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Title: Recent progress in the synthesis of metal–organic frameworks

Journal Article · · Science and Technology of Advanced Materials
 [1];  [1]
  1. Texas A & M Univ., College Station, TX (United States)

Research Organization:
Texas A & M Univ., College Station, TX (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0001015
OSTI ID:
1239842
Alternate ID(s):
OSTI ID: 1387383
Journal Information:
Science and Technology of Advanced Materials, Vol. 16, Issue 5; ISSN 1468-6996
Publisher:
IOP PublishingCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 137 works
Citation information provided by
Web of Science

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Hydrogen adsorption in the nanoporous metal-benzenedicarboxylate M(OH)(O 2 C–C 6 H 4 –CO 2 ) (M = Al 3+ , Cr 3+ ), MIL-53 journal January 2003
A Rationale for the Large Breathing of the Porous Aluminum Terephthalate (MIL-53) Upon Hydration journal March 2004
Different Adsorption Behaviors of Methane and Carbon Dioxide in the Isotypic Nanoporous Metal Terephthalates MIL-53 and MIL-47 journal October 2005
How Hydration Drastically Improves Adsorption Selectivity for CO2 over CH4 in the Flexible Chromium Terephthalate MIL-53 journal November 2006
Hydrogen Storage in the Giant-Pore Metal–Organic Frameworks MIL-100 and MIL-101 journal December 2006
Metal–Organic Frameworks as Efficient Materials for Drug Delivery journal September 2006
High Uptakes of CO 2 and CH 4 in Mesoporous MetalOrganic Frameworks MIL-100 and MIL-101 journal July 2008
Synthesis, Single-Crystal X-ray Microdiffraction, and NMR Characterizations of the Giant Pore Metal-Organic Framework Aluminum Trimesate MIL-100 journal December 2009
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Metal–organic framework MIL-100(Fe) for the adsorption of malachite green from aqueous solution journal January 2012
MIL-100(Al, Fe) as water adsorbents for heat transformation purposes—a promising application journal January 2012
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Catalytic properties of MIL-101 journal January 2008
Giant Pores in a Chromium 2,6-Naphthalenedicarboxylate Open-Framework Structure with MIL-101 Topology journal May 2009
Porous Chromium Terephthalate MIL-101 with Coordinatively Unsaturated Sites: Surface Functionalization, Encapsulation, Sorption and Catalysis journal May 2009
Metal-Organic Framework MIL-101 for High-Resolution Gas-Chromatographic Separation of Xylene Isomers and Ethylbenzene journal January 2010
Metal−Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature journal December 2005
Effects of Functionalization, Catenation, and Variation of the Metal Oxide and Organic Linking Units on the Low-Pressure Hydrogen Adsorption Properties of Metal−Organic Frameworks journal February 2006
Large-Pore Apertures in a Series of Metal-Organic Frameworks journal May 2012
Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg2(dobpdc) journal April 2012
Synthesis and Stability of Tagged UiO-66 Zr-MOFs journal December 2010
Water Stable Zr-Benzenedicarboxylate Metal-Organic Frameworks as Photocatalysts for Hydrogen Generation journal August 2010
Modulated Synthesis of Zr-Based Metal-Organic Frameworks: From Nano to Single Crystals journal May 2011
Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts journal August 2012
Metal–Organic Frameworks Based on Previously Unknown Zr 8 /Hf 8 Cubic Clusters journal October 2013
Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination journal October 2013
An Exceptionally Stable, Porphyrinic Zr Metal–Organic Framework Exhibiting pH-Dependent Fluorescence journal September 2013
A Highly Stable Porphyrinic Zirconium Metal–Organic Framework with shp-a Topology journal December 2014
Rigidifying Fluorescent Linkers by Metal–Organic Framework Formation for Fluorescence Blue Shift and Quantum Yield Enhancement journal May 2014
