Scalable fabrication of efficient organolead trihalide perovskite solar cells with doctor-bladed active layers

Deng, Yehao; Peng, Edwin; Shao, Yuchuan; Xiao, Zhengguo; Dong, Qingfeng; Huang, Jinsong

doi:10.1039/C4EE03907F

Title: Scalable fabrication of efficient organolead trihalide perovskite solar cells with doctor-bladed active layers

Journal Article · Wed Mar 25 00:00:00 EDT 2015 · Energy & Environmental Science

DOI:https://doi.org/10.1039/C4EE03907F· OSTI ID:1237999

Deng, Yehao ^[1]; Peng, Edwin ^[1]; Shao, Yuchuan ^[1]; Xiao, Zhengguo ^[1]; Dong, Qingfeng ^[1]; Huang, Jinsong ^[1]

Univ. of Nebraska, Lincoln, NE (United States)

Organolead trihalide perovskites (OTPs) are nature abundant materials with prospects as future low-cost renewable energy sources boosted by the solution process capability of these materials. Here we report the fabrication of efficient OTP devices by a simple, high throughput and low-cost doctor-blade coating process which can be compatible with the roll-to-roll fabrication process for the large scale production of perovskite solar cell panels. The formulation of appropriate precursor inks by removing impurities is shown to be critical in the formation of continuous, pin-hole free and phase-pure perovskite films on large area substrates, which is assisted by a high deposition temperature to guide the nucleation and grain growth process. The domain size reached 80–250 μm in 1.5–2 μm thick bladed films. By controlling the stoichiometry and thickness of the OTP films, highest device efficiencies of 12.8% and 15.1% are achieved in the devices fabricated on poly(3,4-ethylenedioxythiophene) polystyrene sulfonate and cross-linked N4,N4'-bis(4-(6-((3-ethyloxetan-3-yl)methoxy)hexyl)phenyl)–N4,N4'-diphenylbiphenyl-4,4'-diamine covered ITO substrates. Furthermore, the carrier diffusion length in doctor-bladed OTP films is beyond 3.5 μm which is significantly larger than in the spin-coated films, due to the formation of crystalline grains with a very large size by the doctor-blade coating method.

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Research Organization:: Univ. of Nebraska, Lincoln, NE (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: EE0006709

OSTI ID:: 1237999

Journal Information:: Energy & Environmental Science, Vol. 8, Issue 5; ISSN 1754-5692

