Understanding the structure and structural degradation mechanisms in high-voltage lithium-ion battery cathode oxides. A review of materials diagnostics

Mohanty, Debasish; Li, Jianlin; Nagpure, Shrikant C; Wood, III, David L; Daniel, Claus

doi:10.1557/mre.2015.16

Title: Understanding the structure and structural degradation mechanisms in high-voltage lithium-ion battery cathode oxides. A review of materials diagnostics

Journal Article · Mon Dec 21 00:00:00 EST 2015 · MRS Energy & Sustainability

DOI:https://doi.org/10.1557/mre.2015.16· OSTI ID:1236575

Mohanty, Debasish ^[1]; Li, Jianlin ^[1]; Nagpure, Shrikant C ^[1]; Wood, III, David L ^[1]; Daniel, Claus ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Materials diagnostic techniques are the principal tools used in the development of low-cost, high-performance electrodes for next-generation lithium-based energy storage technologies. Also, this review highlights the importance of materials diagnostic techniques in unraveling the structure and the structural degradation mechanisms in high-voltage, high-capacity oxides that have the potential to be implemented in high-energy-density lithium-ion batteries for transportation that can use renewable energy and is less-polluting than today. The rise in CO₂ concentration in the earth’s atmosphere due to the use of petroleum products in vehicles and the dramatic increase in the cost of gasoline demand the replacement of current internal combustion engines in our vehicles with environmentally friendly, carbon free systems. Therefore, vehicles powered fully/partially by electricity are being introduced into today’s transportation fleet. As power requirements in all-electric vehicles become more demanding, lithium-ion battery (LiB) technology is now the potential candidate to provide higher energy density. Moreover, discovery of layered high-voltage lithium-manganese–rich (HV-LMR) oxides has provided a new direction toward developing high-energy-density LiBs because of their ability to deliver high capacity (~250 mA h/g) and to be operated at high operating voltage (~4.7 V). Unfortunately, practical use of HV-LMR electrodes is not viable because of structural changes in the host oxide during operation that can lead to fundamental and practical issues. This article provides the current understanding on the structure and structural degradation pathways in HV-LMR oxides, and manifests the importance of different materials diagnostic tools to unraveling the key mechanism(s). Furthermore, the fundamental insights reported, might become the tools to manipulate the chemical and/or structural aspects of HV-LMR oxides for low cost, high-energy-density LiB applications.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1236575

Journal Information:: MRS Energy & Sustainability, Vol. 2; ISSN 2329-2237

Publisher:: Materials Research SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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High-Performance Li-Rich Layered Transition Metal Oxide Cathode Materials for Li-Ion Batteries Redel, Katarzyna; Kulka, Andrzej; Plewa, Anna Journal of The Electrochemical Society, Vol. 166, Issue 3 https://doi.org/10.1149/2.0511903jes	journal	January 2019
Editors' Choice—State of Charge Dependent Resistance Build-Up in Li- and Mn-Rich Layered Oxides during Lithium Extraction and Insertion Teufl, Tobias; Pritzl, Daniel; Solchenbach, Sophie Journal of The Electrochemical Society, Vol. 166, Issue 6 https://doi.org/10.1149/2.1131906jes	journal	January 2019
Oxygen Release and Surface Degradation of Li- and Mn-Rich Layered Oxides in Variation of the Li ₂ MnO ₃ Content Teufl, Tobias; Strehle, Benjamin; Müller, Philipp Journal of The Electrochemical Society, Vol. 165, Issue 11 https://doi.org/10.1149/2.0691811jes	journal	January 2018
Modification of Ni-Rich FCG NMC and NCA Cathodes by Atomic Layer Deposition: Preventing Surface Phase Transitions for High-Voltage Lithium-Ion Batteries Mohanty, Debasish; Dahlberg, Kevin; King, David M. Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep26532	journal	May 2016
Energy storage through intercalation reactions: electrodes for rechargeable batteries Massé, Robert C.; Liu, Chaofeng; Li, Yanwei National Science Review, Vol. 4, Issue 1 https://doi.org/10.1093/nsr/nww093	journal	December 2016

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