Guest-induced emergent properties in Metal–Organic Frameworks
Abstract
Metal–Organic frameworks (MOFs) are crystalline nanoporous materials comprised of organic electron donors linked to metal ions by strong coordination bonds. Applications such as gas storage and separations are currently receiving considerable attention, but if the unique properties of MOFs could be extended to electronics, magnetics, and photonics, the impact on material science would greatly increase. Recently, we obtained “emergent properties,” such as electronic conductivity and energy transfer, by infiltrating MOF pores with “guest” molecules that interact with the framework electronic structure. In this Perspective, we define a path to emergent properties based on the Guest@MOF concept, using zinc-carboxylate and copper-paddlewheel MOFs for illustration. Energy transfer and light harvesting are discussed for zinc carboxylate frameworks infiltrated with triplet-scavenging organometallic compounds and thiophene- and fullerene-infiltrated MOF-177. In addition, we discuss the mechanism of charge transport in TCNQ-infiltrated HKUST-1, the first MOF with electrical conductivity approaching conducting organic polymers. Lastly, these examples show that guest molecules in MOF pores should be considered not merely as impurities or analytes to be sensed but also as an important aspect of rational design.
- Authors:
-
- Sandia National Lab. (SNL-CA), Livermore, CA (United States)
- Stanford Univ., Stanford, CA (United States)
- Publication Date:
- Research Org.:
- Sandia National Lab. (SNL-CA), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office
- OSTI Identifier:
- 1235927
- Report Number(s):
- SAND-2015-20820J
Journal ID: ISSN 1948-7185; 558248
- Grant/Contract Number:
- AC04-94AL85000
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Journal of Physical Chemistry Letters
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 7; Journal ID: ISSN 1948-7185
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Allendorf, Mark D., Foster, Michael E., Léonard, François, Stavila, Vitalie, Feng, Patrick L., Doty, F. Patrick, Leong, Kirsty, Ma, Eric Yue, Johnston, Scott R., Talin, A. Alec, and Shen, Zhi -Xun. Guest-induced emergent properties in Metal–Organic Frameworks. United States: N. p., 2015.
Web. doi:10.1021/jz5026883.
Allendorf, Mark D., Foster, Michael E., Léonard, François, Stavila, Vitalie, Feng, Patrick L., Doty, F. Patrick, Leong, Kirsty, Ma, Eric Yue, Johnston, Scott R., Talin, A. Alec, & Shen, Zhi -Xun. Guest-induced emergent properties in Metal–Organic Frameworks. United States. https://doi.org/10.1021/jz5026883
Allendorf, Mark D., Foster, Michael E., Léonard, François, Stavila, Vitalie, Feng, Patrick L., Doty, F. Patrick, Leong, Kirsty, Ma, Eric Yue, Johnston, Scott R., Talin, A. Alec, and Shen, Zhi -Xun. 2015.
"Guest-induced emergent properties in Metal–Organic Frameworks". United States. https://doi.org/10.1021/jz5026883. https://www.osti.gov/servlets/purl/1235927.
@article{osti_1235927,
title = {Guest-induced emergent properties in Metal–Organic Frameworks},
author = {Allendorf, Mark D. and Foster, Michael E. and Léonard, François and Stavila, Vitalie and Feng, Patrick L. and Doty, F. Patrick and Leong, Kirsty and Ma, Eric Yue and Johnston, Scott R. and Talin, A. Alec and Shen, Zhi -Xun},
abstractNote = {Metal–Organic frameworks (MOFs) are crystalline nanoporous materials comprised of organic electron donors linked to metal ions by strong coordination bonds. Applications such as gas storage and separations are currently receiving considerable attention, but if the unique properties of MOFs could be extended to electronics, magnetics, and photonics, the impact on material science would greatly increase. Recently, we obtained “emergent properties,” such as electronic conductivity and energy transfer, by infiltrating MOF pores with “guest” molecules that interact with the framework electronic structure. In this Perspective, we define a path to emergent properties based on the Guest@MOF concept, using zinc-carboxylate and copper-paddlewheel MOFs for illustration. Energy transfer and light harvesting are discussed for zinc carboxylate frameworks infiltrated with triplet-scavenging organometallic compounds and thiophene- and fullerene-infiltrated MOF-177. In addition, we discuss the mechanism of charge transport in TCNQ-infiltrated HKUST-1, the first MOF with electrical conductivity approaching conducting organic polymers. Lastly, these examples show that guest molecules in MOF pores should be considered not merely as impurities or analytes to be sensed but also as an important aspect of rational design.},
doi = {10.1021/jz5026883},
url = {https://www.osti.gov/biblio/1235927},
journal = {Journal of Physical Chemistry Letters},
issn = {1948-7185},
number = 7,
volume = 6,
place = {United States},
year = {Thu Mar 19 00:00:00 EDT 2015},
month = {Thu Mar 19 00:00:00 EDT 2015}
}
Web of Science
Works referenced in this record:
A Chemically Functionalizable Nanoporous Material [Cu3(TMA)2(H2O)3]n
journal, February 1999
- Chui, Stephen S.-Y.; Lo, Samuel M.-F.; Charmant, Jonathan P. H.
