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Title: A Stable Fluorinated and Alkylated Lithium Malonatoborate Salt for Lithium Ion Battery Application

Journal Article · · ChemComm
DOI:https://doi.org/10.1039/C5CC01428J· OSTI ID:1185994
 [1];  [2];  [3];  [4];  [3];  [1]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  2. Univ. of Tennessee, Knoxville, TN (United States)
  3. Univ. of Texas, Austin, TX (United States)
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
+ Show Author Affiliations

A new fluorinated and alkylated lithium malonatoborate salt, lithium bis(2-methyl-2-fluoromalonato)borate (LiBMFMB), has been synthesized for lithium ion battery application. A 0.8 M LiBMFMB solution is obtained in a mixture of ethylene carbonate (EC) and ethyl methyl carbonate (EMC) (1:2 by wt.). The new LiBMFMB based electrolyte exhibits good cycling stability and rate capability in LiNi0.5Mn1.5O4 and graphite based half-cells.

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1185994
Journal Information:
ChemComm, Vol. 51, Issue 48; ISSN 1359-7345
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 17 works
Citation information provided by
Web of Science

References (31)

A New Class of Electrochemically and Thermally Stable Lithium Salts for Lithium Battery Electrolytes journal January 1996
Lithium Bis[5-fluoro-2-olato-1-benzenesulfonato (2-)-O,Oʹ]borate(1-), a New Anodically and Cathodically Stable Salt for Electrolytes of Lithium-Ion Cells journal January 1998
Synthesis and Characterization of Network Type Single Ion Conductors journal March 2004
Synthesis and Characterization of Lithium Bis(fluoromalonato)borate for Lithium-Ion Battery Applications journal November 2013
A New Class of Electrochemically and Thermally Stable Lithium Salts for Lithium Battery Electrolytes journal January 1995
Formation of Solid Electrolyte Interface in Lithium Nickel Mixed Oxide Electrodes during the First Cycling journal January 2002
Formation of the Graphite/Electrolyte Interface by Lithium Bis(oxalato)borate journal January 2003
Interfacial reactions between graphite electrodes and propylene carbonate-based solutions: Electrolyte-concentration dependence of electrochemical lithium intercalation reaction journal January 2008
Synthesis and Characterization of Network Single Ion Conductors Based on Comb-Branched Polyepoxide Ethers and Lithium Bis(allylmalonato)borate journal January 2006
Network Single Ion Conductors Based on Comb-Branched Polyepoxide Ethers and Lithium Bis(allylmalonato)borate journal July 2004
Synthesis and electrochemistry of 5V LiNi0.4Mn1.6O4 cathode materials synthesized by different methods journal February 2008
Polyelectrolyte Membranes Containing Lithium Malonato(difluoro)borate for Lithium-Ion Systems conference January 2011
How Conductivities and Viscosities of PC-DEC and PC-EC Solutions of LiBF[sub 4], LiPF[sub 6], LiBOB, Et[sub 4]NBF[sub 4], and Et[sub 4]NPF[sub 6] Differ and Why journal January 2004
Synthesis and Electrochemistry of LiNi[sub x]Mn[sub 2−x]O[sub 4] journal January 1997
Six-Membered-Ring Malonatoborate-Based Lithium Salts as Electrolytes for Lithium Ion Batteries conference January 2011
New gel polyelectrolytes for rechargeable lithium batteries journal November 2004
The influence of preparation conditions on electrochemical properties of LiNi0.5Mn1.5O4 thin film electrodes by PLD journal February 2007
Lithium Bis(oxalato)borate Stabilizes Graphite Anode in Propylene Carbonate journal September 2002
Weakly Coordinating Anions, and the Exceptional Conductivity of Their Nonaqueous Solutions journal January 2001
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries journal October 2004
Bis(fluoromalonato)borate (BFMB) anion based ionic liquid as an additive for lithium-ion battery electrolytes journal January 2014
Doped sulfone electrolytes for high voltage Li-ion cell applications journal July 2009
Electrochemical and Infrared Studies of the Reduction of Organic Carbonates journal January 2001
A New Class of Electrochemically and Thermally Stable Lithium Salts for Lithium Battery Electrolytes. V. Synthesis and Properties of Lithium Bis[2,3-pyridinediolato(2−)-O,Oʹ]borate journal January 2000
Electrochemical Intercalation of Lithium Ion within Graphite from Propylene Carbonate Solutions journal January 2003
Lithium-Ion Conducting Electrolyte Salts for Lithium Batteries journal November 2011
Film formation in LiBOB-containing electrolytes journal February 2006
Chloride-Free Method to Synthesise New Ionic Liquids with Mixed Borate Anions journal February 2009
A New Class of Electrochemically and Thermally Stable Lithium Salts for Lithium Battery Electrolytes: IV. Investigations of the Electrochemical Oxidation of Lithium Organoborates journal November 1997
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries journal December 2004
New Gel polyelectrolytes for rechargeable lithium batteries report June 2003

Cited By (4)

A Novel Electrolyte Salt Additive for Lithium-Ion Batteries with Voltages Greater than 4.7 V journal November 2016
Designing Low Impedance Interface Films Simultaneously on Anode and Cathode for High Energy Batteries journal May 2018
Fluor und Lithium: Ideale Partner für Elektrolyte in wiederaufladbaren Hochleistungsbatterien journal July 2019
Fluorine and Lithium: Ideal Partners for High‐Performance Rechargeable Battery Electrolytes journal November 2019

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