Thermal Release of 3He from Tritium Aged LaNi4.25Al0.75 Hydride
- Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)
Recently, the demand for He-3 has increased dramatically due to widespread use in nuclear nonproliferation, cryogenic, and medical applications. Essentially all of the world’s supply of He-3 is created by the radiolytic decay of tritium. The Savannah River Site Tritium Facilities (SRS-TF) utilizes LANA.75 in the tritium process to store hydrogen isotopes. The vast majority of He-3 “born” from tritium stored in LANA.75 is trapped in the hydride metal matrix. The SRS-TF has multiple LANA.75 tritium storage beds that have been retired from service with significant quantities of He-3 trapped in the metal. To support He-3 recovery, the Savannah River National Laboratory (SRNL) conducted thermogravimetric analysis coupled with mass spectrometry (TGA-MS) on a tritium aged LANA.75 sample. TGA-MS testing was performed in an argon environment. Prior to testing, the sample was isotopically exchanged with deuterium to reduce residual tritium and passivated with air to alleviate pyrophoric concerns associated with handling the material outside of an inert glovebox. Analyses indicated that gas release from this sample was bimodal, with peaks near 220 and 490°C. The first peak consisted of both He-3 and residual hydrogen isotopes, the second was primarily He-3. The bulk of the gas was released by 600 °C
- Research Organization:
- Savannah River Site (SRS), Aiken, SC (United States)
- Sponsoring Organization:
- USDOE Office of Environmental Management (EM)
- Grant/Contract Number:
- AC09-08SR22470
- OSTI ID:
- 1177877
- Report Number(s):
- SRNL-STI-2014-00110; TRN: US1500499
- Journal Information:
- Fusion Science and Technology, Vol. 67, Issue 3; ISSN 1536-1055
- Publisher:
- American Nuclear SocietyCopyright Statement
- Country of Publication:
- United States
- Language:
- English
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