Microwave-assisted synthesis of carbon nanotubes from tannin, lignin, and derivatives

Viswanathan, Tito

Title: Microwave-assisted synthesis of carbon nanotubes from tannin, lignin, and derivatives

Patent · Tue Jun 17 00:00:00 EDT 2014

OSTI ID:1134455

Viswanathan, Tito

A method of synthesizing carbon nanotubes. In one embodiment, the method includes the steps of: (a) dissolving a first amount of a first transition-metal salt and a second amount of a second transition-metal salt in water to form a solution; (b) adding a third amount of tannin to the solution to form a mixture; (c) heating the mixture to a first temperature for a first duration of time to form a sample; and (d) subjecting the sample to a microwave radiation for a second duration of time effective to produce a plurality of carbon nanotubes.

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Research Organization:: Univ. of Arkansas, Little Rock, AR (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: FG36-06GO86072

Assignee:: The Board of Trustees of the University of Arkansas (Little Rock, AR)

Patent Number(s):: 8,753,603

Application Number:: 13/069,132

OSTI ID:: 1134455

Resource Relation:: Patent File Date: 2011 Mar 22

Country of Publication:: United States

Language:: English

References (65)

Process for the production of carbonized material Miura, Masakatsu; Kaga, Harumi; Ishizaki, Kozo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20020064495 US Patent Application 09/739298; 20020064495	patent-application	May 2002
Processes for manufacturing particles coated with activated lignosulfonate Mitchell, Michael Donovan; Owens, Blair Alex; Collias, Dimitris Ioannis https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6733827 US Patent Document 6,733,827	patent	May 2004
The effect of nanocrystalline magnetite size on arsenic removal Mayo, J. T.; Yavuz, C.; Yean, S. Science and Technology of Advanced Materials, Vol. 8, Issue 1-2, p. 71-75 https://doi.org/10.1016/j.stam.2006.10.005	journal	January 2007
Novel catalysts for advanced hydroprocessing: transition metal phosphides Oyama, S. Ted Journal of Catalysis, Vol. 216, Issue 1-2, p. 343-352 https://doi.org/10.1016/S0021-9517(02)00069-6	journal	May 2003
Adsorption of arsenic to magnetite nanoparticles: Effect of particle concentration, pH, ionic strength, and temperature Shipley, Heather J.; Yean, Sujin; Kan, Amy T. Environmental Toxicology and Chemistry, Vol. 28, Issue 3, p. 509-515 https://doi.org/10.1897/08-155.1	journal	December 2009
Oil spill recovery method using surface-treated iron powder Ulicny, John C.; Golden, Mark A. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7303679 US Patent Document 7,303,679	patent	December 2007
Preparation of high nitrogen compound and materials therefrom Huynh, My Hang V.; Hiskey, Michael A. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7119179 US Patent Document 7,119,179	patent	October 2006
Microwave-Assisted Synthesis of a Superparamagnetic Surface-Functionalized Porous Fe₃O₄/C Nanocomposite Hu, Xianluo; Yu, Jimmy C. Chemistry – An Asian Journal, Vol. 1, Issue 4, p. 605-610 https://doi.org/10.1002/asia.200600111	journal	October 2006
Polymeric nanocomposites comprising epoxy-functionalized graft polymer Ton-That, Minh-Tan; Utracki, Lechoslaw Adam; Cole, Kenneth C. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7220484 US Patent Document 7,220,484	patent	May 2007
High volume production of nanostructured materials Ripley, Edward; Morrell, Jonathan; Seals, Roland https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070266825 US Patent Application 11/415840; 20070266825	patent-application	November 2007
Green Synthesis of Nanometals Using Plant Extracts and Use Thereof Hoag, George E.; Collins, John B.; Varma, Rajender S. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100200501 US Patent Application 12/667384; 20100200501	patent-application	August 2010
Microwave-assisted synthesis of carbon and carbon-metal composites from lignin, tannin and asphalt derivatives Viswanathan, Tito https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8167973 US Patent Document 8,167,973	patent	May 2012