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 533 works

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Gravure‐Printed Flexible Perovskite Solar Cells: Toward Roll‐to‐Roll Manufacturing Kim, Young Yun; Yang, Tae‐Youl; Suhonen, Riikka Advanced Science, Vol. 6, Issue 7 https://doi.org/10.1002/advs.201802094	journal	January 2019
Amino-Functionalized Conjugated Polymer as an Efficient Electron Transport Layer for High-Performance Planar-Heterojunction Perovskite Solar Cells Sun, Chen; Wu, Zhihong; Yip, Hin-Lap Advanced Energy Materials, Vol. 6, Issue 5 https://doi.org/10.1002/aenm.201501534	journal	December 2015
Inverted Perovskite Solar Cells: Progresses and Perspectives Liu, Tanghao; Chen, Ke; Hu, Qin Advanced Energy Materials, Vol. 6, Issue 17 https://doi.org/10.1002/aenm.201600457	journal	May 2016
Alternative Perovskites for Photovoltaics Jodlowski, AlexanderD.; Rodríguez-Padrón, Daily; Luque, Rafael Advanced Energy Materials, Vol. 8, Issue 21 https://doi.org/10.1002/aenm.201703120	journal	April 2018
High-Performance Thickness Insensitive Perovskite Solar Cells with Enhanced Moisture Stability Chen, Jiehuan; Zuo, Lijian; Zhang, Yingzhu Advanced Energy Materials, Vol. 8, Issue 23 https://doi.org/10.1002/aenm.201800438	journal	June 2018
Drying Dynamics of Solution‐Processed Perovskite Thin‐Film Photovoltaics: In Situ Characterization, Modeling, and Process Control Ternes, Simon; Börnhorst, Tobias; Schwenzer, Jonas A. Advanced Energy Materials, Vol. 9, Issue 39 https://doi.org/10.1002/aenm.201901581	journal	August 2019
Scalable Deposition Methods for Large‐area Production of Perovskite Thin Films Swartwout, Richard; Hoerantner, Maximilian T.; Bulović, V. ENERGY & ENVIRONMENTAL MATERIALS, Vol. 2, Issue 2 https://doi.org/10.1002/eem2.12043	journal	June 2019
Controlling Apparent Coordinated Solvent Number in the Perovskite Intermediate Phase Film for Developing Large‐Area Perovskite Solar Modules Lou, Lingyun; Liu, Tongfa; Xiao, Junyan Energy Technology, Vol. 8, Issue 4 https://doi.org/10.1002/ente.201900972	journal	April 2020
Solvent and Spinning Speed Effects on CH ₃ NH ₃ PbI ₃ Films Deposited by Spin Coating Belaidi, Itidal; Khelfaoui, Fatima; Attaf, Nadhir physica status solidi (a), Vol. 216, Issue 22 https://doi.org/10.1002/pssa.201900340	journal	September 2019
Metal Halide Perovskites: From Crystal Formations to Light-Emitting-Diode Applications Kim, Young-Hoon; Kim, Sungjin; Jo, Seung Hyeon Small Methods, Vol. 2, Issue 11 https://doi.org/10.1002/smtd.201800093	journal	July 2018
Spray-cast multilayer perovskite solar cells with an active-area of 1.5 cm2 Bishop, James E.; Mohamad, David K.; Wong-Stringer, Michael Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-08642-2	journal	August 2017
Perovskite Thin Film Synthesised from Sputtered Lead Sulphide Silva Filho, José Maria Clemente da; Ermakov, Viktor A.; Marques, Francisco Chagas Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-018-19746-8	journal	January 2018
UV Degradation and Recovery of Perovskite Solar Cells Lee, Sang-Won; Kim, Seongtak; Bae, Soohyun Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep38150	journal	December 2016
Manipulation of the crystallization of perovskite films induced by a rotating magnetic field during blade coating in air Lin, Yichuan; Ye, Xiaoqin; Wu, Zhiming Journal of Materials Chemistry A, Vol. 6, Issue 9 https://doi.org/10.1039/c7ta09721b	journal	January 2018
Low-dimensional halide perovskites: review and issues Hong, Kootak; Le, Quyet Van; Kim, Soo Young Journal of Materials Chemistry C, Vol. 6, Issue 9 https://doi.org/10.1039/c7tc05658c	journal	January 2018
Solution-processed resistive switching memory devices based on hybrid organic–inorganic materials and composites Shan, Yingying; Lyu, Zhensheng; Guan, Xinwei Physical Chemistry Chemical Physics, Vol. 20, Issue 37 https://doi.org/10.1039/c8cp03945c	journal	January 2018
Control of aggregation and dissolution of small molecule hole transport layers via a doping strategy for highly efficient perovskite solar cells Ali, Jazib; Song, Jingnan; Li, Yu Journal of Materials Chemistry C, Vol. 7, Issue 38 https://doi.org/10.1039/c9tc03120k	journal	January 2019
