Monodisperse core/shell Ni/FePt nanoparticles and their con-version to Ni/Pt to catalyze oxygen reduction

Zhang, Sen; Hao, Yizhou; Su, Dong; Doan-Nguyen, Vicky V. T.; Wu, Yaoting; Li, Jing; Sun, Shouheng; Murray, Christopher B.

doi:10.1021/ja5099066

Title: Monodisperse core/shell Ni/FePt nanoparticles and their con-version to Ni/Pt to catalyze oxygen reduction

Journal Article · Tue Oct 28 00:00:00 EDT 2014 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/ja5099066· OSTI ID:1182492

Zhang, Sen ^[1]; Hao, Yizhou ^[1]; Su, Dong ^[2]; Doan-Nguyen, Vicky V. T. ^[1]; Wu, Yaoting ^[1]; Li, Jing ^[2]; Sun, Shouheng ^[3]; Murray, Christopher B. ^[1]

Univ. of Pennsylvania, Philadelphia, PA (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Brown Univ., Providence, RI (United States)

We report a size-controllable synthesis of monodisperse core/shell Ni/FePt nanoparticles (NPs) via a seed-mediated growth and their subsequent conversion to Ni/Pt NPs. Preventing surface oxidation of the Ni seeds is essential for the growth of uniform FePt shells. These Ni/FePt NPs have a thin (≈ 1 nm) FePt shell, and can be converted to Ni/Pt by acetic acid wash to yield active catalysts for oxygen reduction reaction (ORR). Tuning the core size allow for optimization of their electrocatalytic activity. The specific activity and mass activity of 4.2 nm/0.8 nm core/shell Ni/FePt reach 1.95 mA/cm² and 490 mA/mg_Pt at 0.9 V (vs. reversible hydrogen electrode, RHE), which are much higher than those of benchmark commercial Pt catalyst (0.34 mA/cm² and 92 mA/mg_Pt at 0.9 V). Our studies provide a robust approach to monodisperse core/shell NPs with non-precious metal core, making it possible to develop advanced NP catalysts with ultralow Pt content for ORR and many other heterogeneous reactions.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC00112704

OSTI ID:: 1182492

Report Number(s):: BNL-107369-2015-JA; R&D Project: 16060; KC0403020

Journal Information:: Journal of the American Chemical Society, Vol. 136, Issue 45; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 147 works

Citation information provided by
Web of Science

References (47)

