Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000

Wang, Timothy C.; Vermeulen, Nicolaas A.; Kim, In Soo; Martinson, Alex B. F.; Stoddart, J. Fraser; Hupp, Joseph T.; Farha, Omar K.

doi:10.1038/nprot.2016.001

Title: Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000

Journal Article · Thu Dec 17 00:00:00 EST 2015 · Nature Protocols

DOI:https://doi.org/10.1038/nprot.2016.001· OSTI ID:1249523

^[1]; Vermeulen, Nicolaas A. ^[1]; Kim, In Soo ^[2]; Martinson, Alex B. F. ^[2]; Stoddart, J. Fraser ^[1]; Hupp, Joseph T. ^[1]; Farha, Omar K. ^[3]

Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry; King Abdulaziz Univ., Jeddah (Saudi Arabia). Dept. of Chemistry

The synthesis of NU-1000, a mesoporous metal-organic framework (MOF), can be conducted efficiently on a multigram scale from inexpensive starting materials. NU-1000 has been reported as an excellent candidate for gas separation and catalysis. In particular, it is ideal for the catalytic deactivation of nerve agents and shows great promise as a new generic platform for a wide range of applications. Multiple post-synthetic modification protocols have been developed using NU-1000 as the parent material, making it a potentially useful scaffold for several catalytic applications. The procedure for the preparation of NU-1000 can be scaled up reliably, and it is suitable for the production of 50 g of the tetracarboxylic acid containing organic linker and 200 mg–2.5 g of NU-1000. Lastly, the entire synthesis is performed without purification by column chromatography and can be completed within 10 d.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; SC0012702

OSTI ID:: 1249523

Journal Information:: Nature Protocols, Vol. 11, Issue 1; ISSN 1754-2189

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 220 works

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