Recent advances in interfacial engineering of perovskite solar cells Ye, Meidan; He, Chunfeng; Iocozzia, James Journal of Physics D: Applied Physics, Vol. 50, Issue 37 https://doi.org/10.1088/1361-6463/aa7cb0	journal	August 2017
A general printing approach for scalable growth of perovskite single-crystal films Gu, Zhenkun; Huang, Zhandong; Li, Chang Science Advances, Vol. 4, Issue 6 https://doi.org/10.1126/sciadv.aat2390	journal	June 2018
Editors' Choice—Stability of Unstable Perovskites: Recent Strategies for Making Stable Perovskite Solar Cells Mali, Sawanta S.; Patil, Jyoti V.; Arandiyan, Hamidreza ECS Journal of Solid State Science and Technology, Vol. 8, Issue 6 https://doi.org/10.1149/2.0201906jss	journal	January 2019
Surfactant-controlled ink drying enables high-speed deposition of perovskite films for efficient photovoltaic modules X., Zheng,; Q., Wang,; Y., Bai, The University of North Carolina at Chapel Hill University Libraries https://doi.org/10.17615/06w1-cw07	text	January 2018
Molecular doping enabled scalable blading of efficient hole-transport-layer-free perovskite solar cells A., Gruverman,; Y., Shao,; Y., Liu, The University of North Carolina at Chapel Hill University Libraries https://doi.org/10.17615/236r-qz11	text	January 2018
Bilateral alkylamine for suppressing charge recombination and improving stability in blade-coated perovskite solar cells J., Huang,; X., Xiao,; J., Zhao, The University of North Carolina at Chapel Hill University Libraries https://doi.org/10.17615/r232-5f04	text	January 2019
Meniscus-assisted solution printing of large-grained perovskite films for high-efficiency solar cells P., Szymanski,; Y., He,; M. A., Ei-Sayed, The University of North Carolina at Chapel Hill University Libraries https://doi.org/10.17615/y8f3-3655	text	January 2017
Perovskite Solar Cells: Progress and Advancements Elumalai, Naveen; Mahmud, Md; Wang, Dian Energies, Vol. 9, Issue 11 https://doi.org/10.3390/en9110861	journal	October 2016
A Review of Perovskite Photovoltaic Materials’ Synthesis and Applications via Chemical Vapor Deposition Method Liu, Xia; Cao, Lianzhen; Guo, Zhen Materials, Vol. 12, Issue 20 https://doi.org/10.3390/ma12203304	journal	October 2019
Micrometric Wrinkled Patterns Spontaneously Formed on Hydrogel Thin Films via Argon Plasma Exposure González-Henríquez, Carmen M.; Veliz-Silva, Diego F.; Sarabia-Vallejos, Mauricio A. Molecules, Vol. 24, Issue 4 https://doi.org/10.3390/molecules24040751	journal	February 2019
High-Performance Perovskite Solar Cells with Enhanced Environmental Stability Based on Amphiphile-Modified CH ₃ NH ₃ PbI ₃ Bi, Dongqin; Gao, Peng; Scopelliti, Rosario Advanced Materials, Vol. 28, Issue 15 https://doi.org/10.1002/adma.201505255	journal	February 2016
Spray-Cast Multilayer Organometal Perovskite Solar Cells Fabricated in Air Mohamad, David K.; Griffin, Jonathon; Bracher, Christopher Advanced Energy Materials, Vol. 6, Issue 22 https://doi.org/10.1002/aenm.201600994	journal	August 2016
General Nondestructive Passivation by 4‐Fluoroaniline for Perovskite Solar Cells with Improved Performance and Stability Zhao, Shenghe; Xie, Jiangsheng; Cheng, Guanghui Small, Vol. 14, Issue 50 https://doi.org/10.1002/smll.201803350	journal	October 2018
Lead Iodide and Perovskite Films Obtained by Iodination of PbS Thin Films da Silva Filho, José Maria Clemente; Landers, Richard; Marques, Francisco Chagas Journal of Inorganic and Organometallic Polymers and Materials, Vol. 29, Issue 6 https://doi.org/10.1007/s10904-019-01175-3	journal	May 2019
Gas-solid reaction based over one-micrometer thick stable perovskite films for efficient solar cells and modules Liu, Zonghao; Qiu, Longbin; Juarez-Perez, Emilio J. Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06317-8	journal	September 2018
Recent progressive efforts in perovskite solar cells toward commercialization Kim, Byeong Jo; Lee, Sangwook; Jung, Hyun Suk Journal of Materials Chemistry A, Vol. 6, Issue 26 https://doi.org/10.1039/c8ta02159g	journal	January 2018
