Electro-chemical sensors, sensor arrays and circuits

Katz, Howard E.; Kong, Hoyoul

Title: Electro-chemical sensors, sensor arrays and circuits

Patent · Tue Jul 08 00:00:00 EDT 2014

OSTI ID:1136991

Katz, Howard E.; Kong, Hoyoul

An electro-chemical sensor includes a first electrode, a second electrode spaced apart from the first electrode, and a semiconductor channel in electrical contact with the first and second electrodes. The semiconductor channel includes a trapping material. The trapping material reduces an ability of the semiconductor channel to conduct a current of charge carriers by trapping at least some of the charge carriers to localized regions within the semiconductor channel. The semiconductor channel includes at least a portion configured to be exposed to an analyte to be detected, and the trapping material, when exposed to the analyte, interacts with the analyte so as to at least partially restore the ability of the semiconductor channel to conduct the current of charge carriers.

View Patent

Cite

Export

Save

Research Organization:: Johns Hopkins Univ., Baltimore, MD (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: FG02-07ER46465

Assignee:: The Johns Hopkins University (Baltimore, MD)

Patent Number(s):: 8,772,764

Application Number:: 13/725,630

OSTI ID:: 1136991

Country of Publication:: United States

Language:: English

References (77)

Bioluminescent bioreporter integrated circuit detection methods Simpson, Michael L.; Paulus, Michael J.; Sayler, Gary S. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6905834 US Patent Document 6,905,834	patent	June 2005
Polymer Semiconductors with High Mobility Pan, Hualong; Wu, Yiliang; Liu, Ping https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090181509 US Patent Application 12/013700; 20090181509	patent-application	July 2009
Ammonia Nanosensors, and Environmental Control System Briman, Mikhail; Bryant, Craig; Chang, Ying-Lan https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20130075690 US Patent Application 13/442720; 20130075690	patent-application	March 2013
Materials and Applications for Large Area Electronics: Solution-Based Approaches Arias, Ana Claudia; MacKenzie, J. Devin; McCulloch, Iain Chemical Reviews, Vol. 110, Issue 1 https://doi.org/10.1021/cr900150b	journal	January 2010
Localized Charge Transfer in a Molecularly Doped Conducting Polymer Aziz, E. F.; Vollmer, A.; Eisebitt, S. Advanced Materials, Vol. 19, Issue 20, p. 3257-3260 https://doi.org/10.1002/adma.200700926	journal	September 2007
Modification of electrodes with porphyrin-functionalised conductive polymers Ballarin, B.; Masiero, S.; Seeber, R. Journal of Electroanalytical Chemistry, Vol. 449, Issue 1-2, p. 173-180 https://doi.org/10.1016/S0022-0728(98)00048-5	journal	June 1998
Synthesis and Self-Assembly of Copolymers with Pendant Electroactive Units Barik, Satyananda; Valiyaveettil, Suresh Macromolecules, Vol. 41, Issue 17 https://doi.org/10.1021/ma8008349	journal	September 2008
Molecular Design and Ordering Effects in π-Functional Materials for Transistor and Solar Cell Applications Beaujuge, Pierre M.; Fréchet, Jean M. J. Journal of the American Chemical Society, Vol. 133, Issue 50, p. 20009-20029 https://doi.org/10.1021/ja2073643	journal	December 2011
Rapid and Efficient Post-Polymerization Functionalization of Poly(3,4-ethylenedioxythiophene) (PEDOT) Derivatives on an Electrode Surface Besbes, M.; Trippé, G.; Leviallain, E. Advanced Materials, Vol. 13, Issue 16 https://doi.org/10.1002/1521-4095(200108)13:16<1249::AID-ADMA1249>3.0.CO;2-W	journal	August 2001