Improved Oxygen Reduction Activity on Pt₃Ni(111) via Increased Surface Site Availability Stamenkovic, V. R.; Fowler, B.; Mun, B. S. Science, Vol. 315, Issue 5811, p. 493-497 https://doi.org/10.1126/science.1135941	journal	January 2007
Tuning Nanoparticle Catalysis for the Oxygen Reduction Reaction Guo, Shaojun; Zhang, Sen; Sun, Shouheng Angewandte Chemie International Edition, Vol. 52, Issue 33 https://doi.org/10.1002/anie.201207186	journal	June 2013
Advanced Platinum Alloy Electrocatalysts for the Oxygen Reduction Reaction Wang, Chao; Markovic, Nenad M.; Stamenkovic, Vojislav R. ACS Catalysis, Vol. 2, Issue 5 https://doi.org/10.1021/cs3000792	journal	April 2012
Platinum-Based Oxygen Reduction Electrocatalysts Wu, Jianbo; Yang, Hong Accounts of Chemical Research, Vol. 46, Issue 8 https://doi.org/10.1021/ar300359w	journal	April 2013
Mixed-PtPd-Shell PtPdCu Nanoparticle Nanotubes Templated from Copper Nanowires as Efficient and Highly Durable Electrocatalysts Li, Hui-Hui; Cui, Chun-Hua; Zhao, Shuo Advanced Energy Materials, Vol. 2, Issue 10 https://doi.org/10.1002/aenm.201200207	journal	May 2012
Engineering Interface and Surface of Noble Metal Nanoparticle Nanotubes toward Enhanced Catalytic Activity for Fuel Cell Applications Cui, Chun-Hua; Yu, Shu-Hong Accounts of Chemical Research, Vol. 46, Issue 7 https://doi.org/10.1021/ar300254b	journal	February 2013
Monodisperse Pt ₃ Co Nanoparticles as a Catalyst for the Oxygen Reduction Reaction: Size-Dependent Activity Wang, Chao; van der Vliet, Dennis; Chang, Kee-Chul The Journal of Physical Chemistry C, Vol. 113, Issue 45 https://doi.org/10.1021/jp908203p	journal	October 2009
A General Approach to the Size- and Shape-Controlled Synthesis of Platinum Nanoparticles and Their Catalytic Reduction of Oxygen Wang, Chao; Daimon, Hideo; Onodera, Taigo Angewandte Chemie International Edition, Vol. 47, Issue 19 https://doi.org/10.1002/anie.200800073	journal	April 2008
Compositional segregation in shaped Pt alloy nanoparticles and their structural behaviour during electrocatalysis Cui, Chunhua; Gan, Lin; Heggen, Marc Nature Materials, Vol. 12, Issue 8 https://doi.org/10.1038/nmat3668	journal	June 2013
Highly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces Chen, C.; Kang, Y.; Huo, Z. Science, Vol. 343, Issue 6177 https://doi.org/10.1126/science.1249061	journal	February 2014
Synthesis and Oxygen Reduction Activity of Shape-Controlled Pt ₃ Ni Nanopolyhedra Zhang, Jun; Yang, Hongzhou; Fang, Jiye Nano Letters, Vol. 10, Issue 2 https://doi.org/10.1021/nl903717z	journal	February 2010
Synthesis and Characterization of 9 nm Pt–Ni Octahedra with a Record High Activity of 3.3 A/mg _Pt for the Oxygen Reduction Reaction Choi, Sang-Il; Xie, Shuifen; Shao, Minhua Nano Letters, Vol. 13, Issue 7 https://doi.org/10.1021/nl401881z	journal	June 2013
Icosahedral Platinum Alloy Nanocrystals with Enhanced Electrocatalytic Activities Wu, Jianbo; Qi, Liang; You, Hongjun Journal of the American Chemical Society, Vol. 134, Issue 29 https://doi.org/10.1021/ja303950v	journal	July 2012
FePt and CoPt Nanowires as Efficient Catalysts for the Oxygen Reduction Reaction Guo, Shaojun; Li, Dongguo; Zhu, Huiyuan Angewandte Chemie International Edition, Vol. 52, Issue 12 https://doi.org/10.1002/anie.201209871	journal	February 2013
Synthesis and Electrocatalytic Properties of Cubic Mn−Pt Nanocrystals (Nanocubes) Kang, Yijin; Murray, Christopher B. Journal of the American Chemical Society, Vol. 132, Issue 22 https://doi.org/10.1021/ja100705j	journal	June 2010
Carbon Monoxide-Assisted Size Confinement of Bimetallic Alloy Nanoparticles Cui, Chunhua; Gan, Lin; Neumann, Maximilian Journal of the American Chemical Society, Vol. 136, Issue 13 https://doi.org/10.1021/ja4124658	journal	March 2014