- Science, Vol. 283, Issue 5405, p. 1148-1150
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
journal, November 1999
- Li, Hailian; Eddaoudi, Mohamed; M., O'Keeffe
- Nature, Vol. 402, Issue 6759, p. 276-279
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
journal, January 2002
- Eddaoudi, Mohamed; Kim, Jaheon; Rosi, Nathaniel
- Science, Vol. 295, Issue 5554, p. 469-472
A Roadmap to Implementing Metal-Organic Frameworks in Electronic Devices: Challenges and Critical Directions
journal, September 2011
- Allendorf, Mark D.; Schwartzberg, Adam; Stavila, Vitalie
- Chemistry - A European Journal, Vol. 17, Issue 41, p. 11372-11388
MOF-based electronic and opto-electronic devices
journal, January 2014
- Stavila, V.; Talin, A. A.; Allendorf, M. D.
- Chem. Soc. Rev., Vol. 43, Issue 16
Tuning the Ferroelectric Polarization in a Multiferroic Metal–Organic Framework
journal, November 2013
- Di Sante, Domenico; Stroppa, Alessandro; Jain, Prashant
- Journal of the American Chemical Society, Vol. 135, Issue 48
A Highly Thermally Stable Ferroelectric Metal–Organic Framework and Its Thin Film with Substrate Surface Nature Dependent Morphology
journal, August 2011
- Pan, Chen; Nan, Jiangpu; Dong, Xueliang
- Journal of the American Chemical Society, Vol. 133, Issue 32
When metal organic frameworks turn into linear magnets
journal, March 2013
- Canepa, Pieremanuele; Chabal, Yves J.; Thonhauser, T.
- Physical Review B, Vol. 87, Issue 9
Two 3D metal–organic frameworks with different topologies, thermal stabilities and magnetic properties
journal, January 2012
- Gao, Ting; Wang, Xiao-Zhu; Gu, Hao-Xue
- CrystEngComm, Vol. 14, Issue 18
First-Principles Study of Microporous Magnets M-MOF-74 (M = Ni, Co, Fe, Mn): the Role of Metal Centers
journal, August 2013
- Zhang, Qiuju; Li, Baihai; Chen, Liang
- Inorganic Chemistry, Vol. 52, Issue 16
Dimethylammonium copper formate [(CH ) NH ]Cu(HCOO) : A metal-organic framework with quasi-one-dimensional antiferromagnetism and magnetostriction
journal, June 2013
- Wang, Zhenxing; Jain, Prashant; Choi, Kwang-Yong
- Physical Review B, Vol. 87, Issue 22
A Water-Stable Metal–Organic Framework with Highly Acidic Pores for Proton-Conducting Applications
journal, January 2013
- Taylor, Jared M.; Dawson, Karl W.; Shimizu, George K. H.
- Journal of the American Chemical Society, Vol. 135, Issue 4
Proton Conduction in Metal-Organic Frameworks and Related Modularly Built Porous Solids
journal, January 2013
- Yoon, Minyoung; Suh, Kyungwon; Natarajan, Srinivasan
- Angewandte Chemie International Edition, Vol. 52, Issue 10
Ion Conductivity and Transport by Porous Coordination Polymers and Metal–Organic Frameworks
journal, June 2013
- Horike, Satoshi; Umeyama, Daiki; Kitagawa, Susumu
- Accounts of Chemical Research, Vol. 46, Issue 11
Metal organic frameworks for electrochemical applications
journal, January 2012
- Morozan, Adina; Jaouen, Frédéric
- Energy & Environmental Science, Vol. 5, Issue 11
Luminescent metal–organic frameworks
journal, January 2009
- Allendorf, M. D.; Bauer, C. A.; Bhakta, R. K.