Optical, Electrochemical, Magnetic, and Conductive Properties of New Polyindolocarbazoles and Polydiindolocarbazoles Blouin, Nicolas; Michaud, Alexandre; Wakim, Salem Macromolecular Chemistry and Physics, Vol. 207, Issue 2 https://doi.org/10.1002/macp.200500423	journal	January 2006
Organic metals Bryce, Martin R.; Murphy, Lynne C. Nature, Vol. 309, Issue 5964 https://doi.org/10.1038/309119a0	journal	May 1984
Towards highly oriented polythiophenes incorporating mesogenic or tetrathiafulvalene substituents Bryce, Martin R.; Chissel, André D.; Gopal, Jaya Synthetic Metals, Vol. 39, Issue 3, p. 397-400 https://doi.org/10.1016/0379-6779(91)91766-4	journal	January 1991
Comparison of surface and bulk doping levels in chemical polypyrroles of low, medium and high conductivity Carrasco, Pedro M.; Cortazar, Milagros; Ochoteco, Estibalitz Surface and Interface Analysis, Vol. 39, Issue 1 https://doi.org/10.1002/sia.2457	journal	January 2006
Printable polythiophene gas sensor array for low-cost electronic noses Chang, Josephine B.; Liu, Vincent; Subramanian, Vivek Journal of Applied Physics, Vol. 100, Issue 1 https://doi.org/10.1063/1.2208743	journal	July 2006
Synthesis of Conjugated Polymers for Organic Solar Cell Applications Cheng, Yen-Ju; Yang, Sheng-Hsiung; Hsu, Chain-Shu Chemical Reviews, Vol. 109, Issue 11 https://doi.org/10.1021/cr900182s	journal	November 2009
Electronic sensing of vapors with organic transistors Crone, B.; Dodabalapur, A.; Gelperin, A. Applied Physics Letters, Vol. 78, Issue 15 https://doi.org/10.1063/1.1360785	journal	April 2001
Organic Thin Film Transistors for Large Area Electronics Dimitrakopoulos, C.D.; Malenfant, P. R. L. Advanced Materials, Vol. 14, Issue 2, p. 99-117 https://doi.org/10.1002/1521-4095(20020116)14:2<99::AID-ADMA99>3.0.CO;2-9	journal	January 2002
Research progress on polymer–inorganic thermoelectric nanocomposite materials Du, Yong; Shen, Shirley Z.; Cai, Kefeng Progress in Polymer Science, Vol. 37, Issue 6, p. 820-841 https://doi.org/10.1016/j.progpolymsci.2011.11.003	journal	June 2012
Conducting polymers: Efficient thermoelectric materials Dubey, Nidhi; Leclerc, Mario Journal of Polymer Science Part B: Polymer Physics, Vol. 49, Issue 7 https://doi.org/10.1002/polb.22206	journal	February 2011
Semiconductors for organic transistors Facchetti, Antonio Materials Today, Vol. 10, Issue 3 https://doi.org/10.1016/S1369-7021(07)70017-2	journal	March 2007
π-Conjugated Polymers for Organic Electronics and Photovoltaic Cell Applications ^† Facchetti, Antonio Chemistry of Materials, Vol. 23, Issue 3 https://doi.org/10.1021/cm102419z	journal	February 2011
The path to ubiquitous and low-cost organic electronic appliances on plastic Forrest, Stephen R. Nature, Vol. 428, Issue 6986, p. 911-918 https://doi.org/10.1038/nature02498	journal	April 2004
Improved Syntheses of Carboxytetrathiafulvalene, Formyltetrathiafulvalene and (Hydroxymethyl)tetrathiafulvalene ¹ : Versatile Building Blocks for New Functionalised Tetrathiafulvalene Derivatives Garín, Javier; Orduna, Jesús; Uriel, Santiago Synthesis, Vol. 1994, Issue 05 https://doi.org/10.1055/s-1994-25510	journal	January 1994
Electrosynthesis of a tetrathiafulvalene-derivatized polythiophene Thobie-Gautier, Christine; Gorgues, Alain; Jubault, Michel Macromolecules, Vol. 26, Issue 16 https://doi.org/10.1021/ma00068a004	journal	August 1993