Nanoparticles And Their Manufacture Pickett, Nigel; Daniels, Steven; Mushtaq, Imrana https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100283005 US Patent Application 12/239254; 20100283005	patent-application	November 2010
Activated carbon with active metal sites and process for producing same Dimitri, Mitchell https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/3886093 US Patent Document 3,886,093	patent	May 1975
Copper-doped mesoporous activated carbons as electrode material for electrochemical capacitors Qinghan, Meng; Ling, Liu; Huaihe, Song Journal of Applied Electrochemistry, Vol. 36, Issue 1, p. 63-67 https://doi.org/10.1007/s10800-005-9023-9	journal	October 2005
Diamond/carbon/carbon composite useful as an integral dielectric heat sink Ting, Jyh-Ming; Lake, Max L. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5604037 US Patent Document 5,604,037	patent	February 1997
Material comprising a surface consisting of a metal carbide-carbon composite and a method for producing the same Meschke, Frank https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050271816 US Patent Application 10/522533; 20050271816	patent-application	December 2005
Manufacturing method of a thin film on a substrate Lee, Tien-Hsi https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6486008 US Patent Document 6,486,008	patent	November 2002
Flash Carbonization of Biomass Antal, Michael Jerry; Mochidzuki, Kazuhiro; Paredes, Lloyd S. Industrial & Engineering Chemistry Research, Vol. 42, Issue 16, p. 3690-3699 https://doi.org/10.1021/ie0301839	journal	August 2003
A Novel Carbothermal Method for the Preparation of Nano-sized WC on High Surface Area Carbon Liu, Wei; Soneda, Yasushi; Hatori, Hiroaki Chemistry Letters, Vol. 35, Issue 10, p. 1148-1149 https://doi.org/10.1246/cl.2006.1148	journal	October 2006
Apparatus for making industrial diamond Pike-Biegunski, Maciej J. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5609683 US Patent Document 5,609,683	patent	March 1997
Removal of arsenic from water streams: an overview of available techniques Vaclavikova, Miroslava; Gallios, George P.; Hredzak, Slavomir Clean Technologies and Environmental Policy, Vol. 10, Issue 1, p. 89-95 https://doi.org/10.1007/s10098-007-0098-3	journal	July 2007
Process For Removal Of Organic Contaminants From A Fluid Stream Sutherland, Gordon https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/3803033 US Patent Document 3,803,033	patent	April 1974
Separation of an aqueous or water-miscible liquid from a fluid mixture Cooper, William D. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4108767 US Patent Document 4,108,767	patent	August 1978
A novel nanostructure of nickel nanotubes encapsulated in carbon nanotubes Bao, Jianchun; Wang, Keyu; Xu, Zheng Chemical Communications, Issue 2, p. 208-209 https://doi.org/10.1039/B208539A	journal	December 2002
Microwave-assisted route for synthesis of nanosized metal oxides Lagashetty, Arunkumar; Havanoor, Vijayanand; Basavaraja, S. Science and Technology of Advanced Materials, Vol. 8, Issue 6, p. 484-493 https://doi.org/10.1016/j.stam.2007.07.001	journal	January 2007
Carbon electrode material for electrochemical cells and method of making same Mao, Zhenhua; Deng, Guoping; Kerzhner-Hal, Inna https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5972537 US Patent Document 5,972,537	patent	October 1999
Oil well drilling clay conditioners and method of their preparation Detroit, William J. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4457853 US Patent Document 4,457,853	patent	July 1984
Microwave synthesis of nanocarbons from conducting polymers Zhang, Xinyu; Manohar, Sanjeev K. Chemical Communications, Issue 23, p. 2477-2479 https://doi.org/10.1039/B603925A	journal	May 2006
Fabrication of novel copper phosphide (Cu₃P) hollow spheres by a simple solvothermal method Wang, Xinjun; Han, Kun; Gao, Youjun Journal of Crystal Growth, Vol. 307, Issue 1, p. 126-130 https://doi.org/10.1016/j.jcrysgro.2007.06.004	journal	September 2007
Oil spill recovery method using surface-treated iron powder Ulicny, John; Golden, Mark https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050139550 US Patent Application 11/009417; 20050139550	patent-application	June 2005
