High efficiency organic photovoltaic cells employing hybridized mixed-planar heterojunctions

Xue, Jiangeng; Uchida, Soichi; Rand, Barry P.; Forrest, Stephen

Title: High efficiency organic photovoltaic cells employing hybridized mixed-planar heterojunctions

Patent · Tue Aug 18 00:00:00 EDT 2015

OSTI ID:1210224

Xue, Jiangeng; Uchida, Soichi; Rand, Barry P.; Forrest, Stephen

A device is provided, having a first electrode, a second electrode, and a photoactive region disposed between the first electrode and the second electrode. The photoactive region includes a first photoactive organic layer that is a mixture of an organic acceptor material and an organic donor material, wherein the first photoactive organic layer has a thickness not greater than 0.8 characteristic charge transport lengths; a second photoactive organic layer in direct contact with the first organic layer, wherein the second photoactive organic layer is an unmixed layer of the organic acceptor material of the first photoactive organic layer, and the second photoactive organic layer has a thickness not less than about 0.1 optical absorption lengths; and a third photoactive organic layer disposed between the first electrode and the second electrode and in direct contact with the first photoactive organic layer. The third photoactive organic layer is an unmixed layer of the organic donor layer of the first photoactive organic layer and has a thickness not less than about 0.1 optical absorption lengths.

View Patent

Cite

Export

Save

Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC36-99GO10337

Assignee:: The Trustees of Princeton University (Princeton, NJ)

Patent Number(s):: 9,112,164

Application Number:: 14/068,430

OSTI ID:: 1210224

Resource Relation:: Patent File Date: 2013 Oct 31

Country of Publication:: United States

Language:: English

References (44)