Conjugated Polymer-Based Organic Solar Cells Günes, Serap; Neugebauer, Helmut; Sariciftci, Niyazi Serdar Chemical Reviews, Vol. 107, Issue 4, p. 1324-1338 https://doi.org/10.1021/cr050149z	journal	April 2007
Poly(3,6-dihexyl-thieno[3,2-b]thiophene vinylene): Synthesis, Field-Effect Transistors, and Photovoltaic Properties He, Youjun; Wu, Weiping; Zhao, Guangjing Macromolecules, Vol. 41, Issue 24 https://doi.org/10.1021/ma801923c	journal	December 2008
High thermoelectric performance of poly(2,5-dimethoxyphenylenevinylene) and its derivatives Hiroshige, Yuji; Ookawa, Makoto; Toshima, Naoki Synthetic Metals, Vol. 156, Issue 21-24 https://doi.org/10.1016/j.synthmet.2006.10.004	journal	December 2006
Thermoelectric figure-of-merit of iodine-doped copolymer of phenylenevinylene with dialkoxyphenylenevinylene Hiroshige, Yuji; Ookawa, Makoto; Toshima, Naoki Synthetic Metals, Vol. 157, Issue 10-12, p. 467-474 https://doi.org/10.1016/j.synthmet.2007.05.003	journal	June 2007
Monolayer‐Dimensional 5,5′‐Bis(4‐hexylphenyl)‐2,2′‐bithiophene Transistors and Chemically Responsive Heterostructures Huang, Jia; Sun, Jia; Katz, Howard E. Advanced Materials, Vol. 20, Issue 13, p. 2567-2572 https://doi.org/10.1002/adma.200703212	journal	July 2008
Molecular Junctions Composed of Oligothiophene Dithiol-Bridged Gold Nanoparticles Exhibiting Photoresponsive Properties Huang, Wei; Masuda, Gou; Maeda, Seisuke Chemistry - A European Journal, Vol. 12, Issue 2, p. 607-619 https://doi.org/10.1002/chem.200500822	journal	January 2006
Hydroxy-Terminated Organic Semiconductor-Based Field-Effect Transistors for Phosphonate Vapor Detection Huang, Jia; Miragliotta, Joseph; Becknell, Alan Journal of the American Chemical Society, Vol. 129, Issue 30 https://doi.org/10.1021/ja068964z	journal	August 2007
Response diversity and dual response mechanism of organic field-effect transistors with dinitrotoluene vapor Huang, J.; Dawidczyk, T. J.; Jung, B. J. J. Mater. Chem., Vol. 20, Issue 13 https://doi.org/10.1039/B916037J	journal	January 2010
Spectroelectrochemistry of Electrogenerated Tetrathiafulvalene-Derivatized Poly(thiophenes): Toward a Rational Design of Organic Conductors with Mixed Conduction Huchet, Laurent; Akoudad, Said; Levillain, Eric The Journal of Physical Chemistry B, Vol. 102, Issue 40 https://doi.org/10.1021/jp982593u	journal	October 1998
Electrosynthesis of Highly Electroactive Tetrathiafulvalene-Derivatized Polythiophenes Huchet, Laurent; Akoudad, Said; Roncali, Jean Advanced Materials, Vol. 10, Issue 7, p. 541-545 https://doi.org/10.1002/(SICI)1521-4095(199805)10:7<541::AID-ADMA541>3.0.CO;2-1	journal	May 1998
Thermoelectric power and conductivity of different types of polypyrrole Kemp, N. T.; Kaiser, A. B.; Liu, C.-J. Journal of Polymer Science Part B: Polymer Physics, Vol. 37, Issue 9, p. 953-960 https://doi.org/10.1002/(SICI)1099-0488(19990501)37:9<953::AID-POLB7>3.0.CO;2-L	journal	May 1999
Electrical “Turn-On” Response of Poly(3,3‴-didodecylquaterthiophene) and Electron Donor Blend Transistors to 2,4,6-Trinitrotoluene Kong, Hoyoul; Jung, Byung Jun; Sinha, Jasmine Chemistry of Materials, Vol. 24, Issue 14 https://doi.org/10.1021/cm3012292	journal	July 2012
Supramolecular Structures from Rod−Coil Block Copolymers Lee, Myongsoo; Cho, Byoung-Ki; Zin, Wang-Cheol Chemical Reviews, Vol. 101, Issue 12 https://doi.org/10.1021/cr0001131	journal	December 2001
