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Title: Interfacial development of electrophoretically deposited graphene oxide films on Al alloys

Journal Article · · Journal of the Electrochemical Society
DOI:https://doi.org/10.1149/2.0121511jes· OSTI ID:1235849
 [1];  [2];  [3];  [1]
  1. McGill Univ., Montreal, QC (Canada)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States); Brown Univ., Providence, RI (United States)
  3. Brookhaven National Lab. (BNL), Upton, NY (United States)

Adhesion between film and substrate is critical for electronic device and coating applications. Interfacial development between electrophoretically deposited graphene oxide films on Al 1100 and Al 5052 alloys were investigated using FT-IR and XPS depth profiling techniques. Obtained results suggest metal ion permeation from the substrates into deposited graphene oxide films. The interface between the films and the substrates were primarily composed of Al-O-C bonds from oxygenated defects on graphene oxide plane rather than expected Al-C formation. Films heat treated at 150 °C had change in microstructure and peak shifts in XPS spectra suggesting change in chemical structure of bonds between the films and the substrates.

Research Organization:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC00112704
OSTI ID:
1235849
Report Number(s):
BNL-108606-2015-JA; KC0403020
Journal Information:
Journal of the Electrochemical Society, Vol. 162, Issue 11; ISSN 0013-4651
Publisher:
The Electrochemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 2 works
Citation information provided by
Web of Science

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Cited By (1)