- Chemical Society Reviews, Vol. 38, Issue 5
Engineering metal-based luminescence in coordination polymers and metal–organic frameworks
journal, January 2013
- Heine, Johanna; Müller-Buschbaum, Klaus
- Chemical Society Reviews, Vol. 42, Issue 24
Multifunctional amino-decorated metal–organic frameworks: nonlinear-optic, ferroelectric, fluorescence sensing and photocatalytic properties
journal, January 2012
- Wen, Lili; Zhou, Li; Zhang, Bingguang
- Journal of Materials Chemistry, Vol. 22, Issue 42
A multifunctional three-dimensional uninodal eight-connected metal–organic framework based on pentanuclear cadmium subunits: New topology, fluorescent and NLO properties
journal, January 2012
- Cheng, Lin; Hu, Huayou; Zhang, Liming
- Inorganic Chemistry Communications, Vol. 15
Porous, Conductive Metal-Triazolates and Their Structural Elucidation by the Charge-Flipping Method
journal, June 2012
- Gándara, Felipe; Uribe-Romo, Fernando J.; Britt, David K.
- Chemistry - A European Journal, Vol. 18, Issue 34, p. 10595-10601
Conductivity, Doping, and Redox Chemistry of a Microporous Dithiolene-Based Metal−Organic Framework
journal, July 2010
- Kobayashi, Yoji; Jacobs, Benjamin; Allendorf, Mark D.
- Chemistry of Materials, Vol. 22, Issue 14
High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal–Organic Framework
journal, July 2012
- Narayan, Tarun C.; Miyakai, Tomoyo; Seki, Shu
- Journal of the American Chemical Society, Vol. 134, Issue 31
Mn 2 (2,5-disulfhydrylbenzene-1,4-dicarboxylate): A Microporous Metal–Organic Framework with Infinite (−Mn–S−) ∞ Chains and High Intrinsic Charge Mobility
journal, May 2013
- Sun, Lei; Miyakai, Tomoyo; Seki, Shu
- Journal of the American Chemical Society, Vol. 135, Issue 22
Large-scale screening of hypothetical metal–organic frameworks
journal, November 2011
- Wilmer, Christopher E.; Leaf, Michael; Lee, Chang Yeon
- Nature Chemistry, Vol. 4, Issue 2, p. 83-89
Tunable Electrical Conductivity in Metal-Organic Framework Thin-Film Devices
journal, December 2013
- Talin, A. Alec; Centrone, Andrea; Ford, Alexandra C.
- Science, Vol. 343, Issue 6166, p. 66-69
Energy and charge transfer by donor–acceptor pairs confined in a metal–organic framework: a spectroscopic and computational investigation
journal, January 2014
- Leong, Kirsty; Foster, Michael E.; Wong, Bryan M.
- J. Mater. Chem. A, Vol. 2, Issue 10
Charge-transfer guest interactions in luminescent MOFs: implications for solid-state temperature and environmental sensing
journal, January 2012
- Feng, Patrick L.; Leong, Kirsty; Allendorf, Mark D.
- Dalton Transactions, Vol. 41, Issue 29
Adsorption properties and structure of CO2 adsorbed on open coordination sites of metal–organic framework Ni2(dhtp) from gas adsorption, IR spectroscopy and X-ray diffraction
journal, January 2008
- Dietzel, Pascal D. C.; Johnsen, Rune E.; Fjellvåg, Helmer
- Chemical Communications, Issue 41
Metal–Organic Framework Materials as Chemical Sensors
journal, September 2011
- Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K.
- Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125
Molecular decoding using luminescence from an entangled porous framework
journal, January 2011
- Takashima, Yohei; Martínez, Virginia Martínez; Furukawa, Shuhei
- Nature Communications, Vol. 2, Issue 1
Design and synthesis of metal–organic frameworks using metal–organic polyhedra as supermolecular building blocks
journal, January 2009
- Perry IV, John J.; Perman, Jason A.; Zaworotko, Michael J.
- Chemical Society Reviews, Vol. 38, Issue 5
From Molecules to Crystal Engineering: Supramolecular Isomerism and Polymorphism in Network Solids
journal, June 2001
- Moulton, Brian; Zaworotko, Michael J.
- Chemical Reviews, Vol. 101, Issue 6
Connecting structure with function in metal–organic frameworks to design novel photo- and radioluminescent materials
journal, January 2012
- Perry IV, John J.; Feng, Patrick L.; Meek, Scott T.