Synthesis and Thermoelectric Properties of Polycarbazole, Polyindolocarbazole, and Polydiindolocarbazole Derivatives Lévesque, Isabelle; Bertrand, Pier-Olivier; Blouin, Nicolas Chemistry of Materials, Vol. 19, Issue 8 https://doi.org/10.1021/cm070063h	journal	April 2007
Humidity effect on electrical performance of organic thin-film transistors Li, Dawen; Borkent, Evert-Jan; Nortrup, Robert Applied Physics Letters, Vol. 86, Issue 4 https://doi.org/10.1063/1.1852708	journal	January 2005
Tuning Optical Properties and Enhancing Solid-State Emission of Poly(thiophene)s by Molecular Control: A Postfunctionalization Approach Li, Yuning; Vamvounis, George; Holdcroft, Steven Macromolecules, Vol. 35, Issue 18 https://doi.org/10.1021/ma020140o	journal	August 2002
Self-Assembly of α-Functionalized Terthiophenes on Gold Liedberg, B.; Yang, Z.; Engquist, I. The Journal of Physical Chemistry B, Vol. 101, Issue 31 https://doi.org/10.1021/jp970229+	journal	July 1997
Development of Dendrimers: Macromolecules for Use in Organic Light-Emitting Diodes and Solar Cells Lo, Shih-Chun; Burn, Paul L. Chemical Reviews, Vol. 107, Issue 4, p. 1097-1116 https://doi.org/10.1021/cr050136l	journal	April 2007
Polyfluorene-Based Light-Emitting Rod−Coil Block Copolymers Lu, Su; Liu, Tianxi; Ke, Lin Macromolecules, Vol. 38, Issue 20 https://doi.org/10.1021/ma050267o	journal	October 2005
Univocal Demonstration of the Electrochemically Mediated Binding of Pb ²⁺ by a Modified Surface Incorporating a TTF-Based Redox-Switchable Ligand Lyskawa, Joël; Le Derf, Franck; Levillain, Eric Journal of the American Chemical Society, Vol. 126, Issue 39 https://doi.org/10.1021/ja047411q	journal	October 2004
Electrical conductivity and thermoelectric power of polypyrrole with different doping levels Maddison, D. S.; Unsworth, J.; Roberts, R. B. Synthetic Metals, Vol. 26, Issue 1, p. 99-108 https://doi.org/10.1016/0379-6779(88)90339-6	journal	October 1988
Metallic transport properties in electrochemically as-grown and heavily doped polythiophene and poly(3-methylthiophene) Masubuchi, S.; Kazama, S.; Mizoguchi, K. Synthetic Metals, Vol. 57, Issue 2-3, p. 4962-4967 https://doi.org/10.1016/0379-6779(93)90846-O	journal	April 1993
Correlation of Seebeck coefficient and electric conductivity in polyaniline and polypyrrole Mateeva, N.; Niculescu, H.; Schlenoff, J. Journal of Applied Physics, Vol. 83, Issue 6 https://doi.org/10.1063/1.367119	journal	March 1998
Conjugated Polymer-Based Chemical Sensors McQuade, D. Tyler; Pullen, Anthony E.; Swager, Timothy M. Chemical Reviews, Vol. 100, Issue 7 https://doi.org/10.1021/cr9801014	journal	July 2000
Functional Oligothiophenes: Molecular Design for Multidimensional Nanoarchitectures and Their Applications ^† Mishra, Amaresh; Ma, Chang-Qi; Bäuerle, Peter Chemical Reviews, Vol. 109, Issue 3 https://doi.org/10.1021/cr8004229	journal	March 2009
Self-assembly of nanoscale cuboctahedra by coordination chemistry Olenyuk, Bogdan; Whiteford, Jeffery A.; Fechtenkötter, Andreas Nature, Vol. 398, Issue 6730, p. 796-799 https://doi.org/10.1038/19740	journal	April 1999
All jet-printed polymer thin-film transistor active-matrix backplanes Arias, A. C.; Ready, S. E.; Lujan, R. Applied Physics Letters, Vol. 85, Issue 15 https://doi.org/10.1063/1.1801673	journal	October 2004
Molecular and Supramolecular Architectures of Organic Semiconductors for Field-Effect Transistor Devices and Sensors: A Synthetic Chemical Perspective Operamolla, Alessandra; Farinola, Gianluca M. European Journal of Organic Chemistry, Vol. 2011, Issue 3 https://doi.org/10.1002/ejoc.201001103	journal	December 2010
