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Title: A high performance hybrid battery based on aluminum anode and LiFePO4 cathode

Abstract

A unique battery hybrid utilizes an aluminum anode, a LiFePO4 cathode and an acidic ionic liquid electrolyte based on 1-ethyl-3-methylimidazolium chloride (EMImCl) and aluminum trichloride (AlCl 3) (EMImCl-AlCl 3, 1-1.1 in molar ratio) with or without LiAlCl4 is proposed. This hybrid ion battery delivers an initial high capacity of 160 mAh g-1 at a current rate of C/5. It also shows good rate capability and cycling performance.

Authors:
 [1];  [1];  [1];  [1];  [1];  [2];  [1]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1237159
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 52; Journal Issue: 8; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Sun, Xiao-Guang, Bi, Zhonghe, Liu, Hansan, Bridges, Craig A., Paranthaman, Mariappan Parans, Dai, Sheng, and Brown, Gilbert M. A high performance hybrid battery based on aluminum anode and LiFePO4 cathode. United States: N. p., 2015. Web. doi:10.1039/C5CC09019A.
Sun, Xiao-Guang, Bi, Zhonghe, Liu, Hansan, Bridges, Craig A., Paranthaman, Mariappan Parans, Dai, Sheng, & Brown, Gilbert M. A high performance hybrid battery based on aluminum anode and LiFePO4 cathode. United States. https://doi.org/10.1039/C5CC09019A
Sun, Xiao-Guang, Bi, Zhonghe, Liu, Hansan, Bridges, Craig A., Paranthaman, Mariappan Parans, Dai, Sheng, and Brown, Gilbert M. 2015. "A high performance hybrid battery based on aluminum anode and LiFePO4 cathode". United States. https://doi.org/10.1039/C5CC09019A. https://www.osti.gov/servlets/purl/1237159.
@article{osti_1237159,
title = {A high performance hybrid battery based on aluminum anode and LiFePO4 cathode},
author = {Sun, Xiao-Guang and Bi, Zhonghe and Liu, Hansan and Bridges, Craig A. and Paranthaman, Mariappan Parans and Dai, Sheng and Brown, Gilbert M.},
abstractNote = {A unique battery hybrid utilizes an aluminum anode, a LiFePO4 cathode and an acidic ionic liquid electrolyte based on 1-ethyl-3-methylimidazolium chloride (EMImCl) and aluminum trichloride (AlCl 3) (EMImCl-AlCl 3, 1-1.1 in molar ratio) with or without LiAlCl4 is proposed. This hybrid ion battery delivers an initial high capacity of 160 mAh g-1 at a current rate of C/5. It also shows good rate capability and cycling performance.},
doi = {10.1039/C5CC09019A},
url = {https://www.osti.gov/biblio/1237159}, journal = {ChemComm},
issn = {1359-7345},
number = 8,
volume = 52,
place = {United States},
year = {Mon Dec 07 00:00:00 EST 2015},
month = {Mon Dec 07 00:00:00 EST 2015}
}

Journal Article:
Free Publicly Available Full Text
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Citation Metrics:
Cited by: 45 works
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Works referencing / citing this record:

Emerging Nonaqueous Aluminum-Ion Batteries: Challenges, Status, and Perspectives
journal, June 2018


Paving the Path toward Reliable Cathode Materials for Aluminum-Ion Batteries
journal, February 2019


Trends in Aluminium-Based Intercalation Batteries
journal, March 2017


Die wiederaufladbare Aluminiumbatterie: Möglichkeiten und Herausforderungen
journal, June 2019


The Rechargeable Aluminum Battery: Opportunities and Challenges
journal, August 2019


Stable Performance of Aluminum-Metal Battery by Incorporating Lithium-Ion Chemistry
journal, May 2017


Synthesis and Characterization of Bromoaluminate Ionic Liquids
journal, June 2017


Critical Role of pH Evolution of Electrolyte in the Reaction Mechanism for Rechargeable Zinc Batteries
journal, September 2016


Ion Dynamics in Ionic-Liquid-Based Li-Ion Electrolytes Investigated by Neutron Scattering and Dielectric Spectroscopy
journal, September 2018


Design and modification of cathode materials for high energy density aluminum-ion batteries: a review
journal, June 2018