- Journal of Materials Chemistry, Vol. 22, Issue 20, p. 10235-10248
Ab-initio prediction of materials properties with CRYSTAL: MOF-5 as a case study
journal, January 2006
- Civalleri, Bartolomeo; Napoli, Francesco; Noël, Yves
- CrystEngComm, Vol. 8, Issue 5
Electronic structure and properties of isoreticular metal-organic frameworks: The case of M-IRMOF1 (M=Zn, Cd, Be, Mg, and Ca)
journal, September 2005
- Fuentes-Cabrera, Miguel; Nicholson, Donald M.; Sumpter, Bobby G.
- The Journal of Chemical Physics, Vol. 123, Issue 12
Influence of Connectivity and Porosity on Ligand-Based Luminescence in Zinc Metal−Organic Frameworks
journal, June 2007
- Bauer, Christina A.; Timofeeva, Tatiana V.; Settersten, Thomas B.
- Journal of the American Chemical Society, Vol. 129, Issue 22
Do Special Noncovalent π–π Stacking Interactions Really Exist?
journal, April 2008
- Grimme, Stefan
- Angewandte Chemie International Edition, Vol. 47, Issue 18
Rethinking the term “pi-stacking”
journal, January 2012
- Martinez, Chelsea R.; Iverson, Brent L.
- Chemical Science, Vol. 3, Issue 7
Semiconductor Behavior of a Metal-Organic Framework (MOF)
journal, June 2007
- Alvaro, Mercedes; Carbonell, Esther; Ferrer, Belén
- Chemistry - A European Journal, Vol. 13, Issue 18
Metal–organic frameworks as semiconductors
journal, January 2010
- Silva, Cláudia Gomes; Corma, Avelino; García, Hermenegildo
- Journal of Materials Chemistry, Vol. 20, Issue 16
Electronic and vibrational properties of a MOF-5 metal–organic framework: ZnO quantum dot behaviour
journal, January 2004
- Bordiga, S.; Lamberti, C.; Ricchiardi, G.
- Chem. Commun., Issue 20
Hexakis(acetato)oxotetrazinc, a well-tailored molecular model of zinc oxide. An experimental and theoretical investigation of the electronic structure of Zn4O(acetate)6 and ZnO by means of UV and x-ray photoelectron spectroscopies and first principle local density molecular cluster calculations
journal, April 1992
- Bertoncello, Renzo; Bettinelli, Marco; Casarin, Maurizio
- Inorganic Chemistry, Vol. 31, Issue 9
High Capacity Hydrogen Adsorption in Cu(II) Tetracarboxylate Framework Materials: The Role of Pore Size, Ligand Functionalization, and Exposed Metal Sites
journal, February 2009
- Lin, Xiang; Telepeni, Irvin; Blake, Alexander J.
- Journal of the American Chemical Society, Vol. 131, Issue 6
Investigation of the synthesis, activation, and isosteric heats of CO2 adsorption of the isostructural series of metal–organic frameworks M3(BTC)2 (M = Cr, Fe, Ni, Cu, Mo, Ru)
journal, January 2012
- Wade, Casey R.; Dincă, Mircea
- Dalton Transactions, Vol. 41, Issue 26
Excited electronic states of transition-metal dimers and the VBCI model: an overview
journal, October 2001
- Tuczek, F.
- Coordination Chemistry Reviews, Vol. 219-221
CW and Pulsed ESR Spectroscopy of Cupric Ions in the Metal−Organic Framework Compound Cu 3 (BTC) 2
journal, February 2008
- Pöppl, Andreas; Kunz, Sebastian; Himsl, Dieter
- The Journal of Physical Chemistry C, Vol. 112, Issue 7
Cooperative magnetic behavior in the coordination polymers [Cu3(TMA)2L3] (L=H2O, pyridine)
journal, May 2000
- Zhang, Xi Xiang; Chui, Stephen S. -Y.; Williams, Ian D.
- Journal of Applied Physics, Vol. 87, Issue 9
Interdimer exchange in linear chain copper acetate-pyrazine
journal, January 1974
- Valentine, J. S.; Silverstein, A. J.; Soos, Z. G.
- Journal of the American Chemical Society, Vol. 96, Issue 1
Local Structure of Framework Cu(II) in HKUST-1 Metallorganic Framework: Spectroscopic Characterization upon Activation and Interaction with Adsorbates
journal, March 2006
- Prestipino, C.; Regli, L.; Vitillo, J. G.
- Chemistry of Materials, Vol. 18, Issue 5
The electronic spectrum of binuclear copper acetate monohydrate
journal, January 1972
- Dubicki, L.
