Multifunctional mesoporous silica catalyst

Lin, Victor Shang-Yi; Tsai, Chih-Hsiang; Chen, Hung-Ting; Pruski, Marek; Kobayashi, Takeshi

Title: Multifunctional mesoporous silica catalyst

Patent · Tue Mar 31 00:00:00 EDT 2015

OSTI ID:1177030

Lin, Victor Shang-Yi; Tsai, Chih-Hsiang; Chen, Hung-Ting; Pruski, Marek; Kobayashi, Takeshi

The present invention provides bifunctional silica mesoporous materials, including mesoporous silica nanoparticles ("MSN"), having pores modified with diarylammonium triflate and perfluoroaryl moieties, that are useful for the acid-catalyzed esterification of organic acids with organic alcohols.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-07CH11358

Assignee:: Iowa State University Research Foundation, Inc. (Ames, IA)

Patent Number(s):: 8,993,793

Application Number:: 13/361,613

OSTI ID:: 1177030

Resource Relation:: Patent File Date: 2012 Jan 30

Country of Publication:: United States

Language:: English

References (13)

Use of functionalized mesoporous silicates to esterify fatty acids and transesterify oils Lin, Victor Shang-Yi; Radu, Daniela Rodica https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7122688 US Patent Document 7,122,688	patent	October 2006
??-functionalized mesoporous MCM-41 silica shows high activity and selectivity for carboxylic acid esterification and Friedel?Crafts acylation reactions Alvaro, M.; Corma, A.; Das, D. Journal of Catalysis, Vol. 231, Issue 1 https://doi.org/10.1016/j.jcat.2005.01.007	journal	April 2005
Organosulfonic acid-functionalized mesoporous silicas for the esterification of fatty acid Mbaraka, I. Journal of Catalysis, Vol. 219, Issue 2 https://doi.org/10.1016/S0021-9517(03)00193-3	journal	October 2003
Design of multifunctionalized mesoporous silicas for esterification of fatty acid Mbaraka, I.; Shanks, B. Journal of Catalysis, Vol. 229, Issue 2 https://doi.org/10.1016/j.jcat.2004.11.008	journal	January 2005
Acidic Mesoporous Silica for the Catalytic Conversion of Fatty Acids in Beef Tallow Mbaraka, Isa K.; McGuire, Kyle J.; Shanks, Brent H. Industrial & Engineering Chemistry Research, Vol. 45, Issue 9 https://doi.org/10.1021/ie0601089	journal	April 2006
Synthesis and Characterization of the Amphoteric Amino Acid Bifunctional Mesoporous Silica Han, Lu; Ruan, Juanfang; Li, Yongsheng Chemistry of Materials, Vol. 19, Issue 11 https://doi.org/10.1021/cm0705845	journal	May 2007
Pentafluorophenylammonium triflate (PFPAT): an efficient, practical, and cost-effective catalyst for esterification, thioesterification, transesterification, and macrolactone formation Funatomi, Takashi; Wakasugi, Kazunori; Misaki, Tomonori Green Chemistry, Vol. 8, Issue 12 https://doi.org/10.1039/b609181b	journal	January 2006
Diphenylammonium triflate (DPAT): efficient catalyst for esterification of carboxylic acids and for transesterification of carboxylic esters with nearly equimolar amounts of alcohols Wakasugi, Kazunori; Misaki, Tomonori; Yamada, Kayo Tetrahedron Letters, Vol. 41, Issue 27, p. 5249-5252 https://doi.org/10.1016/S0040-4039(00)00821-2	journal	July 2000
Mesoporous organosilicas containing disulfide moiety: Synthesis and generation of sulfonic acid functionality through chemical transformation in the pore wall Li, Congming; Liu, Jian; Zhang, Lei Microporous and Mesoporous Materials, Vol. 113, Issue 1-3, p. 333-342 https://doi.org/10.1016/j.micromeso.2007.11.031	journal	August 2008
Synthesis of a Novel Heterogeneous Strong Acid Catalyst from p-Toluenesulfonic Acid (PTSA) and its Catalytic Activities Liang, Xuezheng; Gao, Shan; Gong, Guozhen Catalysis Letters, Vol. 124, Issue 3-4 https://doi.org/10.1007/s10562-008-9474-9	journal	May 2008
Conformations of Silica-Bound (Pentafluorophenyl)propyl Groups Determined by Solid-State NMR Spectroscopy and Theoretical Calculations Mao, Kanmi; Kobayashi, Takeshi; Wiench, Jerzy W. Journal of the American Chemical Society, Vol. 132, Issue 35 https://doi.org/10.1021/ja105007b	journal	September 2010
Efficient Two-Step Synthesis of Biodiesel from Greases ^† Ngo, Helen L.; Zafiropoulos, Nicholas A.; Foglia, Thomas A. Energy & Fuels, Vol. 22, Issue 1 https://doi.org/10.1021/ef700343b	journal	January 2008
Rational Catalyst Design: A Multifunctional Mesoporous Silica Catalyst for Shifting the Reaction Equilibrium by Removal of Byproduct Tsai, Chih-Hsiang; Chen, Hung-Ting; Althaus, Stacey M. ACS Catalysis, Vol. 1, Issue 7 https://doi.org/10.1021/cs200222t	journal	May 2011

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