Copolymer, a process for producing the same and an electroluminescent element using the same Uchida, Manabu; Izumizawa, Takenori; Furukawa, Kenji https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5587444 US Patent Document 5,587,444	patent	December 1996
Organic solar cell or light-emitting diode Meissner, Dieter; Rostalski, Jörn https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6559375 US Patent Document 6,559,375	patent	May 2003
Organic photovoltaic devices Forrest, Stephen R.; Yakimov, Aharon https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6657378 US Patent Document 6,657,378	patent	December 2003
Method of preparing photoresponsive devices, and devices made thereby Halls, Jonathan; Friend, Richard Henry https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6670213 US Patent Document 6,670,213	patent	December 2003
Organic photovoltaic devices Forrest, Stephen R.; Yakimov, Aharon https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20030042846 US Patent Application 09/948226; 20030042846	patent-application	March 2003
Organic photosensitive optoelectronic device Lazarev, Pavel I.; Nazarov, Victor V. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040067324 US Patent Application 10/656578; 20040067324	patent-application	April 2004
Modeling of thin film solar cells: Uniform field approximation Crandall, Richard S. Journal of Applied Physics, Vol. 54, Issue 12 https://doi.org/10.1063/1.331955	journal	December 1983
Highly efficient p–i–n type organic photovoltaic devices Gebeyehu, D.; Pfeiffer, M.; Maennig, B. Thin Solid Films, Vol. 451-452, p. 29-32 https://doi.org/10.1016/j.tsf.2003.10.087	journal	March 2004
Low-band-gap, sublimable rhenium(I) diimine complex for efficient bulk heterojunction photovoltaic devices Wong, H. L.; Lam, L. S. M.; Cheng, K. W. Applied Physics Letters, Vol. 84, Issue 14 https://doi.org/10.1063/1.1682676	journal	April 2004
Small molecular weight organic thin-film photodetectors and solar cells Peumans, Peter; Yakimov, Aharon; Forrest, Stephen R. Journal of Applied Physics, Vol. 93, Issue 7, p. 3693-3723 https://doi.org/10.1063/1.1534621	journal	April 2003
Two‐layer organic photovoltaic cell Tang, C. W. Applied Physics Letters, Vol. 48, Issue 2 https://doi.org/10.1063/1.96937	journal	January 1986
High photovoltage multiple-heterojunction organic solar cells incorporating interfacial metallic nanoclusters Yakimov, A.; Forrest, S. R. Applied Physics Letters, Vol. 80, Issue 9 https://doi.org/10.1063/1.1457531	journal	March 2002
Very-high-efficiency double-heterostructure copper phthalocyanine/C60 photovoltaic cells Peumans, P.; Forrest, S. R. Applied Physics Letters, Vol. 79, Issue 1 https://doi.org/10.1063/1.1384001	journal	July 2001
2.5% efficient organic plastic solar cells Shaheen, Sean E.; Brabec, Christoph J.; Sariciftci, N. Serdar Applied Physics Letters, Vol. 78, Issue 6, p. 841-843 https://doi.org/10.1063/1.1345834	journal	February 2001
Efficient bulk heterojunction photovoltaic cells using small-molecular-weight organic thin films Peumans, Peter; Uchida, Soichi; Forrest, Stephen R. Nature, Vol. 425, Issue 6954 https://doi.org/10.1038/nature01949	journal	September 2003
Bulk-heterojunction photovoltaic devices based on donor–acceptor organic small molecule blends Gebeyehu, D.; Maennig, B.; Drechsel, J. Solar Energy Materials and Solar Cells, Vol. 79, Issue 1, p. 81-92 https://doi.org/10.1016/S0927-0248(02)00369-0	journal	August 2003
4.2% efficient organic photovoltaic cells with low series resistances Xue, Jiangeng; Uchida, Soichi; Rand, Barry P. Applied Physics Letters, Vol. 84, Issue 16 https://doi.org/10.1063/1.1713036	journal	April 2004
Three‐layered organic solar cell with a photoactive interlayer of codeposited pigments Hiramoto, Masahiro; Fujiwara, Hiroshi; Yokoyama, Masaaki Applied Physics Letters, Vol. 58, Issue 10 https://doi.org/10.1063/1.104423	journal	March 1991
Ultrathin Organic Films Grown by Organic Molecular Beam Deposition and Related Techniques Forrest, Stephen R. Chemical Reviews, Vol. 97, Issue 6 https://doi.org/10.1021/cr941014o	journal	October 1997
Influence of codeposition on the performance of CuPc–C60 heterojunction photovoltaic devices Sullivan, P.; Heutz, S.; Schultes, S. M. Applied Physics Letters, Vol. 84, Issue 7 https://doi.org/10.1063/1.1643549	journal	February 2004
Relationship between electroluminescence and current transport in organic heterojunction light‐emitting devices Burrows, P. E.; Shen, Z.; Bulovic, V. Journal of Applied Physics, Vol. 79, Issue 10 https://doi.org/10.1063/1.362350	journal	May 1996
Carrier transport in multilayer organic photodetectors: II. Effects of anode preparation Xue, Jiangeng; Forrest, Stephen R. Journal of Applied Physics, Vol. 95, Issue 4 https://doi.org/10.1063/1.1640454	journal	February 2004
Variable range hopping as possible origin of a universal relation between conductivity and mobility in disordered organic semiconductors Paasch, G.; Lindner, T.; Scheinert, S. Synthetic Metals, Vol. 132, Issue 1, p. 97-104 https://doi.org/10.1016/S0379-6779(02)00236-9	journal	December 2002
Weak intrinsic charge transfer complexes: A new route for developing wide spectrum organic photovoltaic cells Ruani, G.; Fontanini, C.; Murgia, M. The Journal of Chemical Physics, Vol. 116, Issue 4 https://doi.org/10.1063/1.1429235	journal	January 2002