Stable metal-organic frameworks containing single-molecule traps for enzyme encapsulation journal January 2015
A Highly Stable Zeotype Mesoporous Zirconium Metal-Organic Framework with Ultralarge Pores journal November 2014
A zirconium methacrylate oxocluster as precursor for the low-temperature synthesis of porous zirconium( iv ) dicarboxylates journal January 2010
A Route to the Synthesis of Trivalent Transition-Metal Porous Carboxylates with Trimeric Secondary Building Units journal September 2004
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Facile synthesis of nano-sized metal-organic frameworks, chromium-benzenedicarboxylate, MIL-101 journal February 2011
Adsorption and Diffusion of Benzene on Chromium-Based Metal Organic Framework MIL-101 Synthesized by Microwave Irradiation journal February 2011
Carbon dioxide adsorption in microwave-synthesized metal organic framework CPM-5: Equilibrium and kinetics study journal July 2013
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Electrochemical Synthesis of Some Archetypical Zn 2+ , Cu 2+ , and Al 3+ Metal Organic Frameworks journal June 2012
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Electrochemical Film Deposition of the Zirconium Metal–Organic Framework UiO-66 and Application in a Miniaturized Sorbent Trap journal February 2015
Reusable Oxidation Catalysis Using Metal-Monocatecholato Species in a Robust Metal–Organic Framework journal March 2014
Postsynthetic Covalent Modification of a Neutral Metal−Organic Framework journal October 2007
Single-Crystalline Molecular Flasks: Chemical Transformation with Bulky Reagents in the Pores of Porous Coordination Networks journal October 2008
Tandem Modification of Metal–Organic Frameworks by a Postsynthetic Approach journal June 2008
Direct Observation of the Labile Imine Formation through Single-Crystal-to-Single-Crystal Reactions in the Pores of a Porous Coordination Network journal February 2008
Framework functionalisation triggers metal complex binding journal January 2008
Post-Synthetic Modification of Tagged Metal-Organic Frameworks journal October 2008
Covalent modification of a metal–organic framework with isocyanates: probing substrate scope and reactivity journal January 2008
Salen-Co(II) complex incorporated into amino-functionalized MIL-101(Cr) through postsynthetic modification as a cooperative catalyst for cyclohexane selective oxidation journal September 2013
“Clickable” Metal−Organic Framework journal November 2008
Covalent surface modification of a metal–organic framework: selective surface engineering via CuI-catalyzed Huisgen cycloaddition journal January 2008
Nucleic Acid–Metal Organic Framework (MOF) Nanoparticle Conjugates journal May 2014
Synthesis and click modification of an azido-functionalized Zr( iv ) metal–organic framework and a catalytic study journal January 2015
A Mesoporous Metal−Organic Framework with Permanent Porosity journal December 2006
Generation of a solid Brønsted acid site in a chiral framework journal January 2008
Metal–organic framework tethering PNIPAM for ON–OFF controlled release in solution journal January 2015
Metal–Organic Framework Based upon the Synergy of a Brønsted Acid Framework and Lewis Acid Centers as a Highly Efficient Heterogeneous Catalyst for Fixed-Bed Reactions journal March 2015
Stepwise Synthesis of Robust Metal–Organic Frameworks via Postsynthetic Metathesis and Oxidation of Metal Nodes in a Single-Crystal to Single-Crystal Transformation journal May 2014
Enhancing CO 2 Separation Ability of a Metal-Organic Framework by Post-Synthetic Ligand Exchange with Flexible Aliphatic Carboxylates journal December 2013
Metalation of a Thiocatechol-Functionalized Zr(IV)-Based Metal–Organic Framework for Selective C–H Functionalization journal February 2015
Tetrazine functionalized zirconium MOF as an optical sensor for oxidizing gases journal January 2015
