A porous proton-relaying metal-organic framework material that accelerates electrochemical hydrogen evolution

Hod, Idan; Deria, Pravas; Bury, Wojciech; Mondloch, Joseph E.; Kung, Chung-Wei; So, Monica; Sampson, Matthew D.; Peters, Aaron W.; Kubiak, Cliff P.; Farha, Omar K.; Hupp, Joseph T.

doi:10.1038/ncomms9304

Title: A porous proton-relaying metal-organic framework material that accelerates electrochemical hydrogen evolution

Journal Article · Mon Sep 14 00:00:00 EDT 2015 · Nature Communications

DOI:https://doi.org/10.1038/ncomms9304· OSTI ID:1258602

Hod, Idan ^[1]; Deria, Pravas ^[2]; Bury, Wojciech ^[3]; Mondloch, Joseph E. ^[2]; Kung, Chung-Wei ^[4]; So, Monica ^[2]; Sampson, Matthew D. ^[5]; Peters, Aaron W. ^[6]; Kubiak, Cliff P. ^[5]; Farha, Omar K. ^[7]; Hupp, Joseph T. ^[6]

Northwestern Univ., Evanston, IL (United States); Northwestern Univ., Evanston, IL (United States). Argonne-Northwestern Solar Energy Research (ANSER) Center
Northwestern Univ., Evanston, IL (United States)
Northwestern Univ., Evanston, IL (United States); Warsaw Univ. of Technology, Warsaw (Poland)
Northwestern Univ., Evanston, IL (United States); Northwestern Univ., Evanston, IL (United States). Argonne-Northwestern Solar Energy Research (ANSER) Center; National Taiwan Univ., Taipei (Taiwan)
Univ. of California, San Diego, CA (United States)
Northwestern Univ., Evanston, IL (United States); Northwestern Univ., Evanston, IL (United States). Argonne-Northwestern Solar Energy Research (ANSER) Center
Northwestern Univ., Evanston, IL (United States); Northwestern Univ., Evanston, IL (United States). Argonne-Northwestern Solar Energy Research (ANSER) Center; King Abdulaziz Univ., Jeddah (Saudi Arabia)

The availability of efficient hydrogen evolution reaction (HER) catalysts is of high importance for solar fuel technologies aimed at reducing future carbon emissions. Even though Pt electrodes are excellent HER electrocatalysts, commercialization of large-scale hydrogen production technology requires finding an equally efficient, low-cost, earth-abundant alternative. Here, high porosity, metal-organic framework (MOF) films have been used as scaffolds for the deposition of a Ni-S electrocatalyst. Compared with an MOF-free Ni-S, the resulting hybrid materials exhibit significantly enhanced performance for HER from aqueous acid, decreasing the kinetic overpotential by more than 200 mV at a benchmark current density of 10 mA cm^-2. In conclusion, although the initial aim was to improve electrocatalytic activity by greatly boosting the active area of the Ni-S catalyst, the performance enhancements instead were found to arise primarily from the ability of the proton-conductive MOF to favourably modify the immediate chemical environment of the sulfide-based catalyst.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Energy Frontier Research Centers (EFRC) (United States). Argonne-Northwestern Solar Energy Research Center (ANSER)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0001059

OSTI ID:: 1258602

Journal Information:: Nature Communications, Vol. 6; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 197 works