Synthesis of Homogeneous Pt-Bimetallic Nanoparticles as Highly Efficient Electrocatalysts Wang, Chao; Chi, Miaofang; Li, Dongguo ACS Catalysis, Vol. 1, Issue 10, p. 1355-1359 https://doi.org/10.1021/cs200328z	journal	September 2011
Synthetic Control of FePtM Nanorods (M = Cu, Ni) To Enhance the Oxygen Reduction Reaction Zhu, Huiyuan; Zhang, Sen; Guo, Shaojun Journal of the American Chemical Society, Vol. 135, Issue 19 https://doi.org/10.1021/ja403041g	journal	May 2013
Ternary Heterostructured Nanoparticle Tubes: A Dual Catalyst and Its Synergistic Enhancement Effects for O2/H2O2 Reduction Cui, Chun-Hua; Li, Hui-Hui; Yu, Jin-Wen Angewandte Chemie International Edition, Vol. 49, Issue 48 https://doi.org/10.1002/anie.201003261	journal	October 2010
Ultrathin PtPdTe Nanowires as Superior Catalysts for Methanol Electrooxidation Li, Hui-Hui; Zhao, Shuo; Gong, Ming Angewandte Chemie International Edition, Vol. 52, Issue 29 https://doi.org/10.1002/anie.201302090	journal	June 2013
Tuning Nanoparticle Structure and Surface Strain for Catalysis Optimization Zhang, Sen; Zhang, Xu; Jiang, Guangming Journal of the American Chemical Society, Vol. 136, Issue 21 https://doi.org/10.1021/ja5030172	journal	May 2014
Structurally ordered intermetallic platinum–cobalt core–shell nanoparticles with enhanced activity and stability as oxygen reduction electrocatalysts Wang, Deli; Xin, Huolin L.; Hovden, Robert Nature Materials, Vol. 12, Issue 1, p. 81-87 https://doi.org/10.1038/nmat3458	journal	October 2012
A Surfactant-Free Strategy for Synthesizing and Processing Intermetallic Platinum-Based Nanoparticle Catalysts Chen, Hao; Wang, Deli; Yu, Yingchao Journal of the American Chemical Society, Vol. 134, Issue 44 https://doi.org/10.1021/ja308674b	journal	October 2012
Structure-Induced Enhancement in Electrooxidation of Trimetallic FePtAu Nanoparticles Zhang, Sen; Guo, Shaojun; Zhu, Huiyuan Journal of the American Chemical Society, Vol. 134, Issue 11 https://doi.org/10.1021/ja300708j	journal	March 2012
Strained Lattice with Persistent Atomic Order in Pt ₃ Fe ₂ Intermetallic Core–Shell Nanocatalysts Prabhudev, Sagar; Bugnet, Matthieu; Bock, Christina ACS Nano, Vol. 7, Issue 7 https://doi.org/10.1021/nn4019009	journal	June 2013
Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces Stamenkovic, Vojislav R.; Mun, Bongjin Simon; Arenz, Matthias Nature Materials, Vol. 6, Issue 3, p. 241-247 https://doi.org/10.1038/nmat1840	journal	February 2007
Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts Strasser, Peter; Koh, Shirlaine; Anniyev, Toyli Nature Chemistry, Vol. 2, Issue 6 https://doi.org/10.1038/nchem.623	journal	April 2010
Platinum Monolayer Fuel Cell Electrocatalysts Adzic, R. R.; Zhang, J.; Sasaki, K. Topics in Catalysis, Vol. 46, Issue 3-4, p. 249-262 https://doi.org/10.1007/s11244-007-9003-x	journal	November 2007
Platinum-Based Electrocatalysts with Core-Shell Nanostructures Yang, Hong Angewandte Chemie International Edition, Vol. 50, Issue 12 https://doi.org/10.1002/anie.201005868	journal	February 2011
Pd-Pt Bimetallic Nanodendrites with High Activity for Oxygen Reduction Lim, B.; Jiang, M.; Camargo, P. H. C. Science, Vol. 324, Issue 5932, p. 1302-1305 https://doi.org/10.1126/science.1170377	journal	May 2009
Multimetallic Au/FePt ₃ Nanoparticles as Highly Durable Electrocatalyst Wang, Chao; van der Vliet, Dennis; More, Karren L. Nano Letters, Vol. 11, Issue 3 https://doi.org/10.1021/nl102369k	journal	March 2011
Core/Shell Pd/FePt Nanoparticles as an Active and Durable Catalyst for the Oxygen Reduction Reaction Mazumder, Vismadeb; Chi, Miaofang; More, Karren L. Journal of the American Chemical Society, Vol. 132, Issue 23 https://doi.org/10.1021/ja1024436	journal	June 2010