Coated and Printed Perovskites for Photovoltaic Applications Howard, Ian A.; Abzieher, Tobias; Hossain, Ihteaz M. Wiley https://doi.org/10.5445/ir/1000093372	text	January 2019
Flexible Wire-Shaped Perovskite Photodetector via Joule Heating for Improved Crystallization and Performance Adams, Geoffrey Ryan; Adhikari, Nirmal; Parker, Helen Advanced Materials Interfaces, Vol. 5, Issue 15 https://doi.org/10.1002/admi.201800082	journal	May 2018
Solution-processed bathocuproine cathode buffer layer towards efficient planar heterojunction perovskite solar cells Wang, Yunxiang; Zhang, Jihua; Wu, Yanhua Semiconductor Science and Technology, Vol. 34, Issue 7 https://doi.org/10.1088/1361-6641/ab2309	journal	June 2019
Back-Contact Perovskite Solar Cells Friend, Richard; Deschler, Felix; Pazos-Outón, Luis M. Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.37328	text	January 2019
Composition Engineering in Doctor-Blading of Perovskite Solar Cells Y., Fang,; Q., Dong,; J., Huang, The University of North Carolina at Chapel Hill University Libraries https://doi.org/10.17615/f38k-7987	text	January 2017
Drying Dynamics of Solution‐Processed Perovskite Thin‐Film Photovoltaics: In Situ Characterization, Modeling, and Process Control Ternes, Simon; Börnhorst, Tobias; Schwenzer, Jonas A. Wiley-VCH Verlag https://doi.org/10.5445/ir/1000097909	text	January 2019
Roll-to-Roll Fabrication of Solution Processed Electronics Abbel, Robert; Galagan, Yulia; Groen, Pim Advanced Engineering Materials, Vol. 20, Issue 8 https://doi.org/10.1002/adem.201701190	journal	April 2018
Air-Stable, Efficient Mixed-Cation Perovskite Solar Cells with Cu Electrode by Scalable Fabrication of Active Layer Deng, Yehao; Dong, Qingfeng; Bi, Cheng Advanced Energy Materials, Vol. 6, Issue 11 https://doi.org/10.1002/aenm.201600372	journal	April 2016
Processing‐Performance Evolution of Perovskite Solar Cells: From Large Grain Polycrystalline Films to Single Crystals Haque, Md Azimul; Troughton, Joel; Baran, Derya Advanced Energy Materials, Vol. 10, Issue 13 https://doi.org/10.1002/aenm.201902762	journal	April 2020
Amino-Acid-Induced Preferential Orientation of Perovskite Crystals for Enhancing Interfacial Charge Transfer and Photovoltaic Performance Shih, Yen-Chen; Lan, Yu-Bing; Li, Chia-Shuo Small, Vol. 13, Issue 22 https://doi.org/10.1002/smll.201604305	journal	April 2017
Enhancing the Performance of Perovskite Solar Cells by Hybridizing SnS Quantum Dots with CH ₃ NH ₃ PbI ₃ Han, Jianhua; Yin, Xuewen; Nan, Hui Small, Vol. 15, Issue 27 https://doi.org/10.1002/smll.201902152	journal	April 2019
One‐Step Inkjet Printed Perovskite in Air for Efficient Light Harvesting Liang, Chao; Li, Pengwei; Gu, Hao Solar RRL, Vol. 2, Issue 2 https://doi.org/10.1002/solr.201700217	journal	January 2018
Cations Functionalized Carbon Nano‐Dots Enabling Interfacial Passivation and Crystallization Control for Inverted Perovskite Solar Cells Li, Zhiqi; Liu, Chunyu; Ren, Guanha Solar RRL, Vol. 4, Issue 1 https://doi.org/10.1002/solr.201900369	journal	October 2019
Three in situ -synthesized novel inorganic–organic hybrid materials based on metal (M = Bi, Pb) iodide and organoamine using one-pot reactions: structures, band gaps and optoelectronic properties Yan, Zhi Shuo; Long, Ji Ying; Gong, Yun New Journal of Chemistry, Vol. 42, Issue 1 https://doi.org/10.1039/c7nj02815f	journal	January 2018
Multifunctional asymmetrical molecules for high-performance perovskite and organic solar cells Gao, Wei; Wu, Fei; Liu, Tao Journal of Materials Chemistry A, Vol. 7, Issue 5 https://doi.org/10.1039/c8ta10975c	journal	January 2019
Flexible and Transparent Substrates Based on Gold Nanoparticles and TiO2 for in Situ Bioanalysis by Surface-Enhanced Raman Spectroscopy Mandrile, Luisa; Giovannozzi, Andrea; Sacco, Alessio Biosensors, Vol. 9, Issue 4 https://doi.org/10.3390/bios9040145	journal	December 2019
Carrier Diffusion in Thin-Film CH3NH3PbI3 Perovskite Measured using Four-Wave Mixing Webber, D.; Clegg, C.; Mason, A. W. arXiv https://doi.org/10.48550/arxiv.1706.04154	text	January 2017

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