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Catalysis and photocatalysis by metal organic frameworks Dhakshinamoorthy, Amarajothi; Li, Zhaohui; Garcia, Hermenegildo Chemical Society Reviews, Vol. 47, Issue 22 https://doi.org/10.1039/c8cs00256h	journal	January 2018
Insights into the mechanism and aging of a noble-metal free H ₂ -evolving dye-sensitized photocathode Kaeffer, Nicolas; Windle, Christopher D.; Brisse, Romain Chemical Science, Vol. 9, Issue 32 https://doi.org/10.1039/c8sc00899j	journal	January 2018
Copper-modulated bismuth nanocrystals alter the formate formation pathway to achieve highly selective CO ₂ electroreduction Zu, Meng Yang; Zhang, Le; Wang, Chongwu Journal of Materials Chemistry A, Vol. 6, Issue 35 https://doi.org/10.1039/c8ta05355c	journal	January 2018
Facile synthesis of amorphous MoS _x –Fe anchored on Zr-MOFs towards efficient and stable electrocatalytic hydrogen evolution Zhang, Le; Yan, Zhenhua; Chen, Xiang Chemical Communications, Vol. 56, Issue 18 https://doi.org/10.1039/c9cc08771k	journal	January 2020
An efficient bifunctional electrocatalyst based on a nickel iron layered double hydroxide functionalized Co ₃ O ₄ core shell structure in alkaline media Tahira, Aneela; Ibupoto, Zafar Hussain; Vagin, Mikhail Catalysis Science & Technology, Vol. 9, Issue 11 https://doi.org/10.1039/c9cy00351g	journal	January 2019
Electrodeposition of sulfur-engineered amorphous nickel hydroxides on MIL-53(Fe) nanosheets to accelerate the oxygen evolution reaction Wu, Fang; Guo, Xiaoxue; Hao, Gazi Nanoscale, Vol. 11, Issue 31 https://doi.org/10.1039/c9nr03430g	journal	January 2019
Co ₉ S ₈ embedded into N/S doped carbon composites: in situ derivation from a sulfonate-based metal–organic framework and its electrochemical properties Chen, Lin; Yang, Wenjuan; Li, Xiaoyu Journal of Materials Chemistry A, Vol. 7, Issue 17 https://doi.org/10.1039/c9ta01433k	journal	January 2019
On the potential for nanoscale metal–organic frameworks for energy applications Kuyuldar, Seher; Genna, Douglas T.; Burda, Clemens Journal of Materials Chemistry A, Vol. 7, Issue 38 https://doi.org/10.1039/c9ta09896h	journal	January 2019
Metal-Organic Frameworks-Based Electrocatalysis: Insight and Future Perspectives Li, Xinlin; Maindan, Karan; Deria, Pravas Comments on Inorganic Chemistry, Vol. 38, Issue 5 https://doi.org/10.1080/02603594.2018.1545225	journal	September 2018
Artificial photosynthesis with metal and covalent organic frameworks (MOFs and COFs): challenges and prospects in fuel‐forming electrocatalysis Heidary, Nina; Harris, Tomos G. A. A.; Ly, Khoa H. Physiologia Plantarum, Vol. 166, Issue 1 https://doi.org/10.1111/ppl.12935	journal	March 2019
Metal–Organic Framework Thin Film-Based Dye Sensitized Solar Cells with Enhanced Photocurrent Ahmad, Shargeel; Liu, Jinxuan; Ji, Wei Materials, Vol. 11, Issue 10 https://doi.org/10.3390/ma11101868	journal	October 2018
Mechanochemically Assisted Synthesis of a Ru Catalyst for Hydrogen Evolution with Performance Superior to Pt in Both Acidic and Alkaline Media Li, Feng; Han, Gao-Feng; Noh, Hyuk-Jun Advanced Materials, Vol. 30, Issue 44 https://doi.org/10.1002/adma.201803676	journal	September 2018
Metal–Organic Framework Based Catalysts for Hydrogen Evolution Zhu, Bingjun; Zou, Ruqiang; Xu, Qiang Advanced Energy Materials, Vol. 8, Issue 24 https://doi.org/10.1002/aenm.201801193	journal	June 2018
POM & MOF-based Electrocatalysts for Energy-related Reactions Freire, Cristina; Fernandes, Diana M.; Nunes, Marta ChemCatChem, Vol. 10, Issue 8 https://doi.org/10.1002/cctc.201701926	journal	March 2018
Pristine Transition‐Metal‐Based Metal‐Organic Frameworks for Electrocatalysis Sun, Fancheng; Li, Qing; Xue, Huaiguo ChemElectroChem, Vol. 6, Issue 5 https://doi.org/10.1002/celc.201801520	journal	January 2019
Hierarchical Cobalt-Based Metal-Organic Framework for High-Performance Lithium-Ion Batteries Chen, Lin; Yang, Wenjuan; Wang, Jianbiao Chemistry - A European Journal, Vol. 24, Issue 50 https://doi.org/10.1002/chem.201802629	journal	August 2018
Copper-Based Metal-Organic Porous Materials for CO ₂ Electrocatalytic Reduction to Alcohols Albo, Jonathan; Vallejo, Daniel; Beobide, Garikoitz ChemSusChem, Vol. 10, Issue 6 https://doi.org/10.1002/cssc.201600693	journal	August 2016