Advances in Molecular Design and Synthesis of Regioregular Polythiophenes Osaka, Itaru; McCullough, Richard D. Accounts of Chemical Research, Vol. 41, Issue 9 https://doi.org/10.1021/ar800130s	journal	September 2008
Metallic properties of transition metal halides doped polyacetylene: The soliton liquid state Park, Y. W.; Yoon, C. O.; Na, B. C. Synthetic Metals, Vol. 41, Issue 1-2, p. 27-32 https://doi.org/10.1016/0379-6779(91)90989-I	journal	April 1991
Structure and morphology: relation to thermopower properties of conductive polymers Park, Y. W. Synthetic Metals, Vol. 45, Issue 2, p. 173-182 https://doi.org/10.1016/0379-6779(91)91801-G	journal	November 1991
Anisotropy of thermoelectric power of stretch-oriented new polyacetylene Pukacki, Wojciech; Płocharski, Janusz; Roth, Siegmar Synthetic Metals, Vol. 62, Issue 3, p. 253-256 https://doi.org/10.1016/0379-6779(94)90213-5	journal	February 1994
Characterization of the conductivity of organic thiols by field emission microscopy and field emission spectroscopy Purcell, S. T.; Garcia, N.; Binh, Vu Thien Journal of the American Chemical Society, Vol. 116, Issue 26, p. 11985-11989 https://doi.org/10.1021/ja00105a045	journal	December 1994
Tuning of the aqueous electroactivity of substituted poly(thiophene)s by ether groups Roncali, Jean; Shi, Li Hong; Garreau, Robert Synthetic Metals, Vol. 36, Issue 2, p. 267-273 https://doi.org/10.1016/0379-6779(90)90060-X	journal	June 1990
Analyte selective response in solution-deposited tetrabenzoporphyrin thin-film field-effect transistor sensors Royer, James E.; Lee, Sangyeob; Chen, Charlene Sensors and Actuators B: Chemical, Vol. 158, Issue 1, p. 333-339 https://doi.org/10.1016/j.snb.2011.06.030	journal	November 2011
Synthesis and characterization of oligo- and crown ether-substituted polythiophenes-a comparative study Scheib, Stefan; Bäuerle, Peter Journal of Materials Chemistry, Vol. 9, Issue 9 https://doi.org/10.1039/A902823D	journal	January 1999
Enhanced Response of n-Channel Naphthalenetetracarboxylic Diimide Transistors to Dimethyl Methylphosphonate Using Phenolic Receptors See, K. C.; Becknell, A.; Miragliotta, J. Advanced Materials, Vol. 19, Issue 20, p. 3322-3327 https://doi.org/10.1002/adma.200602924	journal	September 2007
Simultaneous Increase in Seebeck Coefficient and Conductivity in a Doped Poly(alkylthiophene) Blend with Defined Density of States Sun, J.; Yeh, M. -L.; Jung, B. J. Macromolecules, Vol. 43, Issue 6 https://doi.org/10.1021/ma902467k	journal	March 2010
Molecular recognition and chemoresistive materials Swager, Timothy M.; Marsella, Michael J. Advanced Materials, Vol. 6, Issue 7-8, p. 595-597 https://doi.org/10.1002/adma.19940060717	journal	July 1994
Electron transport in networks of gold nanoparticles connected by oligothiophene molecular wires Taniguchi, Shin-ichi; Minamoto, Masaru; Matsushita, Michio M. Journal of Materials Chemistry, Vol. 16, Issue 34 https://doi.org/10.1039/B604732G	journal	January 2006
Polymer–Fullerene Composite Solar Cells Thompson, Barry C.; Fréchet, Jean M. J. Angewandte Chemie International Edition, Vol. 47, Issue 1, p. 58-77 https://doi.org/10.1002/anie.200702506	journal	January 2008
Side-Chain Role in Chemically Sensing Conducting Polymer Field-Effect Transistors Torsi, L.; Tanese, M. C.; Cioffi, N. The Journal of Physical Chemistry B, Vol. 107, Issue 31 https://doi.org/10.1021/jp0344951	journal	August 2003