Postsynthetic Ligand and Cation Exchange in Robust Metal–Organic Frameworks journal October 2012
A route to drastic increase of CO2 uptake in Zr metal organic framework UiO-66 journal January 2013
Photocatalytic CO 2 reduction by a mixed metal (Zr/Ti), mixed ligand metal–organic framework under visible light irradiation journal January 2015
Unusual and Highly Tunable Missing-Linker Defects in Zirconium Metal–Organic Framework UiO-66 and Their Important Effects on Gas Adsorption journal May 2013
A facile synthesis of UiO-66, UiO-67 and their derivatives journal January 2013
A UiO-66 analogue with uncoordinated carboxylic acids for the broad-spectrum removal of toxic chemicals journal January 2015
Tandem Modification of Metal–Organic Frameworks by a Postsynthetic Approach journal June 2008
A Route to the Synthesis of Trivalent Transition-Metal Porous Carboxylates with Trimeric Secondary Building Units journal September 2004
Single-Crystalline Molecular Flasks: Chemical Transformation with Bulky Reagents in the Pores of Porous Coordination Networks journal October 2008
A Highly Stable Zeotype Mesoporous Zirconium Metal-Organic Framework with Ultralarge Pores journal November 2014
Hydrogen Storage in the Giant-Pore Metal–Organic Frameworks MIL-100 and MIL-101 journal December 2006
How Hydration Drastically Improves Adsorption Selectivity for CO2 over CH4 in the Flexible Chromium Terephthalate MIL-53 journal November 2006
Giant Pores in a Chromium 2,6-Naphthalenedicarboxylate Open-Framework Structure with MIL-101 Topology journal May 2009
Metal–Organic Frameworks as Efficient Materials for Drug Delivery journal September 2006
Postsynthetic Modifications of Iron-Carboxylate Nanoscale Metal−Organic Frameworks for Imaging and Drug Delivery text January 2009
Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts journal August 2012
Tuning the structure and function of metal–organic frameworks via linker design journal January 2014
Metal–organic frameworks for artificial photosynthesis and photocatalysis journal January 2014

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Metal-Organic Framework (MOF)-Based Drug/Cargo Delivery and Cancer Therapy journal March 2017
Hierarchical Nanostructures: Design for Sustainable Water Splitting journal July 2017
Schalten in Metall‐organischen Gerüsten journal December 2019
Multivariate Modulation of the Zr MOF UiO‐66 for Defect‐Controlled Combination Anticancer Drug Delivery journal February 2020
Multivariate Modulation of the Zr MOF UiO‐66 for Defect‐Controlled Combination Anticancer Drug Delivery journal March 2020
Aerobic Homocoupling of Arylboronic Acids Catalyzed by Regenerable Pd(II)@MIL‐88B‐NH 2 (Cr) journal May 2019
Coordination Polymers and Clusters Based on the Versatile Mercaptonicotinate Ligands: Coordination Polymers and Clusters Based on the Versatile Mercaptonicotinate Ligands journal October 2019
Sulfonic Acid Functionalized MIL‐101(Cr) Metal‐Organic Framework for Catalytic Production of Acetals journal July 2019
Synthesis and Characterization of New Organometallic Hybrid Material LCP-1 Based on MOF (Metal–Organic Framework) and Maghnite-H+, a Protons Exchanged Montmorillonite Clay, as Catalytic Support journal August 2017
Fe(III) porphyrin metal–organic framework as an artificial enzyme mimics and its application in biosensing of glucose and H2O2 journal March 2019
Introducing 2-(2-carboxyphenoxy)terephthalic acid as a new versatile building block for design of diverse coordination polymers: synthesis, structural features, luminescence sensing, and magnetism journal January 2017
Investigating the crystal engineering of the pillared paddlewheel metal–organic framework Zn 2 (NH 2 BDC) 2 DABCO journal January 2018
Deformation behavior of an amorphous zeolitic imidazolate framework – from a supersoft material to a complex organometallic alloy journal January 2018