Core/Shell Au/CuPt Nanoparticles and Their Dual Electrocatalysis for Both Reduction and Oxidation Reactions Sun, Xiaolian; Li, Dongguo; Ding, Yong Journal of the American Chemical Society, Vol. 136, Issue 15 https://doi.org/10.1021/ja500590n	journal	April 2014
Stabilization and compressive strain effect of AuCu core on Pt shell for oxygen reduction reaction Yang, Jinhua; Chen, Xiaojun; Yang, Xianfeng Energy & Environmental Science, Vol. 5, Issue 10 https://doi.org/10.1039/c2ee22172a	journal	January 2012
Morphology and Lateral Strain Control of Pt Nanoparticles via Core–Shell Construction Using Alloy AgPd Core Toward Oxygen Reduction Reaction Yang, Jinhua; Yang, Jun; Ying, Jackie Y. ACS Nano, Vol. 6, Issue 11 https://doi.org/10.1021/nn303298s	journal	October 2012
Ordered bilayer ruthenium–platinum core-shell nanoparticles as carbon monoxide-tolerant fuel cell catalysts Hsieh, Yu-Chi; Zhang, Yu; Su, Dong Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3466	journal	September 2013
Seed-Mediated Synthesis of Core/Shell FePtM/FePt (M = Pd, Au) Nanowires and Their Electrocatalysis for Oxygen Reduction Reaction Guo, Shaojun; Zhang, Sen; Su, Dong Journal of the American Chemical Society, Vol. 135, Issue 37 https://doi.org/10.1021/ja406091p	journal	September 2013
Platinum Monolayer Electrocatalysts for O₂ Reduction: Pt Monolayer on Pd(111) and on Carbon-Supported Pd Nanoparticles Zhang, J.; Mo, Y.; Vukmirovic, M. B. The Journal of Physical Chemistry B, Vol. 108, Issue 30, p. 10955-10964 https://doi.org/10.1021/jp0379953	journal	July 2004
Platinum-Monolayer Shell on AuNi _0.5 Fe Nanoparticle Core Electrocatalyst with High Activity and Stability for the Oxygen Reduction Reaction Gong, Kuanping; Su, Dong; Adzic, Radoslav R. Journal of the American Chemical Society, Vol. 132, Issue 41 https://doi.org/10.1021/ja1063873	journal	October 2010
Highly stable Pt monolayer on PdAu nanoparticle electrocatalysts for the oxygen reduction reaction Sasaki, Kotaro; Naohara, Hideo; Choi, YongMan Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms2124	journal	January 2012
Control of Metal Nanocrystal Size Reveals Metal-Support Interface Role for Ceria Catalysts Cargnello, M.; Doan-Nguyen, V. V. T.; Gordon, T. R. Science, Vol. 341, Issue 6147 https://doi.org/10.1126/science.1240148	journal	July 2013
Dispersible Ferromagnetic FePt Nanoparticles Kim, Jaemin; Rong, Chuanbing; Liu, J. Ping Advanced Materials, Vol. 21, Issue 8 https://doi.org/10.1002/adma.200801620	journal	February 2009
Bulk Metallic Glass-like Scattering Signal in Small Metallic Nanoparticles Doan-Nguyen, Vicky V. T.; Kimber, Simon A. J.; Pontoni, Diego ACS Nano, Vol. 8, Issue 6 https://doi.org/10.1021/nn501591g	journal	May 2014
Z-contrast stem for materials science Pennycook, S. J. Ultramicroscopy, Vol. 30, Issue 1-2 https://doi.org/10.1016/0304-3991(89)90173-3	journal	June 1989
Oxygen reduction in nanoporous metal–ionic liquid composite electrocatalysts Snyder, J.; Fujita, T.; Chen, M. W. Nature Materials, Vol. 9, Issue 11 https://doi.org/10.1038/nmat2878	journal	October 2010
Computational Design of Core/Shell Nanoparticles for Oxygen Reduction Reactions Zhang, Xu; Lu, Gang The Journal of Physical Chemistry Letters, Vol. 5, Issue 2 https://doi.org/10.1021/jz4024699	journal	December 2013
The role of transition metals in the catalytic activity of Pt alloys: quantification of strain and ligand effects Shao, Minhua; Odell, Jonathan H.; Peles, Amra Chemical Communications, Vol. 50, Issue 17 https://doi.org/10.1039/c3cc47341d	journal	January 2014