Microwave-assisted synthesis of carbon supported Pt nanoparticles for fuel cell applications Chen, Wei Xiang; Lee, Jim Yang; Liu, Zhaolin Chemical Communications, Issue 21, p. 2588-2589 https://doi.org/10.1039/B208600J	journal	October 2002
Method of preparing a nanoporous nickel phosphate molecular sieve Jhung, Sung Hwa; Chang, Jong-San; Park, Sang-Eon https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7297652 US Patent Document 7,297,652	patent	November 2007
Obtaining carbon nanotubes from grass Kang, Zhenhui; Wang, Enbo; Mao, Baodong Nanotechnology, Vol. 16, Issue 8 https://doi.org/10.1088/0957-4484/16/8/036	journal	May 2005
Method and apparatus for synthesizing diamond, electrode for diamond synthesis, and method for manufacturing the electrode Takagi, Yoshiki; Suda, Yoshihisa; Shimizu, Osamu https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050186344 US Patent Application 11/059334; 20050186344	patent-application	August 2005
Process for producing metal oxide flakes Xiong, Rong; Bujard, Patrice https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070243337 US Patent Application 11/732405; 20070243337	patent-application	October 2007
Preparation of Nanoparticle Materials Mushtaq, Imrana; Daniels, Steven; Pickett, Nigel https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080160306 US Patent Application 11/852748; 20080160306	patent-application	July 2008
Lignocellulose-based anion-adsorbing medium (LAM) and process for making and using same for the selective removal of phosphate and arsenic anionic contaminants from aqueous solutions Kim, Ju-Young https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7758756 US Patent Document 7,758,756	patent	July 2010
Mechanism of Hydrodenitrogenation on Phosphides and Sulfides Oyama, S. Ted; Lee, Yong-Kul The Journal of Physical Chemistry B, Vol. 109, Issue 6, p. 2109-2119 https://doi.org/10.1021/jp049194l	journal	February 2005
Preparation and characterization of NiO nanorods by thermal decomposition of NiC₂O₄ precursor Xu, Congkang; Xu, Guoding; Wang, Guanghou Journal of Materials Science, Vol. 38, Issue 4, p. 779-782 https://doi.org/10.1023/A:1021856930632	journal	February 2003
Use of Nanosized Particulates and Fibers in Elastomer Seals for Improved Performance Metrics for Roller Cone Bits Griffo, Anthony; Keshavan, Madapusi K. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090038858 US Patent Application 12/185580; 20090038858	patent-application	February 2009
Controlled Synthesis, Characterization, and Crystallization of Ni−P Nanospheres Xie, Songhai; Qiao, Minghua; Zhou, Wuzong The Journal of Physical Chemistry B, Vol. 109, Issue 51 https://doi.org/10.1021/jp055068l	journal	December 2005
Enhanced field emission from O₂ and CF₄ plasma-treated CuO nanowires Zhu, Y. W.; Moo, A. M.; Yu, T. Chemical Physics Letters, Vol. 419, Issue 4-6, p. 458-463 https://doi.org/10.1016/j.cplett.2005.11.087	journal	February 2006
Carbon Nitride Preparation Method Mamakhel, Mohammad Aref Hasan; Philippov, Sergej Nicolaevich; Lappalainen, Reijo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100015030 US Patent Application 12/307959; 20100015030	patent-application	January 2010
Structured inorganic materials and method for making and using same Shin, Yongsoon; White, James; Exarhos, Gregory https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080017291 US Patent Application 11/488351; 20080017291	patent-application	January 2008
Process For Producing Carbon Nanotubes And Carbon Nanotubes Produced Thereby Goodell, Barry; Xie, Xinfeng; Qian, Yuhui https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110256401 US Patent Application 13/172132; 20110256401	patent-application	October 2011
Lignosulfonate composition and process for its preparation Briggs, William Scott; Kjargaard, Niels J. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4019995 US Patent Document 4,019,995	patent	April 1977
Sulfonated aromatic copolyesters containing hydroxyalkanoic acid groups and shaped articles produced therefrom Hayes, Richard Allen https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7358325 US Patent Document 7,358,325	patent	April 2008
Ceramic composite material and method for producing same Ueno, Tomoyuki; Yoshimura, Masashi https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070129233 US Patent Application 10/595577; 20070129233	patent-application	June 2007
