Seed-Mediated Growth of Gold Nanocrystals: Changes to the Crystallinity or Morphology as Induced by the Treatment of Seeds with a Sulfur Species
- Georgia Inst. of Technology, Atlanta, GA (United States). School of Chemistry and Biochemistry
- Georgia Inst. of Technology, Atlanta, GA (United States) Wallace H. Coulter Dept. of Biomedical Engineering; Emory Univ., Atlanta, GA (United States); Wuhan Univ. (China). College of Chemistry and Molecular Sciences. State Key Lab. of Analytical Chemistry for Biology and Medicine
- Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Matter Physics and Materials Science Dept.
- Georgia Inst. of Technology, Atlanta, GA (United States). School of Chemistry and Biochemistry
- Georgia Inst. of Technology, Atlanta, GA (United States) Wallace H. Coulter Dept. of Biomedical Engineering; Emory Univ., Atlanta, GA (United States)
- Georgia Inst. of Technology, Atlanta, GA (United States). School of Chemistry and Biochemistry and Wallace H. Coulter Dept. of Biomedical Engineering; Emory Univ., Atlanta, GA (United States)
We report our observation of changes to the crystallinity or morphology during seed-mediated growth of Au nanocrystals. When single-crystal Au seeds with a spherical or rod-like shape were treated with a chemical species such as S₂O₃²⁻ ions, twin defects were developed during the growth process to generate multiply twinned nanostructures. X-ray photoelectron spectroscopy analysis indicated that the S₂O₃²⁻ ions were chemisorbed on the surfaces of the seeds during the treatment. The chemisorbed S₂O₃²⁻ ions somehow influenced the crystallization of Au atoms added onto the surface during a growth process, leading to the formation of twin defects. In contrast to the spherical and rod-like Au seeds, the single-crystal structure was retained to generate a concave morphology when single-crystal Au seeds with a cubic or octahedral shape were used for a similar treatment and then seed-mediated growth. The different outcomes are likely related to the difference in spatial distribution of S₂O₃²⁻ ions chemisorbed on the surface of a seed. This approach based on surface modification is potentially extendable to other noble metals for engineering the crystallinity and morphology of nanocrystals formed via seed-mediated growth.
- Research Organization:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Grant/Contract Number:
- SC00112704
- OSTI ID:
- 1201341
- Report Number(s):
- BNL-107873-2015-JA; R&D Project: MA015MACA; KC0201010
- Journal Information:
- Journal of Physical Chemistry. B, Vol. 118, Issue 49; ISSN 1520-6106
- Publisher:
- American Chemical SocietyCopyright Statement
- Country of Publication:
- United States
- Language:
- English
Web of Science
Building up strain in colloidal metal nanoparticle catalysts
|
journal | January 2015 |
Seed-Mediated Growth of Colloidal Metal Nanocrystals
|
journal | December 2016 |
Keimvermitteltes Wachstum kolloidaler Metallnanokristalle
|
journal | December 2016 |
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