Cited By (32)

The controlled construction of a ternary hybrid of monodisperse Ni ₃ S ₄ nanorods/graphitic C ₃ N ₄ nanosheets/nitrogen-doped graphene in van der Waals heterojunctions as a highly efficient electrocatalyst for overall water splitting and a promising anode material for sodium-ion batteries Yang, Jing; Xing, Shiqi; Zhou, Jianbin Journal of Materials Chemistry A, Vol. 7, Issue 8 https://doi.org/10.1039/c8ta07253a	journal	January 2019
Core–Shell-Structured Low-Platinum Electrocatalysts for Fuel Cell Applications Wang, Rongfang; Wang, Hui; Luo, Fan Electrochemical Energy Reviews, Vol. 1, Issue 3 https://doi.org/10.1007/s41918-018-0013-0	journal	July 2018
A bimetallic oxide Fe _1.89 Mo _4.11 O ₇ electrocatalyst with highly efficient hydrogen evolution reaction activity in alkaline and acidic media Hao, Zhaomin; Yang, Shishuai; Niu, Jingyang Chemical Science, Vol. 9, Issue 25 https://doi.org/10.1039/c8sc01710g	journal	January 2018
Highly Durable and Active Pt-Based Nanoscale Design for Fuel-Cell Oxygen-Reduction Electrocatalysts Chung, Dong Young; Yoo, Ji Mun; Sung, Yung-Eun Advanced Materials, Vol. 30, Issue 42 https://doi.org/10.1002/adma.201704123	journal	January 2018
Nano PdAu Bimetallic Alloy as an Effective Catalyst for the Buchwald-Hartwig Reaction Chen, Zheng; Wang, Shuo; Lian, Chao Chemistry - An Asian Journal, Vol. 11, Issue 3 https://doi.org/10.1002/asia.201500531	journal	July 2015
Ru@RuO ₂ Core‐Shell Nanorods: A Highly Active and Stable Bifunctional Catalyst for Oxygen Evolution and Hydrogen Evolution Reactions Jiang, Rongzhong; Tran, Dat T.; Li, Jiangtian ENERGY & ENVIRONMENTAL MATERIALS, Vol. 2, Issue 3 https://doi.org/10.1002/eem2.12031	journal	April 2019
MoS ₂ /NiS Yolk–Shell Microsphere‐Based Electrodes for Overall Water Splitting and Asymmetric Supercapacitor Qin, Qing; Chen, Lulu; Wei, Tao Small, Vol. 15, Issue 29 https://doi.org/10.1002/smll.201803639	journal	November 2018
Monodisperse nanoparticles for catalysis and nanomedicine Muzzio, Michelle; Li, Junrui; Yin, Zhouyang Nanoscale, Vol. 11, Issue 41 https://doi.org/10.1039/c9nr06080d	journal	January 2019
Ni nanoparticles supported on graphitic carbon nitride as visible light catalysts for hydrolytic dehydrogenation of ammonia borane Gao, Manyi; Yu, Yongsheng; Yang, Weiwei Nanoscale, Vol. 11, Issue 8 https://doi.org/10.1039/c8nr09005j	journal	January 2019
Facile fabrication of bimetallic Cu–Ag binary hybrid nanoparticles and their application in catalysis Meng, Yuxi; Gao, Hanyu; Li, Shuang New Journal of Chemistry, Vol. 43, Issue 17 https://doi.org/10.1039/c9nj00816k	journal	January 2019
Synergistically Enhanced Oxygen Reduction Electrocatalysis by Subsurface Atoms in Ternary PdCuNi Alloy Catalysts Wang, Huawei; Luo, Wenjia; Zhu, Lujun Advanced Functional Materials, Vol. 28, Issue 15 https://doi.org/10.1002/adfm.201707219	journal	February 2018
When Cubic Cobalt Sulfide Meets Layered Molybdenum Disulfide: A Core-Shell System Toward Synergetic Electrocatalytic Water Splitting Zhu, Han; Zhang, Junfeng; Yanzhang, Ruoping Advanced Materials, Vol. 27, Issue 32 https://doi.org/10.1002/adma.201501969	journal	July 2015
Tailoring the shape and size of wet-chemical synthesized FePt nanoparticles by controlling nucleation and growth with a high magnetic field Wu, Chun; Wang, Xiaoyang; Pei, Wenli Nanoscale, Vol. 11, Issue 32 https://doi.org/10.1039/c9nr04565a	journal	January 2019
Synthesis, Characterization, and Potential Applications of Transition Metal Nanoparticles Cid, A.; Simal-Gandara, J. Journal of Inorganic and Organometallic Polymers and Materials, Vol. 30, Issue 4 https://doi.org/10.1007/s10904-019-01331-9	journal	September 2019
Ordered mesoporous FeN x -doped carbon: a class of highly active and stable catalysts in acids, bases and polymer electrolyte membrane fuel cells Jiang, Rongzhong; Tran, Dat T.; McClure, Joshua P. Journal of Materials Chemistry A, Vol. 6, Issue 9 https://doi.org/10.1039/c7ta10555j	journal	January 2018
Porous AgPd-Pd Composite Nanotubes as Highly Efficient Electrocatalysts for Lithium-Oxygen Batteries Luo, Wen-Bin; Gao, Xuan-Wen; Chou, Shu-Lei Advanced Materials, Vol. 27, Issue 43 https://doi.org/10.1002/adma.201502262	journal	September 2015