Hydrothermal generation, structural versatility and properties of metal( ii )-organic architectures driven by a pyridine-tricarboxylic acid journal January 2019
Post-synthetic modification of a Tb-based metal–organic framework for highly selective and sensitive detection of metal ions in aqueous solution journal January 2019
Two mixed-ligand Cd( ii )–organic frameworks with unique topologies: selective luminescence sensing of TNP and Cu 2+ ions with recyclable performances journal January 2019
Mechanosynthesis of coordination polymers based on dithiophosphato and dithiophosphonato Ni II complexes and 1,4-di(3-pyridinyl)buta-1,3-diyne ligand journal October 2017
New Microbe Killers: Self-Assembled Silver(I) Coordination Polymers Driven by a Cagelike Aminophosphine journal October 2019
Switching in Metal–Organic Frameworks journal December 2019
A novel microwave assisted reverse micelle fabrication route for Th (IV)-MOFs as highly efficient adsorbent nanostructures with controllable structural properties to CO and CH 4 adsorption: Design, and a systematic study: novel Th (IV)-MOF as highly efficient CO and CH4 adsorbent journal February 2019
Carboxylate-Hydrazone Mixed-Linker Metal-Organic Frameworks: Synthesis, Structure, and Selective Gas Adsorption: Carboxylate-Hydrazone Mixed-Linker Metal-Organic Frameworks: Synthesis, Structure, and Selective Gas Adsorption journal April 2016
10000-Fold Enhancement in Proton Conduction by Doping of Cesium Ions in a Proton-Conducting Zwitterionic Metal-Organic Framework: 10000-Fold Enhancement in Proton Conduction by Doping of Cesium Ions in a Proton-Conducting Zwitterionic Metal-Organic Framework journal June 2016
Variation of Desolvation Behavior in Two Isostructural Metal-Organic Frameworks Based on a Flexible, Racemic Bifunctional Organic Linker: Variation of Desolvation Behavior in Two Isostructural Metal-Organic Frameworks Based on a Flexible, Racemic Bifunctional Organic Linker journal August 2016
Field-Dependent Magnetic Behaviour in Mn II (dicarboxylate)-(bipyridyl)-type 3D Metal-Organic Frameworks with Interpenetrated Structures journal March 2017
Size and surface controllable metal–organic frameworks (MOFs) for fluorescence imaging and cancer therapy journal January 2018
Transmission electron microscopy on metal–organic frameworks – a review journal January 2017
Plasma-catalysed reaction M n+ + L–H → MOFs: facile and tunable construction of metal–organic frameworks in dielectric barrier discharge journal January 2019
Hollow structural metal–organic frameworks exhibit high drug loading capacity, targeted delivery and magnetic resonance/optical multimodal imaging journal January 2019
Ambient synthesis of nanomaterials by in situ heterogeneous metal/ligand reactions journal January 2019
Selective decontamination of the reactive air pollutant nitrous acid via node-linker cooperativity in a metal–organic framework journal January 2019
Polymer/Metal Organic Framework (MOF) Nanocomposites for Biomedical Applications journal January 2020
Fe(III) porphyrin metal–organic framework as an artificial enzyme mimics and its application in biosensing of glucose and H2O2 text January 2021
Novel hybrid transition metal complexes of diaquabis(acetylacetonato-κ 2 o,o′)[nickel(II)/zinc (II)] as solid metal-organic precursors: Synthesis, properties and magnetic response journal March 2017
New synthetic routes towards MOF production at scale journal January 2017
Construction of noninterpenetrating and interpenetrating Co( ii ) networks with halogenated carboxylate modulated by auxiliary N-donor co-ligands: structural diversity, electrochemical and photocatalytic properties journal January 2017
An ambient-temperature aqueous synthesis of zirconium-based metal–organic frameworks journal January 2018
Mixed-Matrix Membranes Formed from Imide-Functionalized UiO-66-NH 2 for Improved Interfacial Compatibility journal July 2019