- Australian Journal of Chemistry, Vol. 25, Issue 6
Detailed spectral studies of copper acetate: excited-state interactions in copper dimers
journal, May 1989
- Ross, Paul K.; Allendorf, Mark D.; Solomon, Edward I.
- Journal of the American Chemical Society, Vol. 111, Issue 11
Electronic structure of copper acetate monohydrate based on a coupled chromophore model
journal, January 1965
- Hansen, Aage E.; Ballhausen, C. J.
- Transactions of the Faraday Society, Vol. 61
Charge-transfer states of bridged transition metal dimers: mono- vs binuclear copper azide systems with relevance to oxy-hemocyanin
journal, June 1993
- Tuczek, Felix; Solomon, Edward I.
- Inorganic Chemistry, Vol. 32, Issue 13
Charge Photogeneration in Organic Solar Cells
journal, November 2010
- Clarke, Tracey M.; Durrant, James R.
- Chemical Reviews, Vol. 110, Issue 11, p. 6736-6767
Exciton diffusion in organic photovoltaic cells
journal, January 2014
- Menke, S. Matthew; Holmes, Russell J.
- Energy Environ. Sci., Vol. 7, Issue 2
The Evolution of Organometallic Complexes in Organic Light-Emitting Devices
journal, September 2007
- Thompson, Mark
- MRS Bulletin, Vol. 32, Issue 9, p. 694-701
Energy transfer in supramolecular materials for new applications in photonics and electronics
journal, July 2014
- Wong, Ken-Tsung; Bassani, Dario M.
- NPG Asia Materials, Vol. 6, Issue 7
Spectral- and Pulse-Shape Discrimination in Triplet-Harvesting Plastic Scintillators
journal, December 2012
- Feng, P. L.; Villone, J.; Hattar, K.
- IEEE Transactions on Nuclear Science, Vol. 59, Issue 6, p. 3312-3319
Importance of the Donor:Fullerene Intermolecular Arrangement for High-Efficiency Organic Photovoltaics
journal, June 2014
- Graham, Kenneth R.; Cabanetos, Clement; Jahnke, Justin P.
- Journal of the American Chemical Society, Vol. 136, Issue 27
A route to high surface area, porosity and inclusion of large molecules in crystals
journal, February 2004
- Chae, Hee K.; Siberio-Pérez, Diana Y.; Kim, Jaheon
- Nature, Vol. 427, Issue 6974, p. 523-527
A Shift from Diffusion Assisted to Energy Transfer Controlled Fluorescence Quenching in Polymer–Fullerene Photovoltaic Blends
journal, November 2012
- Ward, Alexander J.; Ruseckas, Arvydas; Samuel, Ifor D. W.
- The Journal of Physical Chemistry C, Vol. 116, Issue 45
Large-Pore Apertures in a Series of Metal-Organic Frameworks
journal, May 2012
- Deng, H.; Grunder, S.; Cordova, K. E.
- Science, Vol. 336, Issue 6084, p. 1018-1023
High Electrical Conductivity in Ni 3 (2,3,6,7,10,11-hexaiminotriphenylene) 2 , a Semiconducting Metal–Organic Graphene Analogue
journal, April 2014
- Sheberla, Dennis; Sun, Lei; Blood-Forsythe, Martin A.
- Journal of the American Chemical Society, Vol. 136, Issue 25
New Insight into the Nature of Cu(TCNQ): Solution Routes to Two Distinct Polymorphs and Their Relationship to Crystalline Films That Display Bistable Switching Behavior
journal, January 1999
- Heintz, Robert A.; Zhao, Hanhua; Ouyang, Xiang
- Inorganic Chemistry, Vol. 38, Issue 1
Electrical switching and memory phenomena in Cu‐TCNQ thin films
journal, March 1979
- Potember, R. S.; Poehler, T. O.; Cowan, D. O.
- Applied Physics Letters, Vol. 34, Issue 6
Electron transfer in a new highly conducting donor-acceptor complex
journal, February 1973
- Ferraris, John.; Cowan, D. O.; Walatka, V.