Superhydrophilic and Superaerophobic Copper Phosphide Microsheets for Efficient Electrocatalytic Hydrogen and Oxygen Evolution Hao, Jinhui; Yang, Wenshu; Huang, Zhipeng Advanced Materials Interfaces, Vol. 3, Issue 16 https://doi.org/10.1002/admi.201600236	journal	June 2016
Ultrafine jagged platinum nanowires enable ultrahigh mass activity for the oxygen reduction reaction Li, Mufan; Zhao, Zipeng; Cheng, Tao Science, Vol. 354, Issue 6318 https://doi.org/10.1126/science.aaf9050	journal	November 2016
Bimetallic synergy in cobalt–palladium nanocatalysts for CO oxidation Wu, Cheng Hao; Liu, Chang; Su, Dong Nature Catalysis, Vol. 2, Issue 1 https://doi.org/10.1038/s41929-018-0190-6	journal	December 2018
Tungsten-Doping-Induced Surface Reconstruction of Porous Ternary Pt-Based Alloy Electrocatalyst for Oxygen Reduction Tu, Wenzhe; Chen, Kai; Zhu, Lujun Advanced Functional Materials, Vol. 29, Issue 7 https://doi.org/10.1002/adfm.201807070	journal	January 2019
Atomic Platinum Anchored on Fe-N-C Material for High Performance Oxygen Reduction Reaction: Atomic Platinum Anchored on Fe-N-C Material for High Performance Oxygen Reduction Reaction Sha, Ying; Ji, Jiapeng; Li, Siyuan European Journal of Inorganic Chemistry, Vol. 2020, Issue 2 https://doi.org/10.1002/ejic.201901027	journal	January 2020
Noble metal alloy complex nanostructures: controllable synthesis and their electrochemical property Liu, Hui-ling; Nosheen, Farhat; Wang, Xun Chemical Society Reviews, Vol. 44, Issue 10 https://doi.org/10.1039/c4cs00478g	journal	January 2015
Integrated Quasiplane Heteronanostructures of MoSe ₂ /Bi ₂ Se ₃ Hexagonal Nanosheets: Synergetic Electrocatalytic Water Splitting and Enhanced Supercapacitor Performance Yang, Jing; Wang, Chunde; Ju, Huanxin Advanced Functional Materials, Vol. 27, Issue 48 https://doi.org/10.1002/adfm.201703864	journal	November 2017
High-index faceted CuFeS ₂ nanosheets with enhanced behavior for boosting hydrogen evolution reaction Li, Yuxuan; Wang, Yu; Pattengale, Brian Nanoscale, Vol. 9, Issue 26 https://doi.org/10.1039/c7nr03182c	journal	January 2017
Core–shell nanoparticles: synthesis and applications in catalysis and electrocatalysis Gawande, Manoj B.; Goswami, Anandarup; Asefa, Tewodros Chemical Society Reviews, Vol. 44, Issue 21 https://doi.org/10.1039/c5cs00343a	journal	January 2015
Facet and dimensionality control of Pt nanostructures for efficient oxygen reduction and methanol oxidation electrocatalysts Bu, Lingzheng; Feng, Yonggang; Yao, Jianlin Nano Research, Vol. 9, Issue 9 https://doi.org/10.1007/s12274-016-1170-2	journal	July 2016
Self-assembly of noble metal monolayers on transition metal carbide nanoparticle catalysts Hunt, S. T.; Milina, M.; Alba-Rubio, A. C. Science, Vol. 352, Issue 6288 https://doi.org/10.1126/science.aad8471	journal	May 2016
Controlled synthesis of Au–Fe heterodimer nanoparticles and their conversion into Au–Fe ₃ O ₄ heterostructured nanoparticles Jiang, Guangming; Huang, Yuxi; Zhang, Sen Nanoscale, Vol. 8, Issue 41 https://doi.org/10.1039/c6nr06395k	journal	January 2016
Surface Segregation of Fe in Pt-Fe Alloy Nanoparticles: Its Precedence and Effect on the Ordered-Phase Evolution during Thermal Annealing Prabhudev, Sagar; Bugnet, Matthieu; Zhu, Guo-Zhen ChemCatChem, Vol. 7, Issue 22 https://doi.org/10.1002/cctc.201501165	journal	November 2015
Taming interfacial electronic properties of platinum nanoparticles on vacancy-abundant boron nitride nanosheets for enhanced catalysis Zhu, Wenshuai; Wu, Zili; Foo, Guo Shiou Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15291	journal	June 2017
Recent developments of nano-structured materials as the catalysts for oxygen reduction reaction Kang, SungYeon; Kim, HuiJung; Chung, Yong-Ho Nano Convergence, Vol. 5, Issue 1 https://doi.org/10.1186/s40580-018-0144-3	journal	April 2018
Nanostructure Optimization of Platinum-Based Nanomaterials for Catalytic Applications Duan, Sibin; Du, Zhe; Fan, Hongsheng Nanomaterials, Vol. 8, Issue 11 https://doi.org/10.3390/nano8110949	journal	November 2018