A synergistic assembly of nanoscale lamellar photoconductor hybrids Sofos, Marina; Goldberger, Joshua; Stone, David A. Nature Materials, Vol. 8, Issue 1, p. 68-75 https://doi.org/10.1038/nmat2336	journal	December 2008
Carbon electrode material for electrochemical cells and method of making same Denton, III, Frank R.; Smith, Daryl R. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6099990 US Patent Document 6,099,990	patent	August 2000
Process for producing aluminum nitride powders Hashimoto, Noboru; Sawada, Yasushi; Yoden, Hiroyoshi https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4985225 US Patent Document 4,985,225	patent	January 1991
Ferromagnetic conducting lignosulfonic acid-doped polyaniline nanocomposites Viswanathan, Tito; Berry, Brian S. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6764617 US Patent Document 6,764,617	patent	July 2004
Controlled synthesis and characterization of nickel phosphide nanocrystal Liu, Shuling; Liu, Xinzheng; Xu, Liqiang Journal of Crystal Growth, Vol. 304, Issue 2, p. 430-434 https://doi.org/10.1016/j.jcrysgro.2007.03.002	journal	June 2007
Control of sp²/sp³ Carbon Ratio and Surface Chemistry of Nanodiamond Powders by Selective Oxidation in Air Osswald, Sebastian; Yushin, Gleb; Mochalin, Vadym Journal of the American Chemical Society, Vol. 128, Issue 35, p. 11635-11642 https://doi.org/10.1021/ja063303n	journal	September 2006
Synthesis of Inorganic Solids Using Microwaves Rao, K. J.; Vaidhyanathan, B.; Ganguli, M. Chemistry of Materials, Vol. 11, Issue 4, p. 882-895 https://doi.org/10.1021/cm9803859	journal	April 1999
Use of a Composite or Composition of Diamond and Other Material for Analysis of Analytes Bachmann, Peter; Van Elsbergen, Volker; Hoffmann, Ralf https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070218564 US Patent Application 11/568191; 20070218564	patent-application	September 2007
Hydrodesulfurization of Petroleum Feedstocks with a New Type of Nonsulfide Hydrotreating Catalyst Oyama, S. T.; Wang, X.; Requejo, F. G. Journal of Catalysis, Vol. 209, Issue 1, p. 1-5 https://doi.org/10.1006/jcat.2002.3613	journal	July 2002
Magnetic activated carbon particles for adsorption of solutes from solution Miller, Jan; Munoz, Gustavo; Duyvesteyn, Saskia https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040147397 US Patent Application 10/468882; 20040147397	patent-application	July 2004
Polymer/Nanoparticle Composites, Film And Molecular Detection Device Li, Changming; Chen, Wei https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110253546 US Patent Application 12/949294; 20110253546	patent-application	October 2011
Polymetallic precursors and compositions and methods for making supported polymetallic nanocomposites Lukehart, Charles M.; King, William D.; Milne, Stephen Bruce https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6232264 US Patent Document 6,232,264	patent	May 2001
Method for manufacturing activated carbon, polarizable electrode, and electric double-layered capacitor Sugo, Nozomu; Iwasaki, Hideharu; Kitamura, Takanori https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050181941 US Patent Application 10/509087; 20050181941	patent-application	August 2005
Negative Active Material Including Metal Nanocrystal Composite, Method Of Preparing The Same, And Anode And Lithium Battery Including The Negative Active Material Kim, Han-su; Park, Jin-hwan; Doo, Seok-gwang https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070264574 US Patent Application 11/736549; 20070264574	patent-application	November 2007
Determination of the Composition of Commercial Tannin Extracts by Liquid Secondary Ion Mass Spectrometry (LSIMS) Vivas, Nicolas; Bourgeois, Guy; Vitry, Christiane Journal of the Science of Food and Agriculture, Vol. 72, Issue 3, p. 309-317 https://doi.org/10.1002/(SICI)1097-0010(199611)72:3<309::AID-JSFA658>3.0.CO;2-U	journal	November 1996
Activated carbon fibers and engineered forms from renewable resources Baker, Frederick S. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20070142225 US Patent Application 11/311184; 20070142225	patent-application	June 2007

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