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Title: Supported liquid inorganic membranes for nuclear waste separation

Patent ·
OSTI ID:1177550

A system and method for the extraction of americium from radioactive waste solutions. The method includes the transfer of highly oxidized americium from an acidic aqueous feed solution through an immobilized liquid membrane to an organic receiving solvent, for example tributyl phosphate. The immobilized liquid membrane includes porous support and separating layers loaded with tributyl phosphate. The extracted solution is subsequently stripped of americium and recycled at the immobilized liquid membrane as neat tributyl phosphate for the continuous extraction of americium. The sequestered americium can be used as a nuclear fuel, a nuclear fuel component or a radiation source, and the remaining constituent elements in the aqueous feed solution can be stored in glassified waste forms substantially free of americium.

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-00OR22725
Assignee:
UT-Battelle, LLC (Oak Ridge, TN)
Patent Number(s):
8,999,168
Application Number:
13/284,174
OSTI ID:
1177550
Resource Relation:
Patent File Date: 2011 Oct 28
Country of Publication:
United States
Language:
English

References (8)

Ceramic filter and process for making it patent March 1992
Extracting metal ions with diphosphonic acid, or derivative thereof patent July 1994
Supported liquid membrane and separation process employing same patent April 1996
Membrane extraction with thermodynamically unstable diphosphonic acid derivatives patent October 1997
Supported liquid membrane separation patent August 2000
Device for turning on light and illumination apparatus patent May 2003
Method and system for recovering metal from metal-containing materials patent March 2010
Agricultural vehicle emission aftertreatment device utilizing heat exchanger ventilation patent May 2012