap during vitrification journal June 2018
Glass production rate in electric furnaces for radioactive waste vitrification journal April 2019
Heat transfer from glass melt to cold cap: Gas evolution and foaming journal April 2019
Effect of sucrose on foaming and melting behavior of a low‐activity waste melter feed journal June 2019
Viscosity of glass‐forming melt at the bottom of high‐level waste melter‐feed cold caps: Effects of temperature and incorporation of solid components journal October 2019
Modeling batch melting: Roles of heat transfer and reaction kinetics journal September 2019

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