- Journal of the American Chemical Society, Vol. 95, Issue 3
Control of Charge Transfer in a Series of Ru 2 II,II /TCNQ Two-Dimensional Networks by Tuning the Electron Affinity of TCNQ Units: A Route to Synergistic Magnetic/Conducting Materials
journal, February 2010
- Miyasaka, Hitoshi; Motokawa, Natsuko; Matsunaga, Satoshi
- Journal of the American Chemical Society, Vol. 132, Issue 5
Electron transfer at the class II/III borderline of mixed valency: dependence of rates on solvent dynamics and observation of a localized-to-delocalized transition in freezing solvents
journal, September 2007
- Glover, Starla D.; Lear, Benjamin J.; Salsman, J. Catherine
- Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 366, Issue 1862
Solvent Dynamical Control of Ultrafast Ground State Electron Transfer: Implications for Class II−III Mixed Valency
journal, October 2007
- Lear, Benjamin J.; Glover, Starla D.; Salsman, J. Catherine
- Journal of the American Chemical Society, Vol. 129, Issue 42
Electronic conductivity in Berlin green and Prussian blue
journal, April 2011
- Pajerowski, Daniel M.; Watanabe, Takeshi; Yamamoto, Takashi
- Physical Review B, Vol. 83, Issue 15
Optical transitions of symmetrical mixed-valence systems in the Class II–III transition regimeElectronic supplementary information (ESI) is available: derivation of eqn. (39c), table summarizing the relationships between band maxima and band widths predicted by the two-state model and table of spectral properties of mixed-valence ruthenium(II)/(III) bridged by pyrazine and dicyanamide. See http://www.rsc.org/suppdata/cs/b0/b008034i/
journal, April 2002
- Brunschwig, Bruce S.; Creutz, Carol; Sutin, Norman
- Chemical Society Reviews, Vol. 31, Issue 3
Raman spectra of conducting TCNQ salts; Estimation of the degree of charge transfer from vibrational frequencies
journal, January 1980
- Matsuzaki, S.; Kuwata, R.; Toyoda, K.
- Solid State Communications, Vol. 33, Issue 4
Hexagonal Layered Materials Composed of [M2(O2CCF3)4] (M=Ru and Rh) Donors and TCNQ Acceptors
journal, November 2000
- Miyasaka, Hitoshi; Campos-Fernández, Cristian S.; Clérac, Rodolphe
- Angewandte Chemie, Vol. 39, Issue 21
Charge Transfer on the Nanoscale: Current Status
journal, July 2003
- Adams, David M.; Brus, Louis; Chidsey, Christopher E. D.
- The Journal of Physical Chemistry B, Vol. 107, Issue 28
Probing Hopping Conduction in Conjugated Molecular Wires Connected to Metal Electrodes †
journal, February 2011
- Luo, Liang; Choi, Seong Ho; Frisbie, C. Daniel
- Chemistry of Materials, Vol. 23, Issue 3
Works referencing / citing this record:
Reversible Optical Writing and Data Storage in an Anthracene‐Loaded Metal–Organic Framework
journal, February 2019
- Tu, Min; Reinsch, Helge; Rodríguez‐Hermida, Sabina
- Angewandte Chemie International Edition, Vol. 58, Issue 8
MOF‐Derived CuS@Cu‐BTC Composites as High‐Performance Anodes for Lithium‐Ion Batteries
journal, October 2019
- Wang, Ping; Shen, Mengqi; Zhou, Hu
- Small, Vol. 15, Issue 47
Defective Metal-Organic Frameworks
journal, January 2018
- Dissegna, Stefano; Epp, Konstantin; Heinz, Werner R.
- Advanced Materials, Vol. 30, Issue 37
Electroactive Metalorganic Frameworks
journal, October 2018
- Medina, Dana D.; Mähringer, Andre; Bein, Thomas
- Israel Journal of Chemistry, Vol. 58, Issue 9-10
New OLEDs Based on Zirconium Metal-Organic Framework
journal, January 2018
- Gutiérrez, Mario; Martin, Cristina; Kennes, Koen
- Advanced Optical Materials, Vol. 6, Issue 6
2D → 3D corrugated structure self‐assembled from 4,4′‐methylenebis( N ‐(pyridin‐2‐ylmethylene)aniline and terephthalic acid: Crystal structure and selective anion separations via anion exchange
journal, May 2020
- Ghorbanloo, Massomeh; Saffari, Mitra; Asadi, Mina
- Applied Organometallic Chemistry
Mechanical Properties in Metal-Organic Frameworks: Emerging Opportunities and Challenges for Device Functionality and Technological Applications
journal, November 2017
- Burtch, Nicholas C.; Heinen, Jurn; Bennett, Thomas D.
