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Title: Nitrogen Atom Transfer From High Valent Iron Nitrides

Technical Report ·
DOI:https://doi.org/10.2172/1236964· OSTI ID:1236964
 [1];  [2]
  1. New Mexico State Univ., Las Cruces, NM (United States)
  2. Indiana Univ., Bloomington, IN (United States)

This report describes the synthesis and reactions of high valent iron nitrides. Organonitrogen compounds such as aziridines are useful species for organic synthesis, but there are few efficient methods for their synthesis. Using iron nitrides to catalytically access these species may allow for their synthesis in an energy-and atom-efficient manner. We have developed a new ligand framework to achieve these goals as well as providing a method for inducing previously unknown reactivity.

Research Organization:
New Mexico State Univ., Las Cruces, NM (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG02-08ER15996
OSTI ID:
1236964
Report Number(s):
DOE-NMSU-15996
Country of Publication:
United States
Language:
English