Magnetic Ordering in Sr3YCo4O10+x

Kishida, Takayoshi; Kapetanakis, Myron D.; Yan, Jiaqiang; Sales, Brian C.; Pantelides, Sokrates T.; Pennycook, Stephen J.; Chisholm, Matthew F.

doi:10.1038/srep19762

Title: Magnetic Ordering in Sr₃YCo₄O_10+x

Journal Article · Thu Jan 28 00:00:00 EST 2016 · Scientific Reports

DOI:https://doi.org/10.1038/srep19762· OSTI ID:1239752

Kishida, Takayoshi ^[1]; Kapetanakis, Myron D. ^[2]; Yan, Jiaqiang ^[3]; Sales, Brian C. ^[3]; Pantelides, Sokrates T. ^[2]; Pennycook, Stephen J. ^[4]; Chisholm, Matthew F. ^[3]

Asahi Kasei Corporation, Fuji, Shizuoka (Japan). Department of Technology Group, Analysis & Simulation Center
Vanderbilt Univ., Nashville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
National University of Singapore, (Singapore). Department of Materials Science and Engineering

Transition-metal oxides often exhibit complex magnetic behavior due to the strong interplay between atomic-structure, electronic and magnetic degrees of freedom. Cobaltates, especially, exhibit complex behavior because of cobalt's ability to adopt various valence and spin state configurations. The case of the oxygen-deficient perovskite Sr3YCo4O10+x (SYCO) has attracted considerable attention because of persisting uncertainties about its structure and the origin of the observed room temperature ferromagnetism. Here we report a combined investigation of SYCO using aberration-corrected scanning transmission electron microscopy and density functional theory calculations. Guided by theoretical results on Co-O distances projected on different planes, the atomic-scale images of several different orientations, especially of the fully oxygenated planes, allow the unambiguous extraction of the underlying structure. The calculated magnetic properties of the new structure are in excellent agreement with the experimental data.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Vanderbilt Univ., Nashville, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725; FG02- 09ER46554; AC02-05CH11231; FG02-09ER46554

OSTI ID:: 1239752

Alternate ID(s):: OSTI ID: 1597737

Journal Information:: Scientific Reports, Vol. 6; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 8 works

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Cited By (3)

Spin states of Co ³⁺ ions in Sr _0.75 Y _0.25 CoO _2.625 system induced by Jahn-Teller distortion: a density-functional study Muhammady, Shibghatullah; Sutjahja, Inge Magdalena Materials Research Express, Vol. 5, Issue 9 https://doi.org/10.1088/2053-1591/aad4e0	journal	August 2018
Ferromagnet-antiferromagnet transition in layered perovskites of Sr ₃ YCo ₄ O _10.5 type Troyanchuk, I. O.; Bushinsky, M. V.; Tereshko, N. V. Materials Research Express, Vol. 6, Issue 2 https://doi.org/10.1088/2053-1591/aaef21	journal	November 2018
Room-Temperature Ferromagnetic Sr₃YCo₄O_10+δ and Carbon Black-Reinforced Polyvinylidenefluoride Composites toward High-Performance Electromagnetic Interference Shielding Lalan, Vidhya; Puthiyedath Narayanan, Aparna; Surendran, Kuzhichalil Peethambharan ACS Omega, Vol. 4, Issue 5 https://doi.org/10.1021/acsomega.9b00454	journal	May 2019

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