Contact effects in organic thin-film transistor sensors Torsi, Luisa; Marinelli, Francesco; Angione, M. Daniela Organic Electronics, Vol. 10, Issue 2, p. 233-239 https://doi.org/10.1016/j.orgel.2008.11.009	journal	April 2009
Conductive polymers as a new type of thermoelectric material Toshima, Naoki Macromolecular Symposia, Vol. 186, Issue 1 https://doi.org/10.1002/1521-3900(200208)186:1<81::AID-MASY81>3.0.CO;2-S	journal	August 2002
Digital-Inverter Amine Sensing via Synergistic Responses by n and p Organic Semiconductors Tremblay, Noah J.; Jung, Byung Jun; Breysse, Patrick Advanced Functional Materials, Vol. 21, Issue 22 https://doi.org/10.1002/adfm.201101324	journal	September 2011
Charge Transport, Photovoltaic, and Thermoelectric Properties of Poly(2,7‐Carbazole) and Poly(Indolo[3,2‐b]Carbazole) Derivatives Wakim, Salem; Aïch, Badrou‐Réda; Tao, Ye Polymer Reviews, Vol. 48, Issue 3, p. 432-462 https://doi.org/10.1080/15583720802231726	journal	August 2008
Recent Progress in n-Channel Organic Thin-Film Transistors Wen, Yugeng; Liu, Yunqi Advanced Materials, Vol. 22, Issue 12, p. 1331-1345 https://doi.org/10.1002/adma.200901454	journal	January 2010
Thermoelectric properties of conducting polymers: The case of poly(3-hexylthiophene) Xuan, Y.; Liu, X.; Desbief, S. Physical Review B, Vol. 82, Issue 11 https://doi.org/10.1103/PhysRevB.82.115454	journal	September 2010
Electronic and Thermoelectric Properties of Polyaniline Organic Semiconductor and Electrical Characterization of Al/PANI MIS Diode Yakuphanoglu, F.; Şenkal, B. F. The Journal of Physical Chemistry C, Vol. 111, Issue 4 https://doi.org/10.1021/jp0653050	journal	February 2007
Highly polarized electron donors, acceptors and donor–acceptor compounds for organic conductors Yamashita, Yoshiro; Tomura, Masaaki Journal of Materials Chemistry, Vol. 8, Issue 9 https://doi.org/10.1039/A803151G	journal	January 1998
Three-Dimensional Electronic Delocalization in Chiral Conjugated Polymers Zahn, Steffen; Swager, Timothy M. Angewandte Chemie, Vol. 114, Issue 22, p. 4399-4404 https://doi.org/10.1002/1521-3757(20021115)114:22<4399::AID-ANGE4399>3.0.CO;2-C	journal	November 2002
Humidity sensors based on pentacene thin-film transistors Zhu, Zheng-Tao; Mason, Jeffrey T.; Dieckmann, Rüdiger Applied Physics Letters, Vol. 81, Issue 24 https://doi.org/10.1063/1.1527233	journal	December 2002
Thermoelectric power and conductivity of iodine‐doped ‘‘new’’ polyacetylene Zuzok, R.; Kaiser, A. B.; Pukacki, W. The Journal of Chemical Physics, Vol. 95, Issue 2 https://doi.org/10.1063/1.461107	journal	July 1991

Similar Records

Investigation of the basic mechanisms of radiation effects on semiconductor devices used in electro-optical sensor applications. Final report, January 1978-January 1979

Technical Report · Fri Aug 31 00:00:00 EDT 1979 · OSTI ID:1136991

Srour, J R; Othmer, S; Chen, S C; +1 more

Modification of nanoparticle-organic composite electronic materials for improved chemical sensors.

Conference · Tue Mar 01 00:00:00 EST 2005 · OSTI ID:1136991

Howell, Stephen Wayne; Dirk, Shawn M; Wheeler, David A

Phase-locked laser array

Patent · Tue Feb 02 00:00:00 EST 1988 · OSTI ID:1136991

Botez, D; Ackley, D E

Related Subjects

47 OTHER INSTRUMENTATION

Title: Electro-chemical sensors, sensor arrays and circuits

Citation Formats

References (77)

Similar Records

Related Subjects