Results Of Hg Speciation Testing On DWPF SMECT-1, SMECT-3, And SMECT-5 Samples
- Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)
The Savannah River National Laboratory (SRNL) was tasked with preparing and shipping samples for Hg speciation by Eurofins Frontier Global Sciences, Inc. in Seattle, WA on behalf of the Savannah River Remediation (SRR) Mercury Task Team. The thirteenth shipment of samples was designated to include Defense Waste Processing Facility (DWPF) Slurry Mix Evaporator Condensate Tank (SMECT) from Sludge Receipt and Adjustment Tank (SRAT) Batch 736 and 738 samples. Triplicate samples of each material were prepared for this shipment. Each replicate was analyzed for seven Hg species: total Hg, total soluble (dissolved) Hg, elemental Hg [Hg(0)], ionic (inorganic) Hg [Hg(I) and Hg(II)], methyl Hg [CH3Hg-X, where X is a counter anion], ethyl Hg [CH3CH2-Hg-X, where X is a counter anion], and dimethyl Hg [(CH3)2Hg]. The difference between the total Hg and total soluble Hg measurements gives the particulate Hg concentration, i.e. Hg adsorbed to the surface of particulate matter in the sample but without resolution of the specific adsorbed species. The average concentrations of Hg species in the aqueous samples derived from Eurofins reported data corrected for dilutions performed by SRNL are tabulated.
- Research Organization:
- Savannah River Site (SRS), Aiken, SC (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC09-08SR22470
- OSTI ID:
- 1235433
- Report Number(s):
- SRNL-L3100-2015-00218; TRN: US1600245
- Country of Publication:
- United States
- Language:
- English
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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
RADIOACTIVE WASTES
SAVANNAH RIVER PLANT
CONCENTRATION RATIO
WASTE PROCESSING
MERCURY
SLURRIES
ABUNDANCE
CONDENSATES
DILUTION
QUALITATIVE CHEMICAL ANALYSIS
SAMPLING