- Advanced Materials, Vol. 30, Issue 37
Redox-active metal–organic frameworks for energy conversion and storage
journal, January 2019
- Calbo, Joaquín; Golomb, Matthias J.; Walsh, Aron
- Journal of Materials Chemistry A, Vol. 7, Issue 28
Achieving current rectification ratios ≥ 10 5 across thin films of coordination polymer
journal, January 2019
- Prasoon, Anupam; Dhara, Barun; Roy, Debashree
- Chemical Science, Vol. 10, Issue 43
Electrically Conductive Porous Metal-Organic Frameworks
journal, January 2016
- Sun, Lei; Campbell, Michael G.; Dincă, Mircea
- Angewandte Chemie International Edition, Vol. 55, Issue 11
Exploiting redox activity in metal–organic frameworks: concepts, trends and perspectives
journal, January 2016
- D'Alessandro, D. M.
- Chemical Communications, Vol. 52, Issue 58
Rational approach to guest confinement inside MOF cavities for low-temperature catalysis
journal, March 2019
- Wang, Tiesheng; Gao, Lijun; Hou, Jingwei
- Nature Communications, Vol. 10, Issue 1
A porous, electrically conductive hexa-zirconium( iv ) metal–organic framework
journal, January 2018
- Goswami, Subhadip; Ray, Debmalya; Otake, Ken-ichi
- Chemical Science, Vol. 9, Issue 19
Strategies to Improve Electrical and Ionic Conductivities of Metal–Organic Frameworks
journal, December 2019
- Gordillo, Monica A.; Saha, Sourav
- Comments on Inorganic Chemistry, Vol. 40, Issue 2
An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensors
journal, January 2017
- Stassen, Ivo; Burtch, Nicholas; Talin, Alec
- Chemical Society Reviews, Vol. 46, Issue 11
Crystal structure and Hirshfeld surface analysis of (μ-2-{4-[(carboxylatomethyl)carbamoyl]benzamido}acetato-κ 2 O : O ′)bis[bis(1,10-phenanthroline-κ 2 N , N ′)copper(II)] dinitrate N , N ′-(1,4-phenylenedicarbonyl)diglycine monosolvate octahydrate
journal, April 2019
- Pook, Niels-Patrick; Adam, Arnold; Gjikaj, Mimoza
- Acta Crystallographica Section E Crystallographic Communications, Vol. 75, Issue 5
Crystal structure of bis[tris(1,10-phenanthroline-κ 2 N , N ′)cobalt(II)] tetranitrate N , N ′-(1,4-phenylenedicarbonyl)diglycine solvate octahydrate
journal, July 2015
- Pook, Niels-Patrick; Hentrich, Philipp; Gjikaj, Mimoza
- Acta Crystallographica Section E Crystallographic Communications, Vol. 71, Issue 8
An experimental and computational study of CO 2 adsorption in the sodalite-type M-BTT (M = Cr, Mn, Fe, Cu) metal–organic frameworks featuring open metal sites
journal, January 2018
- Asgari, Mehrdad; Jawahery, Sudi; Bloch, Eric D.
- Chemical Science, Vol. 9, Issue 20
High electrical conductivity and high porosity in a Guest@MOF material: evidence of TCNQ ordering within Cu 3 BTC 2 micropores
journal, January 2018
- Schneider, Christian; Ukaj, Dardan; Koerver, Raimund
- Chemical Science, Vol. 9, Issue 37
Schalten in Metall‐organischen Gerüsten
journal, December 2019
- Bigdeli, Fahime; Lollar, Christina T.; Morsali, Ali
- Angewandte Chemie
Copper nanoparticles embedded in the triphenylamine functionalized bithiazole–metal complex as active photocatalysts for visible light-driven hydrogen evolution
journal, January 2015
- Huo, Jingpei; Zeng, Heping
- Journal of Materials Chemistry A, Vol. 3, Issue 33
Semiconducting Coordination Polymers Based on the Predesigned Ternary Te-Fe-Cu Carbonyl Cluster and Conjugation-Interrupted Dipyridyl Linkers
journal, June 2017
- Shieh, Minghuey; Yu, Chia-Chi; Miu, Chia-Yeh
- Chemistry - A European Journal, Vol. 23, Issue 47
Optochemically Responsive 2D Nanosheets of a 3D Metal-Organic Framework Material
journal, May 2017
- Chaudhari, Abhijeet K.; Kim, Ha Jin; Han, Intaek
- Advanced Materials, Vol. 29, Issue 27
Doping of metal–organic frameworks towards resistive sensing
journal, May 2017
- Shiozawa, Hidetsugu; Bayer, Bernhard C.; Peterlik, Herwig
- Scientific Reports, Vol. 7, Issue 1
A highly emissive and stable zinc( ii ) metal–organic framework as a host–guest chemopalette for approaching white-light-emission
journal, January 2017
- Cai, Hong; Xu, Li-Li; Lai, He-Yun
- Chemical Communications, Vol. 53, Issue 56
Understanding and Controlling the Dielectric Response of Metal-Organic Frameworks
journal, March 2018
- Ryder, Matthew R.; Donà, Lorenzo; Vitillo, Jenny G.
