Phase diagram and transformations of iron pentacarbonyl to nm layered hematite and carbon-oxygen polymer under pressure

Ryu, Young Jay; Kim, Minseob; Yoo, Choong -Shik

doi:10.1038/srep15139

Title: Phase diagram and transformations of iron pentacarbonyl to nm layered hematite and carbon-oxygen polymer under pressure

Journal Article · Mon Oct 12 00:00:00 EDT 2015 · Scientific Reports

DOI:https://doi.org/10.1038/srep15139· OSTI ID:1239295

Ryu, Young Jay ^[1]; Kim, Minseob ^[1]; Yoo, Choong -Shik ^[1]

Washington State Univ., Pullman, WA (United States)

We present the phase diagram of Fe(CO)₅, consisting of three molecular polymorphs (phase I, II and III) and an extended polymeric phase that can be recovered at ambient condition. The phase diagram indicates a limited stability of Fe(CO)₅ within a pressure-temperature dome formed below the liquid- phase II polymer triple point at 4.2 GPa and 580 K. The limited stability, in turn, signifies the temperature-induced weakening of Fe-CO back bonds, which eventually leads to the dissociation of Fe-CO at the onset of the polymerization of CO. The recovered polymer is a composite of novel nm-lamellar layers of crystalline hematite Fe₂O₃ and amorphous carbon-oxygen polymers. Lastly, these results, therefore, demonstrate the synthesis of carbon-oxygen polymer by compressing Fe(CO)₅, which advocates a novel synthetic route to develop atomistic composite materials by compressing organometallic compounds.

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Research Organization:: Washington State Univ., Pullman, WA (United States); Carnegie Inst. of Science, Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0001974; FG02-99ER45775; NA0002006

OSTI ID:: 1239295

Alternate ID(s):: OSTI ID: 1335642

Journal Information:: Scientific Reports, Vol. 5; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 9 works

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