Similar Records

Core/Shell Pd/FePt Nanoparticles as an Active and Durable Catalyst for the Oxygen Reduction Reaction

Journal Article · Fri Jan 01 00:00:00 EST 2010 · Journal of the American Chemical Society · OSTI ID:1182492

Mazumder, Vismadeb; Chi, Miaofang; More, Karren Leslie; +1 more

Building Durable Multimetallic Electrocatalysts from Intermetallic Seeds

Journal Article · Wed Dec 30 00:00:00 EST 2020 · Accounts of Chemical Research · OSTI ID:1182492

Bueno, Sandra A.; Ashberry, Hannah M.; Shafei, Ibrahim; +1 more

Engineering Ru@Pt Core-Shell Catalysts for Enhanced Electrochemical Oxygen Reduction Mass Activity and Stability

Journal Article · Fri Jan 12 00:00:00 EST 2018 · Nanomaterials · OSTI ID:1182492

Jackson, Ariel; Strickler, Alaina; Higgins, Drew; +1 more

Related Subjects

29 ENERGY PLANNING, POLICY, AND ECONOMY
functional nanomaterials

Title: Monodisperse core/shell Ni/FePt nanoparticles and their con-version to Ni/Pt to catalyze oxygen reduction

Citation Formats

References (47)

Cited By (32)

Similar Records

Related Subjects