- ChemPlusChem, Vol. 83, Issue 4
Elektrisch leitfähige poröse Metall-organische Gerüstverbindungen
journal, January 2016
- Sun, Lei; Campbell, Michael G.; Dincă, Mircea
- Angewandte Chemie, Vol. 128, Issue 11
Thin Film Thermoelectric Metal-Organic Framework with High Seebeck Coefficient and Low Thermal Conductivity
journal, April 2015
- Erickson, Kristopher J.; Léonard, François; Stavila, Vitalie
- Advanced Materials, Vol. 27, Issue 22
Photonic hybrid crystals constructed from in situ host–guest nanoconfinement of a light-emitting complex in metal–organic framework pores
journal, January 2016
- Chaudhari, Abhijeet K.; Ryder, Matthew R.; Tan, Jin-Chong
- Nanoscale, Vol. 8, Issue 12
Application of a novel 2D cadmium( ii )-MOF in the formation of a photo-switch with a substantial on–off ratio
journal, January 2015
- Roy, Sumit; Dey, Arka; Ray, Partha Pratim
- Chemical Communications, Vol. 51, Issue 65
Water-triggered macroscopic structural transformation of a metal–organic framework
journal, January 2016
- Ohtani, Masataka; Takase, Kazutaka; Wang, Pengyu
- CrystEngComm, Vol. 18, Issue 11
Rational modifications of PCN-700 to induce electrical conductivity: a computational study
journal, January 2020
- Chong, Sanggyu; Kim, Jihan
- Dalton Transactions, Vol. 49, Issue 1
Switching in Metal–Organic Frameworks
journal, December 2019
- Bigdeli, Fahime; Lollar, Christina T.; Morsali, Ali
- Angewandte Chemie International Edition, Vol. 59, Issue 12
Electrically Conducting Nanocomposites of Carbon Nanotubes and Metal‐Organic Frameworks with Strong Interactions between the two Components
journal, July 2019
- Schulze, Hendrik A.; Hoppe, Bastian; Schäfer, Malte
- ChemNanoMat, Vol. 5, Issue 9
Electrical semiconduction modulated by light in a cobalt and naphthalene diimide metal-organic framework
journal, December 2017
- Castaldelli, Evandro; Imalka Jayawardena, K. D. G.; Cox, David C.
- Nature Communications, Vol. 8, Issue 1
Electrochromic thin films of Zn-based MOF-74 nanocrystals facilely grown on flexible conducting substrates at room temperature
journal, August 2019
- Chaudhari, Abhijeet K.; Souza, Barbara E.; Tan, Jin-Chong
- APL Materials, Vol. 7, Issue 8
Reversible Optical Writing and Data Storage in an Anthracene‐Loaded Metal‐Organic Framework
journal, December 2018
- Tu, Min; Reinsch, Helge; Rodríguez-Hermida, Sabina
- Angewandte Chemie
Semiconducting Coordination Polymers Based on the Predesigned Ternary Te-Fe-Cu Carbonyl Cluster and Conjugation-Interrupted Dipyridyl Linkers
journal, July 2017
- Shieh, Minghuey; Yu, Chia-Chi; Miu, Chia-Yeh
- Chemistry - A European Journal, Vol. 23, Issue 47
Doping of metal-organic frameworks towards resistive sensing
preprint, January 2016
- Shiozawa, Hidetsugu; Bayer, Bernhard C.; Peterlik, Herwig
- arXiv
Metal–Organic Framework Co-MOF-74-Based Host–Guest Composites for Resistive Gas Sensing
text, January 2019
- Strauss, Ina; Mundstock, Alexander; Treger, Marvin
- Washington D.C. : American Chemical Society
Doping of metal-organic frameworks towards resistive sensing
preprint, January 2016
- Shiozawa, Hidetsugu; Bayer, Bernhard C.; Peterlik, Herwig
- arXiv