p‐i‐n like behavior in three‐layered organic solar cells having a co‐deposited interlayer of pigments Hiramoto, Masahiro; Fujiwara, Hiroshi; Yokoyama, Masaaki Journal of Applied Physics, Vol. 72, Issue 8 https://doi.org/10.1063/1.352274	journal	October 1992
Polymer Photovoltaic Cells: Enhanced Efficiencies via a Network of Internal Donor-Acceptor Heterojunctions Yu, G.; Gao, J.; Hummelen, J. C. Science, Vol. 270, Issue 5243, p. 1789-1791 https://doi.org/10.1126/science.270.5243.1789	journal	December 1995
Effects of Postproduction Treatment on Plastic Solar Cells Padinger, F.; Rittberger, R. S.; Sariciftci, N. S. Advanced Functional Materials, Vol. 13, Issue 1, p. 85-88 https://doi.org/10.1002/adfm.200390011	journal	January 2003
The effect of fullerene doping on photoelectric conversion using titanyl phthalocyanine and a perylene pigment Tsuzuki, Toshimitsu; Shirota, Yasuhiko; Rostalski, Jörn Solar Energy Materials and Solar Cells, Vol. 61, Issue 1 https://doi.org/10.1016/S0927-0248(99)00091-4	journal	February 2000
Monochromatic versus solar efficiencies of organic solar cells Rostalski, Jörn; Meissner, Dieter Solar Energy Materials and Solar Cells, Vol. 61, Issue 1, p. 87-95 https://doi.org/10.1016/S0927-0248(99)00099-9	journal	February 2000
Synthesis and aggregation behavior of hosts containing phthalocyanine and crown ether subunits Sielcken, Ot E.; Van Tilborg, Marcus M.; Roks, Maarten F. M. Journal of the American Chemical Society, Vol. 109, Issue 14 https://doi.org/10.1021/ja00248a021	journal	July 1987
Study of localized and extended excitons in 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) II. Photocurrent response at low electric fields Bulović, V.; Forrest, S. R. Chemical Physics, Vol. 210, Issue 1-2, p. 13-25 https://doi.org/10.1016/0301-0104(96)00115-2	journal	October 1996
Long-Range Singlet Energy Transfer in Perylene Bis(phenethylimide) Films Gregg, Brian A.; Sprague, Julian; Peterson, Mark W. The Journal of Physical Chemistry B, Vol. 101, Issue 27 https://doi.org/10.1021/jp9703263	journal	July 1997
Exciton diffusion and optical interference in organic donor–acceptor photovoltaic cells Stübinger, Thomas; Brütting, Wolfgang Journal of Applied Physics, Vol. 90, Issue 7 https://doi.org/10.1063/1.1394920	journal	October 2001
Modeling photocurrent action spectra of photovoltaic devices based on organic thin films Pettersson, Leif A. A.; Roman, Lucimara S.; Inganäs, Olle Journal of Applied Physics, Vol. 86, Issue 1, p. 487-496 https://doi.org/10.1063/1.370757	journal	July 1999
Exciton Migration and Cathode Quenching in Organic Light Emitting Diodes ^† Burin, Alexander L.; Ratner, Mark A. The Journal of Physical Chemistry A, Vol. 104, Issue 20 https://doi.org/10.1021/jp994162x	journal	May 2000
Photoluminescence quenching of Alq₃ by metal deposition: A surface analytical investigation Choong, V.-E.; Park, Y.; Gao, Y. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 16, Issue 3, p. 1838-1841 https://doi.org/10.1116/1.581115	journal	May 1998
Exciton diffusion and dissociation in a poly(p‐phenylenevinylene)/C₆₀ heterojunction photovoltaic cell Halls, J. J. M.; Pichler, K.; Friend, R. H. Applied Physics Letters, Vol. 68, Issue 22, p. 3120-3122 https://doi.org/10.1063/1.115797	journal	May 1996
Photoluminescence quenching at a ${p o l y t h i o p h e n e / C}_{60}$ heterojunction Theander, M.; Yartsev, A.; Zigmantas, D. Physical Review B, Vol. 61, Issue 19 https://doi.org/10.1103/PhysRevB.61.12957	journal	May 2000
Organic p-i-n solar cells Maennig, B.; Drechsel, J.; Gebeyehu, D. Applied Physics A, Vol. 79, Issue 1 https://doi.org/10.1007/s00339-003-2494-9	journal	June 2004
Molecular level control of donor/acceptor heterostructuresin organic photovoltaic devices Pradhan, Basudev; Bandyopadhyay, Anirban; Pal, Amlan J. Applied Physics Letters, Vol. 85, Issue 4 https://doi.org/10.1063/1.1775891	journal	July 2004
Efficient photodiodes from interpenetrating polymer networks Halls, J. J. M.; Walsh, C. A.; Greenham, N. C. Nature, Vol. 376, Issue 6540, p. 498-500 https://doi.org/10.1038/376498a0	journal	August 1995
Organic small molecule solar cells with a homogeneously mixed copper phthalocyanine: C60 active layer Uchida, Soichi; Xue, Jiangeng; Rand, Barry P. Applied Physics Letters, Vol. 84, Issue 21 https://doi.org/10.1063/1.1755833	journal	May 2004
Amorphous silicon alloy photovoltaic research—present and future Guha, S.; Yang, J.; Banerjee, A. Progress in Photovoltaics: Research and Applications, Vol. 8, Issue 1, p. 141-150 https://doi.org/10.1002/(SICI)1099-159X(200001/02)8:1<141::AID-PIP305>3.0.CO;2-I	journal	January 2000
High efficiency organic solar cells based on single or multiple PIN structures Drechsel, J.; Männig, B.; Kozlowski, F. Thin Solid Films, Vol. 451-452, p. 515-517 https://doi.org/10.1016/j.tsf.2003.11.044	journal	March 2004

Similar Records

High efficiency organic photovoltaic cells employing hybridized mixed-planar heterojunctions

Patent · Tue Nov 19 00:00:00 EST 2013 · OSTI ID:1210224

Xue, Jiangeng; Uchida, Soichi; Rand, Barry P; +1 more

Hybrid planar-mixed heterojunction for organic photovoltaics

Patent · Tue Sep 14 00:00:00 EDT 2021 · OSTI ID:1210224

Forrest, Stephen R.; Zimmerman, Jeramy D.; Xiao, Xin

Stacked organic photosensitive devices

Patent · Tue Mar 27 00:00:00 EDT 2007 · OSTI ID:1210224

Forrest, Stephen; Xue, Jiangeng; Uchida, Soichi; +1 more

Related Subjects

14 SOLAR ENERGY

Title: High efficiency organic photovoltaic cells employing hybridized mixed-planar heterojunctions

Citation Formats

References (44)

Similar Records

Related Subjects