State-of-the-Art Advances and Perspectives for Electrocatalysis Ramohlola, Kabelo E.; Hato, Mpitloane J.; Monama, Gobeng R. Methods for Electrocatalysis: Advanced Materials and Allied Applications, p. 311-352 https://doi.org/10.1007/978-3-030-27161-9_13	book	January 2020
Metal–Organic Frameworks for Electrocatalysis Usman, Muhammad; Zhu, Qi-Long Methods for Electrocatalysis: Advanced Materials and Allied Applications, p. 29-66 https://doi.org/10.1007/978-3-030-27161-9_2	book	January 2020
Missing-linker metal-organic frameworks for oxygen evolution reaction Xue, Ziqian; Liu, Kang; Liu, Qinglin Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-13051-2	journal	November 2019
Electrocatalytic water oxidation by a molecular catalyst incorporated into a metal–organic framework thin film Johnson, Ben A.; Bhunia, Asamanjoy; Ott, Sascha Dalton Transactions, Vol. 46, Issue 5 https://doi.org/10.1039/c6dt03718f	journal	January 2017
Dielectric relaxation and anhydrous proton conduction in [C ₂ H ₅ NH ₃ ][Na _0.5 Fe _0.5 (HCOO) ₃ ] metal–organic frameworks Sieradzki, A.; Pawlus, S.; Tripathy, S. N. Dalton Transactions, Vol. 46, Issue 11 https://doi.org/10.1039/c6dt04546d	journal	January 2017
Polymeric coatings for applications in electrocatalytic and photoelectrosynthetic fuel production Wadsworth, B. L.; Khusnutdinova, D.; Moore, G. F. Journal of Materials Chemistry A, Vol. 6, Issue 44 https://doi.org/10.1039/c8ta05805a	journal	January 2018
Metal/covalent–organic frameworks-based electrocatalysts for water splitting Yan, Ya; He, Ting; Zhao, Bin Journal of Materials Chemistry A, Vol. 6, Issue 33 https://doi.org/10.1039/c8ta05985c	journal	January 2018
A metal–organic framework film with a switchable anodic and cathodic behaviour in a photo-electrochemical cell Ifraemov, Raya; Shimoni, Ran; He, Wenhui Journal of Materials Chemistry A, Vol. 7, Issue 7 https://doi.org/10.1039/c8ta10483b	journal	January 2019
Accelerated proton transmission in metal–organic frameworks for the efficient reduction of CO ₂ in aqueous solutions Mao, Fangxin; Jin, Yan-Huan; Liu, Peng Fei Journal of Materials Chemistry A, Vol. 7, Issue 40 https://doi.org/10.1039/c9ta07967j	journal	January 2019
Metal-organic frameworks and their derived materials for electrochemical energy storage and conversion: Promises and challenges Wu, Hao Bin; Lou, Xiong Wen (David) Science Advances, Vol. 3, Issue 12 https://doi.org/10.1126/sciadv.aap9252	journal	December 2017
Metal–Organic Frameworks Toward Electrocatalytic Applications Li, Jun-Hong; Wang, Yi-Sen; Chen, Yu-Chuan Applied Sciences, Vol. 9, Issue 12 https://doi.org/10.3390/app9122427	journal	June 2019
Metal‐Organic Frameworks for Hydrogen Energy Applications: Advances and Challenges Bakuru, Vasudeva Rao; DMello, Marilyn Esclance; Kalidindi, Suresh Babu ChemPhysChem, Vol. 20, Issue 10 https://doi.org/10.1002/cphc.201801147	journal	March 2019
The organic-moiety-dominated Li ⁺ intercalation/deintercalation mechanism of a cobalt-based metal–organic framework Li, Chao; Hu, Xiaoshi; Lou, Xiaobing Journal of Materials Chemistry A, Vol. 4, Issue 41 https://doi.org/10.1039/c6ta06413b	journal	January 2016
MOF derived carbon based nanocomposite materials as efficient electrocatalysts for oxygen reduction and oxygen and hydrogen evolution reactions Bhattacharyya, Sohini; Das, Chayanika; Maji, Tapas Kumar RSC Advances, Vol. 8, Issue 47 https://doi.org/10.1039/c8ra05102j	journal	January 2018
Insights into the mechanism and aging of a noble-metal free H-2-evolving dye-sensitized photocathode Kaeffer, Nicolas; Windle, Christopher D.; Brisse, Romain ETH Zurich https://doi.org/10.3929/ethz-b-000286962	text	January 2018
Enhanced Charge Collection in MOF-525-PEDOT Nanotube Composites Enable Highly Sensitive Biosensing Huang, Tzu-Yen; Kung, Chung-Wei; Liao, Yu-Te Advanced Science, Vol. 4, Issue 11 https://doi.org/10.1002/advs.201700261	journal	September 2017
Advanced Electrocatalysts Based on Metal–Organic Frameworks Zheng, Fuqin; Zhang, Ziwei; Zhang, Chunmei ACS Omega, Vol. 5, Issue 6 https://doi.org/10.1021/acsomega.9b03295	journal	December 2019

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